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Complexes of Silver 1,1,1,5,5,6,6,6-Octafluorohexane-2,4-dionate with π-Donor Ligands: Synthesis, Structure, and Thermal Properties

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Abstract

Two new Ag(I) complexes with 1,1,1,5,5,6,6,6-octafluorohexane-2,4-dionate ion (Ofhac) and π‑donor neutral ligands, vinyltriethylsilane (VTES) or cycloocta-1,5-diene (COD), were synthesized with the goal to expand the library of silver precursors for chemical vapor deposition. The products were characterized by elemental analysis and IR and NMR spectroscopy. The complex [Ag(VTES)(Ofhac)] (I) was liquid under standard conditions; the temperature of its crystallization was below –20°C. Treatment of I with benzene gave rise to crystals of [Ag4(C6H6)2(Ofhac)4]∞ (II), which was confirmed by NMR and X-ray diffraction (CCDC no. 2232810). The structure of [Ag(COD)(Ofhac)]2 (III) was established by X-ray diffraction (CCDC no. 2232809). The binuclear molecules are formed due to the μ2-κ1(O):κ1(O') function of the Ofhac ligands (Ag–O, 2.458(2)–2.461(2) Å), while COD is κ2-η2:η2-coordinated (Ag–C, 2.420(17)–2.684(11) Å). The thermal properties of I and III in comparison with analogues containing 1,1,1,5,5,5-hexafluoropentane-2,4-dionate ion (Hfac) were studied by thermogravimetry.

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ACKNOWLEDGMENTS

The authors wish to thank M.A. Kurykin (Nesmeyanov Instituted of Organoelement Compounds, Russian Academy of Sciences) for the synthesis of fluorinated β-diketones and S.A. Gulyaev (Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences) for participation in the primary synthesis of [Ag(COD)(Ofhac)]2. We are grateful to the Chemical Research Center for Collective Use, Siberian Branch, Russian Academy of Sciences (Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences) for conduction of the elemental analysis and to the Center for Collective Use of the Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, for the possibility to collect X-ray diffraction data. The authors thank the Ministry of Science and Higher Education of the Russian Federation (Project nos. 121031700313-8 and 121031700314-5).

Funding

This study was supported by a grant of President of the Russian Federation for the state support of young Russian scientists, Candidates of Sciences (MK-6148.2021.1.3).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. S. Vikulova, I. Yu. Il’in, T. S. Sukhikh & N. B. Morozova

  2. Novosibirsk State Technical University, Novosibirsk, Russia

    P. K. Artamonova

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  1. E. S. Vikulova
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  2. I. Yu. Il’in
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  3. T. S. Sukhikh
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Correspondence to E. S. Vikulova.

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Translated by Z. Svitanko

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Vikulova, E.S., Il’in, I.Y., Sukhikh, T.S. et al. Complexes of Silver 1,1,1,5,5,6,6,6-Octafluorohexane-2,4-dionate with π-Donor Ligands: Synthesis, Structure, and Thermal Properties. Russ J Coord Chem 49, 743–752 (2023). https://doi.org/10.1134/S1070328423600407

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