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Copper corrosion prevention in 3.5% NaCl solution by Spartium junceum petals extract as an eco-friendly bio-inhibitor: kinetic and thermodynamic studies

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Abstract

During the last decades, numerous studies were performed to introduce green corrosion inhibitors. So, various materials were utilized due to their being bio-degradable, available, and inexpensive. Because of the aforementioned aspects, Spartium Junceum petals extract (SJPE) was used as a new bio-inhibitor for the prevention of copper corrosion in a 3.5 wt% NaCl solution. This extract was obtained in water as a non-toxic solvent. Also, gas chromatography-mass spectrometry (GC–MS) confirmed the presence of organic molecules containing O, N, and F heteroatoms in SJPE, which are important for inhibitors. Also, Fourier-transform infrared spectroscopy (FT-IR) was used to identify the functional groups of the inhibitor molecules. Moreover, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques were used which verified the great effect of this procedure to promote resistance corrosion of copper substrate. In addition, scanning electron microscopy (SEM) exhibited the surface morphology of copper substrate in the presence of SJPE which demonstrated the improvement of corrosion resistance in comparison to the absence of this bio-inhibitor. It should be noted that by increasing the amount of SJPE, the inhibition efficiency was ameliorated up to 87.8%. Furthermore, variation in temperature magnitude between 298 and 338 K implied that SPJE can improve inhibition behavior in higher temperatures. By applying temperature effect study data, the value of activation energy in the presence of the inhibitor was calculated (37.9 kJ mol−1), and the adsorption isotherm was Langmuir. Also, these data showed the inhibition mechanism is physical adsorption. The proposed inhibitor can be used as an efficient, eco-friendly, and inexpensive bio-inhibitor for the prevention of copper corrosion.

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References

  1. N.R. Vaidya, P. Aklujkar, A.R. Rao, J. Coat. Technol. Res. 19, 223 (2022). https://doi.org/10.1007/s11998-021-00510-z

    Article  CAS  Google Scholar 

  2. S. Harsimran, K. Santosh, K. Rakesh, Proc. Eng. Sci. 3, 13 (2021). https://doi.org/10.24874/PES03.01.002

    Article  Google Scholar 

  3. G. Koch, Cost of corrosion. Trends in oil and gas corrosion research and technologies (Elsevier, 2017) pp. 3–30. https://doi.org/10.1016/B978-0-08-101105-8.00001-2

  4. A. Hossen, R. Mahmud, A. Islam, Int J Hydro. 7, 9 (2023). https://doi.org/10.15406/ijh.2023.07.00334

    Article  Google Scholar 

  5. S.Z. Salleh, A.H. Yusoff, S.K. Zakaria, M.A. Taib, A.A. Seman, M.N. Masri, M. Mohamad, S. Mamat, S.A. Sobri, A. Ali, P. Ter Teo, J. Clean. Prod. (2021). https://doi.org/10.1016/j.jclepro.2021.127030

    Article  Google Scholar 

  6. H. Wei, B. Heidarshenas, L. Zhou, G. Hussain, Q. Li, K.K. Ostrikov, Mater. Today Sustain. (2020). https://doi.org/10.1016/j.mtsust.2020.100044

    Article  Google Scholar 

  7. T.J. Harvey, F.C. Walsh, A.H. Nahlé, J. Mol. Liq. 266, 160 (2018). https://doi.org/10.1016/j.molliq.2018.06.014

    Article  CAS  Google Scholar 

  8. A. Peter, I.B. Obot, Sanjay K. Int J Ind Chem. 6, 153 (2015). https://doi.org/10.1007/s40090-015-0040-1

    Article  CAS  Google Scholar 

  9. L.T. Popoola, Corros. Rev. 37, 71 (2019). https://doi.org/10.1515/corrrev-2018-0058

    Article  CAS  Google Scholar 

  10. N. Chaubey, A. Qurashi, D.S. Chauhan, M.A. Quraishi, J. Mol. Liq. 32, 114385 (2021). https://doi.org/10.1016/j.molliq.2020.114385

    Article  CAS  Google Scholar 

  11. M. Abdallah, H.M. Altass, A.S. Al-Gorair, J.H. Al-Fahemi, B.A. Jahdaly, K.A. Soliman, J. Mol. Liq. 323, 15036 (2021). https://doi.org/10.1016/j.molliq.2020.115036

    Article  CAS  Google Scholar 

  12. Z. Shang, J. Zhu, J. Mater. Res. Technol. 15, 5078 (2021). https://doi.org/10.1016/j.jmrt.2021.10.095

    Article  CAS  Google Scholar 

  13. X. Lai, J. Hu, T. Ruan, J. Zhou, J. Qu, Carbohydr. Polym. 265, 118074 (2021). https://doi.org/10.1016/j.carbpol.2021.118074

