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Mechanical and Functional Properties of Composite Coatings with Fine Reinforcements Produced from Galvanic Processing Waste

  • PROTECTIVE AND FUNCTIONAL POWDER COATINGS
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Powder Metallurgy and Metal Ceramics Aims and scope

The potential of wastewaters from the galvanic industry treated to remove toxic heavy-metal contaminants for the manufacture of commercial products lies in the development of processes for their reuse. This research addresses the feasibility of employing galvanic waste in the production of powder coatings. Powder waste generated through the resource-saving ferritic method and electroerosion dispersion method is significantly safer for the environment than that generated through reagent methods. Coatings resulting from wastewater treatment exhibit mechanical properties that meet current industry standards. The introduction of 15 wt.% spent polyvalent iron oxide sorbent into paint coatings enhances their mechanical performances. Specifically, the rebound strength increases from 20 to 40 cm/kg and tensile strength from 5 to 7.4 mm, the bending strength decreases from 8 to 5 mm, and the corrosion resistance of the coatings improves by 1.5 times compared to the standard samples. These improvements are attributed to the introduction of chemically and thermally stable crystalline phases possessing ferromagnetic properties into the coatings. As a result, these coatings increase shielding against electromagnetic radiation in the megahertz range by three times compared to the standard coatings. A significant research finding is the potential for reusing ferromagnetic waste from the galvanic industry in specialized materials.

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References

  1. A.S. Timonin, Engineering and Environmental Reference Book [in Russian], Izd. N. Bochkarevoy, Kaluga (2003), Vol. 2, p. 884.

  2. A.V. Cheremisin, L.R. Valiullin, N.S. Myazin, and S.E. Logunov, “Efficient treatment of wastewater from galvanic plants,” J. Phys. Conf. Ser., 1942, No. 1, 012095 (2021), https://doi.org/10.1088/1742-6596/1942/1/012095.

  3. S. Stepanov, N. Morozov, N. Morozova, D. Ayupov, D. Makarov, and D. Baishev, “Efficiency of use of galvanic sludge in cement systems,” Proc. Eng., 165, 1112–1117 (2016).

    Article  CAS  Google Scholar 

  4. S.R. Meda, S.K. Sharma, and G.D. Tyagi, “Utilization of waste sludge as a construction material—A review,” Mater. Today: Proc., 46, Part 9, 4195–4202 (2021).

  5. N.K. Nasirova, K.G. Mukhamedov, Sh.A. Mutalov, and Zh.K. Mukhamedov, “Disposal of galvanic sludge,” Universum: Tekh. Nauki Elektron. Nauch. Zh., 12(93) (2021), https://7universum.com/ru/tech/archive/item/12852.

  6. S. Heuss-Aßbichler, M. John, D. Klapper, U.W. Bläß, and G. Kochetov, “Recovery of copper as zero-valent phase and/or copper oxide nanoparticles from wastewater by ferritization,” J. Environ. Manage., 181, 1–7 (2016), https://doi.org/10.1016/j.jenvman.2016.05.053.

    Article  CAS  Google Scholar 

  7. G. Kochetov, T. Prihna, D. Samchenko, and O. Kovalchuk, “Development of ferritization processing of galvanic wastes with energy saving electromagnetic pulse activation of the process,” East.-Eur. J. Enterp. Technol., 6, Issue 102, 6–14 (2019), https://doi.org/10.15587/1729-4061.2019.184179.

  8. B. Yemchura, G. Kochetov, and D. Samchenko, “Ferritization-based treatment of zinc-containing wastewater flows: Influence of aeration rates,” Environ. Sci. Eng., 258519, 171–176 (2021), https://doi.org/10.1007/978-3-030-51210-1_29.

    Article  Google Scholar 

  9. B. Halbedel, T. Prikhna, P. Quiroz, J. Schawohl, T. Kups, and M. Monastyrov, “Iron oxide nanopowder synthesized by electroerosion dispersion (EED)—Properties and potential for microwave applications,” Curr. Appl. Phys., 18, 1410–1414 (2018), https://doi.org/10.1016/j.cap.2018.08.006.

    Article  Google Scholar 

  10. M. Monastyrov, T. Prikhna, B. Halbedel, G. Kochetov, F.D.S. Marquis, A.G. Mamalis, and O. Prysiazhna, “Electroerosion dispersion, sorption and coagulation for complex water purification: Electroerosion waste recycling and manufacturing of metal, oxide and alloy nanopowders,” Nanotechnol. Percept., 15, 48–57 (2019).

    Article  Google Scholar 

  11. O. Kovalchuk, G. Kochetov, D. Samchenko, and A. Kolodko, “Development of a technology for utilizing the electroplating wastes by applying a ferritization method to the alkaline-activated materials,” Eastern-Eur. J. Enterp. Technol., 2/10, Issue 98, 27–34 (2019), https://doi:https://doi.org/10.15587/1729-4061.2019.160959.

  12. P.P. Mohapatra and P. Dobbidi, “Development of spinel ferrite-based composites for efficient EMI shielding,” Mater. Chem. Phys., 301, 127581 (2023).

