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Absorption Spectrum of H217O between 7900 and 9500 cm−1

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Abstract—

Absorption spectrum of water vapor highly enriched with 17O (more than 80%) was recorded using a Bruker IFS 125M Fourier spectrometer in the 7900–9500 cm−1 range at room temperature. The spectrum was recorded at a pressure of about 24 mbar with a spectral resolution of 0.02 cm−1. About 6300 lines with a minimal intensity of 5.0 × 10−27 cm/molecule are found in the spectrum recorded. 4835 recorded lines are assigned to 5185 transitions of five water isotopologues (H216O, H217O, H218O, HD16O, and HD17O). H217O lines are assigned to 14 vibration bands. Most of them are the lines of the ν2 + 2ν3, 3ν2 + ν3, ν1 + ν2 + ν3, ν1 + 3ν2, and 2ν1 + ν2 bands. The lines of the ν1 + 2ν2 + ν3 − ν2, 2ν1 + ν3 − ν2, and 2ν1 + 2ν2 − ν2 hot bands are assigned for the first time. The lines assigned allow us to determine 153 new vibration–rotation energies of nine vibrational states of the H217O molecule and 22 energies of two states of the HD17O molecule. The obtained data are compared with the results of previous studies, HITRAN2020 spectroscopic database, and W2020 list.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (V.E. Zuev Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences).

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  1. V.E. Zuev Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, 634055, Tomsk, Russia

    V. I. Serdyukov, L. N. Sinitsa & S. N. Mikhailenko

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Serdyukov, V.I., Sinitsa, L.N. & Mikhailenko, S.N. Absorption Spectrum of H217O between 7900 and 9500 cm−1. Atmos Ocean Opt 36, 454–464 (2023). https://doi.org/10.1134/S1024856023050147

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