    Article  CAS  PubMed  Google Scholar 

  14. A. Fateh, M. Aliofkhazraei, A.R. Rezvanian, Arab. J. Chem. 13, 481 (2020). https://doi.org/10.1016/j.arabjc.2017.05.021

    Article  CAS  Google Scholar 

  15. X. Zhang, W. Li, G. Yu, X. Zuo, W. Luo, J. Zhang, B. Tan, A. Fu, S. Zhang, J. Mol. Liq. 318, 114080 (2020). https://doi.org/10.1016/j.molliq.2020.114080

    Article  CAS  Google Scholar 

  16. M. Rizvi, H. Gerengi, S. Kaya, I. Uygur, M. Yıldız, I. Sarıoglu, Z. Cingiz, M. Mielniczek, B. El Ibrahimi, Sci. Rep. 11, 1 (2021). https://doi.org/10.1038/s41598-021-87858-9

    Article  CAS  Google Scholar 

  17. M.A. Amin, K.F. Khaled, Corros. Sci. (2010). https://doi.org/10.1016/j.corsci.2009.12.035

    Article  Google Scholar 

  18. S. Pareek, D. Jain, S. Hussain, A. Biswas, R. Shrivastava, S.K. Parida, H.K. Kisan, H. Lgaz, I.M. Chung, D. Behera, J. Chem. Eng. 358, 725 (2019). https://doi.org/10.1016/j.cej.2018.08.079

    Article  CAS  Google Scholar 

  19. H.L. Sin, A.A. Rahim, C.Y. Gan, B. Saad, M.I. Salleh, M. Umeda, Measurement 109, 334 (2017). https://doi.org/10.1016/j.measurement.2017.05.045

    Article  Google Scholar 

  20. R. Farahati, A. Ghaffarinejad, S.M. Mousavi-Khoshdel, J. Rezania, H. Behzadi, A. Shockravi, Prog. Org. Coat. 132, 417 (2019). https://doi.org/10.1016/j.porgcoat.2019.04.005

    Article  CAS  Google Scholar 

  21. K.F. Khaled, Corros. Sci. 52, 3225 (2010). https://doi.org/10.1016/j.corsci.2010.01.019

    Article  CAS  Google Scholar 

  22. W. Guo, M. Talha, Y. Lin, X. Kong, Colloids Surf. A Physicochem. Eng. Asp. 615, 126234 (2021). https://doi.org/10.1016/j.colsurfa.2021.126234

    Article  CAS  Google Scholar 

  23. A. Handy, N.S. El-Gendy, Egypt. J. Pet. 22, 17 (2013). https://doi.org/10.1016/j.ejpe.2012.06.002

    Article  Google Scholar 

  24. H. Khoshsang, A. Ghaffarinejad, CDC. 37, 100799 (2022). https://doi.org/10.1016/j.cdc.2021.100799

    Article  CAS  Google Scholar 

  25. F.S. de Souza, A. Spinelli, Corros. Sci. 51, 642 (2009). https://doi.org/10.1016/j.corsci.2008.12.013

    Article  CAS  Google Scholar 

  26. O.A. Akinbulumo, O.J. Odejobi, E.L. Odekanle, Results Mater. 5, 100074 (2020). https://doi.org/10.1016/j.rinma.2020.100074

    Article  Google Scholar 

  27. M.H. Fekri, F. Omidali, M.M. Alemnezhad, A. Ghaffarinejad, Mater. Chem. Phys. 286, 126150 (2022). https://doi.org/10.1016/j.matchemphys.2022.126150

    Article  CAS  Google Scholar 

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Acknowledgements

The authors gratefully acknowledge the partial support of this work from the Research Council of the Iran University of Science and Technology.

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Authors and Affiliations

  1. Research Laboratory of Real Samples Analysis, Faculty of Chemistry, Iran University of Science and Technology (IUST), Tehran, 1684613114, Iran

    Mojtaba Askari & Ali Ghaffarinejad

  2. Electroanalytical Chemistry Research Center, Iran University of Science and Technology (IUST), Tehran, 1684613114, Iran

    Ali Ghaffarinejad

Authors
  1. Mojtaba Askari
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  2. Ali Ghaffarinejad
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Contributions

MA: formal analysis, writing—original draft. AG: supervision, project administration, funding acquisition, writing—review and editing.

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Correspondence to Ali Ghaffarinejad.

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Askari, M., Ghaffarinejad, A. Copper corrosion prevention in 3.5% NaCl solution by Spartium junceum petals extract as an eco-friendly bio-inhibitor: kinetic and thermodynamic studies. ANAL. SCI. 39, 1967–1979 (2023). https://doi.org/10.1007/s44211-023-00407-4

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