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Estimation of the Efficiency of Oxalic Acid in the Solution Combustion Synthesis of a Catalyst for Production of Hydrogen and Carbon from Methane

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Abstract

The parameters of the synthesis of catalysts by the solution combustion method using oxalic acid as a reducing agent were investigated. The activity of the catalysts was determined in the production of hydrogen and carbon nanofibers by the catalytic decomposition of methane. The efficiency of oxalic acid was demonstrated in the preparation of a nickel catalyst (90% Ni/10% Al2O3), which does not require the preliminary reduction with hydrogen. Regression analysis identified that the yields of carbon and hydrogen are most strongly affected by temperature among other synthesis parameters.

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ACKNOWLEDGMENTS

We thank the Department of Structural Studies, Zelinsky Institute of Organic Chemistry RAS, for studying the samples by electron microscopy.

Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (state task, project no. FSUN-2023-0008).

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Authors and Affiliations

  1. Novosibirsk State Technical University, 630073, Novosibirsk, Russia

    P. B. Kurmashov, M. V. Popov, A. E. Brester & A. G. Bannov

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. V. Popov

  3. Institute of Solid-State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. V. Ukhina

Authors
  1. P. B. Kurmashov
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  2. M. V. Popov
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  3. A. E. Brester
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  4. A. V. Ukhina
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  5. A. G. Bannov
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Corresponding author

Correspondence to P. B. Kurmashov.

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Translated by V. Glyanchenko

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Kurmashov, P.B., Popov, M.V., Brester, A.E. et al. Estimation of the Efficiency of Oxalic Acid in the Solution Combustion Synthesis of a Catalyst for Production of Hydrogen and Carbon from Methane. Dokl Chem 511, 209–216 (2023). https://doi.org/10.1134/S0012500823600426

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  • DOI: https://doi.org/10.1134/S0012500823600426

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