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Crystal Structures of Two Metal-Organic Frameworks Based on Zn(II) and 2,5-Diiodoterephthalate

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Abstract

Three-dimensional coordination polymers Cat2[{Zn4O}2(H2O)2(2,5-I-bdc)7] (1) (2,5-I-bdc = 2,5-diiodoterephthalate, Cat is dimethylammonium) and [Zn2(2,5-I-bdc)2dabco] (2) (dabco is 1,4-diazobicyclo [2.2.2]octane) are prepared. The structures of 1 and 2 are determined by single crystal X-ray diffraction. It is shown that the structure of 2 has a halogen bond between guest DMF molecules and the MOF iodine atom. The I⋯O distances are 2.93-3.03 Å.

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Funding

The work was supported by the Russian Science Foundation (Project No. 21-73-20019) and the Ministry of Science and Higher Education of the Russian Federation (structural characterization of the samples, 121031700313-8).

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. S. Zaguzin, M. A. Bondarenko, T. S. Sukhikh, V. P. Fedin & S. A. Adonin

  2. South Ural State University, Chelyabinsk, Russia

    A. S. Zaguzin, M. A. Bondarenko & S. A. Adonin

  3. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    S. A. Adonin

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  1. A. S. Zaguzin
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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 11, 118589.https://doi.org/10.26902/JSC_id118589

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Zaguzin, A.S., Bondarenko, M.A., Sukhikh, T.S. et al. Crystal Structures of Two Metal-Organic Frameworks Based on Zn(II) and 2,5-Diiodoterephthalate. J Struct Chem 64, 2157–2166 (2023). https://doi.org/10.1134/S0022476623110136

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