Abstract
Glucuronoxylans have been considered as an alternative polymer for petroleum polymers in coatings, films, emulsifiers, and other industries. In this study, different molecule weight glucuronoxylans were obtained through xylanase hydrolysis. Dodecenyl succinic anhydride (DDSA) was used as a modifying agent to functionalize glucuronoxylans. At the same degree of substitution (DS), higher molecule weight glucuronoxylans led to better emulsifying properties and emulsion stability. Higher molecule weight DDSA modified glucuronoxylans showed smaller droplets size, lower zeta potential, higher EA (emulsifying activity) and better emulsion stability. These results suggested that molecule weight has positive impact on the emulsifying properties of DDSA modified glucuronoxylans. Furthermore, DS had positive impact on the emulsifying properties of DDSA modified glucuronoxylans.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: 21904053
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Research ethics: The local Institutional Review Board deemed the study exempt from review.
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Author contributions: Zhenhua Hu, Yushen Liu: investigation, resources, writing-original draft; Zhouyang Xiang: formal analysis, supervision, writing-original draft; Lulaing Wang, Shengdan Wang, Xiaotong Fan: supervision. All authors reviewed the manuscript. The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Competing interests: The authors state no conflicts of interest.
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Research funding: This work was supported by the National Natural Science Foundation of China (21904053) and the Foundation (no. KF202106) of Key Laboratory of Pulp and Paper Science & Technology of Ministry of Education, Qilu University of Technology (Shandong Academy of Sciences).
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Data availability: The raw data can be obtained from the corresponding author on reasonable request.
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