Skip to main content
SpringerLink
Log in

Heterophase Synthesis of Silver Trifluoroacetate with Copper, Indium, and Zinc. Standard Enthalpy of Formation of Copper Trifluoroacetate

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Solid-phase reactions of silver trifluoroacetate CF3COOAg with copper, indium, and zinc are studied by thermogravimetry, differential scanning calorimetry, and mass spectrometry. In a temperature range of 358–428 K, the reactions are found to afford trifluoroacetates of these metals without mass loss of the weighed samples. The obtained experimental data make it possible to calculate the enthalpy of formation of copper trifluoroacetate \({{\Delta }_{f}}H_{{298}}^{^\circ }\)(CF3СООСu, cr) = –1020.5 ± 18.0 kJ/mol.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Syrkin, V.G. CVD-metod. Khimicheskaya parofaznaya metallizatsiya (CVD Method. Chemical Vapor Metallization), Moscow: Nauka, 2000.

  2. Fromm, K.M. and Gueneau, E.D., Polyhedron, 2004, vol. 23, p. 1479.

    Article  CAS  Google Scholar 

  3. Paramonov, S., Samoilenkov, S., Papucha, S., et al., J. Phys. IV, 2001, vol. 11, p. Pr3-645-52.

  4. Morozova, E.A., Dobrokhotova, Zh.V., and Alikhanyan, A.S., J. Therm. Anal. Calorim., 2017, vol. 130, no. 3, p. 2211.

    Article  CAS  Google Scholar 

  5. Lukyanova, V.A., Papina, T.S., Didenko, K.V., et al., J. Therm. Anal. Calorim., 2008, vol. 92, p. 743.

    Article  CAS  Google Scholar 

  6. Kamkin, N.N., Kayumova, D.B., Yaryshev, N.G., et al., Russ. J. Inorg. Chem., 2012, vol. 57, p. 1308.

    Article  CAS  Google Scholar 

  7. Luo, Y.-R., Handbook of Bond Dissociation Energies in Organic Compounds, CRC Press LLC, 2003.

    Google Scholar 

  8. Termicheskie konstanty veshchestv. Spravochnik (Thermal Characteristics of Substances. Handbook), Glushko, V.P., Ed., VINITI, 1965–1981, vol. 4, part 1, vol. 6, part 1.

  9. Gurvich, L.V., Karachevtsev, G.V., Kondrat’ev, V.N., et al., Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu (Chemical Bond Energies. Ionization Potentials and Electron Affinities), Moscow: Nauka, 1974.

  10. Karapet’yants, M.Kh. and Karapet’yants, M.L., Spravochnik. Osnovnye termodinamicheskie konstanty neorganicheskikh i organicheskikh veshchestv (Handbook. Key Thermodynamic Characteristics of Inorganic and Organic Compounds), Moscow: Khimiya, 1968.

  11. NIST Chemistry WebBook, Linstrom, P.J. and Mallard, W.G., Eds., NIST Standard Reference Database Number 69, Gaithersburg (MD): National Institute of Standards and Technology, 2023. https://doi.org/10.18434/T4D303

  12. Kireev, V.A., Metody prakticheskikh raschetov v termodinamike khimicheskikh reaktsii (Practical Calculation Methods for Thermodynamics of Chemical Reactions), Moscow: Khimiya, 1970.

  13. Christe, K.O. and Naumann, D., Spectrochim. Acta, Part A, 1973, vol. 29, no. 12, p. 2017. https://doi.org/10.1016/0584-8539(73)80060-1

    Article  Google Scholar 

  14. Szczęsny, R. and Szłyk, E., J. Therm. Anal. Calorim., 2013, vol. 111, no. 2, p. 1325.

    Article  Google Scholar 

  15. Li, H., Zhao, B., Ding, R., et al., Crystal Growth Design, 2012, vol. 12, no. 8, p. 4170.

    Article  CAS  Google Scholar 

  16. Chirakkara, S., Nanda, K.K., and Krupanidhi, S.B., Thin Solid Films, 2011, vol. 519, p. 3647.

    Article  CAS  Google Scholar 

  17. Bernik, S., Kosir, M., and Guilmeau, E., Zast. Mater., 2016, vol. 57, no. 2, p. 318.

    Google Scholar 

  18. Gholami, M., Khodadadi, A.A., Anaraki Firooz, A., et al., Sensors Actuators B, 2015, vol. 212, p. 395.

    Article  CAS  Google Scholar 

  19. Ahmad, M., Zhao, J., Iqbal, J., et al., J. Phys. D: Appl. Phys., 2009, vol. 42, p. 165406.

    Article  Google Scholar 

  20. Mishra, S. and Daniele, S., Chem. Rev., 2015, vol. 115, no. 16, p. 8379.

    Article  CAS  PubMed  Google Scholar 

  21. Hichou, A.E., Bougrine, A., Bubendorff, J.L., et al., Semicond. Sci. Technol., 2002, vol. 17, no. 6, p. 607.

    Article  Google Scholar 

  22. Gunasekaran, E., Ezhilan, M., Mani, G., et al., Semicond. Sci. Technol., 2018, vol. 33, no. 9, p. 095005.

    Article  Google Scholar 

  23. Antony, A., Pramodini, S., Kityk, I.V., et al., Physica. E, 2017, vol. 94, p. 190.

    Article  CAS  Google Scholar 

  24. Kadi, M.W., McKinney, D., Mohamed, R.M., et al., Ceramics Intern., 2016, vol. 42, no. 4, p. 4672.

    Article  CAS  Google Scholar 

  25. Choi, Y.-J. and Park, H.-H., J. Mater. Chem., 2014, vol. 2, no. 1, p. 98.

    CAS  Google Scholar 

  26. Cosham, S.D., Kociok-Köhn, G., Johnson, A.L., et al., Eur. J. Inorg. Chem., 2015, vol. 2015, no. 26, p. 4362.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Center for Collective Use of Physical Methods of Investigation at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences).

Funding

This work was supported by the Russian Science Foundation, project no. 21-13-00086.

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. P. Malkerova, D. B. Kayumova, E. V. Belova, M. A. Shmelev, A. A. Sidorov, I. L. Eremenko & A. S. Alikhanyan

Authors
  1. I. P. Malkerova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. B. Kayumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Belova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. A. Shmelev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Sidorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. L. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. S. Alikhanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Sidorov.

Ethics declarations

The author of this work declares that they has no conflicts of interest.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Malkerova, I.P., Kayumova, D.B., Belova, E.V. et al. Heterophase Synthesis of Silver Trifluoroacetate with Copper, Indium, and Zinc. Standard Enthalpy of Formation of Copper Trifluoroacetate. Russ J Coord Chem 49, 730–734 (2023). https://doi.org/10.1134/S1070328423600237

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328423600237

Keywords:

Search

Navigation