    Article  CAS  Google Scholar 

  13. D. Kumar, A. Moharana, and A. Kumar, “Current trends in spinel based modified polymer composite materials for electromagnetic shielding,” Mater. Today: Chem., 17, 100346 (2020).

    CAS  Google Scholar 

  14. Z. Ye, K. Wang, X. Li, and J. Yang, “Preparation and characterization of ferrite/carbon aerogel composites for electromagnetic wave absorbing materials,” J. Alloys Compd., 893, 162396 (2022).

    Article  CAS  Google Scholar 

  15. L. Zhang, Y. Liu, S.U. Rehman, L. Wang, Y. Chen, F. Long, S. Shen, C. Chen, and T. Liang, “In situ synthesis of Fe3O4 coated on iron-based magnetic microwave absorbing materials and the influence of oxide magnetic materials on microwave absorption mechanism,” Ceram. Int., 49, Issue 8, 12972–12979 (2023).

    Article  CAS  Google Scholar 

  16. T. Prikhna, M. Monastyrov, I. Soldatov, B. Büchner, L. Giebeler, A. Sathyadharma Prasad, O. Ostash, V. Moshchil, V. Podhurska, P. Potapov, V. Romaka, K. Neufeld, R. Kluge, T. Serbenyuk, M. Karpets, M. Omelyanenko, A. Wolter-Giraud, and S. Ponomaryov, “Corrosion-resistant polymer-based nanocomposite materials with a high level of microwave absorption and soft magnetic materials based on iron oxide nanopowder obtained by electroerosion dispersion,” Ceram. Int., 49, No. 11 (2022), https://doi.org/10.1016/j.ceramint.2022.11.189.

  17. V. Gots, O. Lastivka, O. Berdnyka, O. Tomin, and P. Shilyukb, “Corrosion resistance of polyester powder coatings using fillers of various chemical nature,” Key Eng. Mater., 864, 115–121 (2020), https://doi.org/10.4028/www.scientific.net/KEM.864.115.

    Article  Google Scholar 

  18. G. Kochetov, D. Samchenko, O. Lastivka, and D. Derecha, “Determining the rational parameters for processing spent etching solutions by ferritization using alternating magnetic fields,” East.-Eur. J. Enterp. Technol., 3, Issue 10, 21–28 (2022), DOI: https://doi.org/10.15587/1729-4061.2022.259791.

    Article  CAS  Google Scholar 

  19. G. Kochetov, T. Prikhna, O. Kovalchuk, and D. Samchenko, “Research of the treatment of depleted nickel-plating electrolytes by the ferritization method,” East.-Eur. J. Enterp. Technol., 3, Issue 6, 52–60 (2018), doi.org/https://doi.org/10.15587/1729-4061.2018.133797/ http://journals.uran.ua/eejet/article/view/133797.

  20. G. Kochetov, D. Samchenko, and T. Arhatenko, “Determination of influence of pH on reaction mixture of ferritation process with electromagnetic pulse activation on the processing of galvanic sludge,” East.-Eur. J. Enterp. Technol., 4/10, Issue 112, 24–30 (2021), https://doi.org/10.15587/1729-4061.2021.239102.

  21. G. Kochetov, T. Prikhna, D. Samchenko, O. Prysiazhna, M. Monastyrov, V. Moshchil, and A. Mamalis, “Resource-efficient ferritization treatment for concentrated wastewater from electroplating production with aftertreatment by nanosorbents,” Nanotechnol., 17, Issue 1, 9–18 (2021), DOI: https://doi.org/10.4024/N22KO20A.ntp.17.01.

    Article  CAS  Google Scholar 

  22. A.V. Buketov, G.A. Bagliuk, O.M. Sizonenko, O.O. Sapronov, S.O. Smetankin, and A.S. Torpakov, “Effect of particulate Ti–Al–TiC reinforcements on the mechanical properties of epoxy polymer composites,” Powder Metall. Met. Ceram., 61, No. 9–10, 586–596 (2022).

    Google Scholar 

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Authors and Affiliations

  1. Kyiv National University of Construction and Architecture, Kyiv, Ukraine

    D. M. Samchenko, G. M. Kochetov & O. V. Lastivka

  2. Frantsevich Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    G. A. Bagliuk

  3. Institute of Magnetism, National Academy of Sciences of Ukraine and Ministry of Education and Science of Ukraine, Kyiv, Ukraine

    D. O. Derecha

  4. Bakul Institute for Superhard Materials, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    T. O. Prikhna

Authors
  1. D. M. Samchenko
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  2. G. A. Bagliuk
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  3. G. M. Kochetov
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  4. O. V. Lastivka
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  5. D. O. Derecha
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  6. T. O. Prikhna
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Correspondence to G. A. Bagliuk.

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Translated from Poroshkova Metallurgiya, Vol. 62, Nos. 3–4 (550), pp. 124–133, 2023.

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Samchenko, D.M., Bagliuk, G.A., Kochetov, G.M. et al. Mechanical and Functional Properties of Composite Coatings with Fine Reinforcements Produced from Galvanic Processing Waste. Powder Metall Met Ceram 62, 233–240 (2023). https://doi.org/10.1007/s11106-023-00386-1

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