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Hydrochlorides and Dodecahydro-closo-dodecaborates of Amino Derivatives of 1,3,5-Triazine in the Technology of Isolation and Purification of the [B12H12]2– Anion

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Abstract

The possibility of using salts of 2,4,6-triamine-1,3,5-triazine, 2,4-diamine-6-methyl-1,3,5-triazine, and 2,4-diamine-6-phenyl-1,3,5-triazine for isolation of the dodecahydro-closo-dodecaborate anion [B12H12]2– from aqueous solutions has been studied. Compound [2,4-(NH2)2-6-Ph-1,3,5-N3С3H]2[B12H12]⋅H2O (solubility 0.06 g in 100 g water at 17°C), promising for the precipitation of the [B12H12]2– anion, has been isolated by the metathesis reaction of moderately soluble hydrochloride [2,4-(NH2)2-6-Ph-1,3,5-N3С3H]Cl⋅H2O with sodium and potassium dodecahydro-closo-dodecaborates. A procedure has been developed for the decomposition of [2,4-(NH2)2-6-Ph-1,3,5-N3С3H]2[B12H12]⋅H2O with ammonium hydroxide to obtain soluble salts of the [B12H12]2– anion.

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Funding

The work was carried out within the framework of the State Assignment of the Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences (topic FWFN (205)-2022-0003).

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Authors and Affiliations

  1. Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    V. I. Saldin, L. N. Ignat’eva, V. A. Mashchenko, V. V. Sukhovei & Yu. V. Marchenko

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  1. V. I. Saldin
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  2. L. N. Ignat’eva
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  3. V. A. Mashchenko
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  4. V. V. Sukhovei
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Correspondence to V. I. Saldin.

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Translated by V. Avdeeva

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Saldin, V.I., Ignat’eva, L.N., Mashchenko, V.A. et al. Hydrochlorides and Dodecahydro-closo-dodecaborates of Amino Derivatives of 1,3,5-Triazine in the Technology of Isolation and Purification of the [B12H12]2– Anion. Russ. J. Inorg. Chem. 68, 1363–1370 (2023). https://doi.org/10.1134/S0036023623601915

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