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Coordination Polymer or Cluster: Zinc Bis(3,5-di-tert-octyl-semiquinolate) with Pyrazine

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Abstract

New zinc bis-o-semiquinolate complexes based on 3,5-di-tert-octyl-o-benzoquinone bearing the N-donor ligand (pyrazine) coordinated to the metal are synthesized. Two different products can be obtained depending on the synthesis method: coordination polymer (direct oxidation of metallic zinc with o-quinone (CIF file CCDC no. 2250574 (I)) or polynuclear cluster (exchange reaction (CIF file CCDC no. 2250575 (II)). The coordination polymer is linear and free of intermolecular π,π interactions between the aromatic fragments of the adjacent molecules. The magnetochemical study of complexes I and II shows that intramolecular antiferromagnetic exchange interactions between spins of the o-semiquinolate radical centers dominate.

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ACKNOWLEDGMENTS

This work was carried out using the equipment of the Center for Collective Use “Analytical Center of Institute of Organometallic Chemistry of Russian Academy of Sciences” and supported by the project “Provision of Development of Material Technical Infrastructure of Centers for Collective Use of Scientific Equipment” (unique identifier RF–2296.61321X0017, agreement no. 075-15-2021-670). The XRD studies of complexes I and II were conducted using the equipment of the Center for Collective Use of Physical Methods of Investigation at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences).

Funding

This work was supported by the Council on Grants of the President of the Russian Federation aimed at supporting leading scientific schools, project no. NSh-403.2022.1.3.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    A. V. Maleeva, O. Yu. Trofimova, T. N. Kocherova & A. V. Piskunov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. A. Yakushev

  3. International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. S. Bogomyakov

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  1. A. V. Maleeva
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  2. O. Yu. Trofimova
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  3. T. N. Kocherova
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  4. I. A. Yakushev
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  5. A. S. Bogomyakov
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Correspondence to A. V. Maleeva or A. V. Piskunov.

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Translated by E. Yablonskaya

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Maleeva, A.V., Trofimova, O.Y., Kocherova, T.N. et al. Coordination Polymer or Cluster: Zinc Bis(3,5-di-tert-octyl-semiquinolate) with Pyrazine. Russ J Coord Chem 49, 718–729 (2023). https://doi.org/10.1134/S1070328423600742

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