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Role of Interstitial Solid Solutions in the Formation of the Active Component of Supported Palladium Catalysts for the Selective Hydrogenation of Acetylene to Ethylene

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Abstract

The concepts of the effect of the adsorption of the reaction medium components on the selective hydrogenation of acetylene to ethylene under the action of supported palladium catalysts have been discussed. The role of interstitial solid solutions of carbon and hydrogen in palladium, which are formed upon contact of the catalyst with the reaction medium, in the occurrence of mass transfer processes between the surface and the subsurface layer of the active component has been shown. The ratio of activation barriers to ethylene desorption/adsorption processes, which determines the acetylene hydrogenation selectivity, can vary depending on the structure of palladium nanoparticles and the electronic state of Pd. In addition, changes in the electronic state affect the energy of the activated desorption of ethylene from palladium particles, and their structural features determine the energy of the activated adsorption and subsequent hydrogenation of ethylene to ethane.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of a state task to Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences (project no. AAAA-A21-121011390011-4).

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  1. Center of New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Omsk, Russia

    D. A. Shlyapin, D. V. Glyzdova, T. N. Afonasenko, V. L. Temerev & A. V. Lavrenov

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Shlyapin, D.A., Glyzdova, D.V., Afonasenko, T.N. et al. Role of Interstitial Solid Solutions in the Formation of the Active Component of Supported Palladium Catalysts for the Selective Hydrogenation of Acetylene to Ethylene. Catal. Ind. 15, 297–312 (2023). https://doi.org/10.1134/S207005042303008X

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