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Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2

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Abstract

Crystals of a novel hybrid organo-inorganic borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2 (1), were obtained from aqueous solutions and characterized by single-crystal X-ray diffraction and IR spectroscopy. 1 is triclinic (a = 10.1567(4), b = 11.9941(6), c = 17.1893(9) Å, α = 75.280(4), β = 79.406(4), γ = 88.531(4)°, V = 1990.270369 Å3, SG P-1; R1 = 0.058). Its structure contains [K(C10H20O5)2]+ groups which behave as “hydrophobic” templates for the inorganic part comprised of \({{{\text{B}}}_{{\text{5}}}}{{{\text{O}}}_{{\text{6}}}}\left( {{\text{OH}}} \right)_{4}^{ - }\) anions and neutral B(OH)3 molecules.

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Fig. 1.
Fig. 2.

Notes

  1. The structural data are deposited to the Cambridge Crystallographic Data Centre (CCDC 2255618) and can be obtained from deposit@ccdc.cam.ac.uk or http://www.ccdc.cam.ac.uk.

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Funding

We thank the Russian Science Foundation for the support of this work in the frames of grant no. 22-73-00026; a part of this work was made within the State Task of the Ministry of Science and Higher Education of Russian Federation (no. 0081-2022-0002, Institute of Silicate Chemistry, Russian Academy of Sciences).

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    V. A. Yukhno, S. N. Volkov & R. S. Bubnova

  2. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    D. O. Charkin & L. S. Manelis

  3. Laboratory of Arctic Mineralogy and Materials Sciences, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

    D. O. Charkin, S. N. Volkov, L. S. Manelis & S. M. Aksenov

  4. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Federal Research Center “Cola Science Center,” Russian Academy of Sciences, 184209, Apatity, Murmansk oblast, Russia

    A. N. Gosteva

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  1. V. A. Yukhno
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Correspondence to V. A. Yukhno.

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Yukhno, V.A., Charkin, D.O., Volkov, S.N. et al. Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2. Glass Phys Chem 49, 510–513 (2023). https://doi.org/10.1134/S1087659623600485

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