Nitrogen-doped carbon, which is characterized by a large surface area and the presence of micro- and mesopores, has been obtained by pyrolysis of polyaniline (emeraldine base) in a reducing atmosphere. It is found that the surface layer of such material contains nitrogen in pyridinic, pyrrolic, and quaternary configurations, as well as hydroxyl and carbonyl groups. It is shown that carbonized polyaniline reveals catalytic properties in the processes of gas-phase and liquid-phase hydrogenation with molecular hydrogen of organic substrates containing C=C double bond and nitro group (ethylene, α-methylstyrene, p-nitrotoluene) are revealed.
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Acknowledgements
The author I. B. Bychko expresses his gratitude to the CERIC-ERIC Consortium for the opportunity to conduct X-ray photoelectron spectroscopy measurements at Charles University in Prague and for financial support under proposal No. 20202078.
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Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 59, No. 3, pp. 167-172, May-June, 2023
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Kurys, Y.I., Bychko, I.B., Pariiska, O.O. et al. Carbonized Polyaniline as a Catalyst for Hydrogenation with Molecular Hydrogen of Organic Substrates with C=C Double Bond and Nitro Group. Theor Exp Chem 59, 193–199 (2023). https://doi.org/10.1007/s11237-023-09778-1
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DOI: https://doi.org/10.1007/s11237-023-09778-1