Abstract
The possibility of preparation of a polymetallic dispersed Fe–Ni–Co–Al system in aqueous solutions by a redox process between iron(III), nickel(II), cobalt(II) ions and aluminum microparticles in aqueous solutions is shown. In this case, a structure is formed in the aqueous solution, which, from the standpoint of the phase composition, is a mechanical mixture of elemental metals. It has been found that the synthesized Fe–Ni–Co–Al system consists of metallic aluminum particles coated with elemental metals (iron, nickel, and cobalt) with a minimum content of the oxide phase. Additional HF modification of the studied sample of the polymetallic system in low pressure inductive discharge plasma leads to the formation of a number of intermetallic compounds, mainly CoFe (~60%) and FeNi (~15%), and also ensures particle spheroidization. The resulting intermetallic powder composition is potentially suitable for use in additive manufacturing technologies.
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Funding
The work was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the State order for the provision of public services (performance of work) dated December 29, 2022, no. 075-01508-23-00. The study was carried out using the equipment of the Center for Collective Use “Nanomaterials and Nanotechnologies” of the Kazan National Research Technological University.
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Dresvyannikov, A.F., Kolpakov, M.E. & Ermolaeva, E.A. Preparation of Polymetal Powder Systems Fe–Ni–Co–Al in Aqueous Solutions and Their Physical Characteristics. Russ. J. Phys. Chem. 97, 2136–2143 (2023). https://doi.org/10.1134/S0036024423100072
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DOI: https://doi.org/10.1134/S0036024423100072