Abstract
The effects of power, holding time, Na2CO3, and CaO addition on Si utilization and Al loss rate in hypoeutectic Al-Si alloy prepared by diamond wire saw silicon powder (DWSSP) were investigated. It is found that the appropriate heating power is beneficial to improve the utilization rate of DWSSP and the quality of the alloy, while improper heating power leads to the loss of furnace feed and the increase of power consumption. Insufficient holding time, resulting in an increase in impurities in the alloy, which seriously affects the quality of the alloy. Prolonging the holding time causes excessive energy consumption and increased aluminum loss. Na2CO3 can improve the utilization rate of Si in DWSSP, excessive Na2CO3 can induce an increase in aluminum loss and the appearance of bubbles in the alloy. Appropriate addition of CaO can effectively remove impurities and increase the content of Si and Al in the alloy, but excessive CaO leads to the decrease of Si utilization rate, the increase of Al utilization rate, and the enrichment of Ca impurities. When the condition of heating power of 10 kW, holding time of 45 min, and adding 10% CaO + 10% Na2CO3, the utilization rate of silicon is 62.45%, and the loss rate of aluminum is 45.10%.
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Janet Xuanli Liao (2008) China and the global energy crisis: development and prospects for China’s oil and natural gas Tatsu Kambara Christopher Howe. China J 59:211–212
Hecini M, Drouiche N, Bouchelaghem O (2016) Recovery of cutting fluids used in polycrystalline silicon ingot slicing. J Cryst Growth 2016(453):143–150
Miki S, Iio N, Taniguchi S, Satone H, Arafune K (2012) Filtration of waste coolant from fixed-abrasive wire sawing and recycle of retrieved silicon powder for feedstock. 2012 38th IEEE photovoltaic specialists conference, Texas (USA), pp 2716–2719
Provent E, Briz´e V, Drevet B, Coustier F, Flahaut E (2011) Diamond wire slicing: towards silicon kerf recycling. Proceedings of the 26th European photovoltaic solar energy conference, Hamburg (German), pp 1965–1968
The global photovoltaic installed capacity is 220GW, and China is expected to add 75GW in 2022. The World of Inverter (2022) 3: 36–39
Chou C, Kuo J, Yen S (2018) Silicon-based composite negative electrode prepared from recycled silicon-slicing slurries and lignin/lignocellulose for Li-ion cells. ACS Sustain Chem Eng 6:4759–4766
Huang T, Selvaraj B, Lin H, Sheu H, Song Y, Wang C, Hwang B, Wu N (2016) Exploring an interesting Si source from photovoltaic industry waste and engineering it as a Li-ion battery high-capacity anode. ACS Sustain Chem Eng 4(10):5769–5775
Wurzner S, Herms M, Kaden T, Moller H, Wagner M (2017) 2017 Characterization of the diamond wire sawing process for monocrystalline silicon by Raman spectroscopy and SIREX polarimetry. Energies 10:414
Yang S, Wang X, Wei K, Ma W, Wang Z (2020) Novel reaction media of Na2CO3−CaO for silicon extraction and aluminum removal from diamond wire saw silicon powder by roasting−smelting proces. ACS Sustain Chem Eng 8:4246–4157
Yang S, Ma W, Wei K, Xie K, Wang Z (2019) Thermodynamic analysis and experimental verification for silicon recovery from the diamond wire saw silicon powder by vacuum carbothermal reduction. Sep Purif Technol 228:115754
Yang S, Wang X, Wei K, Xie K, Ma W, Wang Z (2020) Dissolution and mineralization behavior of metallic impurity content in diamond wire saw silicon powder during acid leaching. J Clean Prod 248:119256
Xiao T, Lv G, Wang J, Yang X, Ma W (2020) Thermodynamic and kinetic analysis of the process of preparing Al–Si alloy from polysilicon cutting waste by diamond-wire. Chin J Process Eng 20:1190–1197
Wei D, Kong J, Gao S, Zhou S, Zhuang Y, Xing P (2021) Preparation of Al–Si alloys with silicon cutting waste from diamond wire sawing process. J Environ Manage 290:112548
Wei D, Kong J, Gao S, Zhou S, Jin X, Jiang S, Zhuang Y, Du X, Xing P (2020) Recycling of silicon from silicon cutting waste by Al–Si alloying in cryolite media and its mechanism analysis. Environ Pollut 265:114892
Wei D, Gao S, Kong J, Jin X, Jiang S, Zhou S, Zhuang Y, Yin H, Xing P (2020) Recycling silicon from silicon cutting waste by Al–Si alloying. J Clean Prod 265:119647
Yang H, Liu I, Liu C, Hsu HP, Lan C (2019) Recycling and reuse of kerf-loss silicon from diamond wire sawing for photovoltaic industry. Waste Manage 84:204–210
Wang J, Xing P, Du X, Luo X, Zhuang Y, Lyu T, Dong X (2017) Kinetics analysis and effects of various factors on removing iron from silica sand under ultrasound-assistance. SILICON 9:265–272
Wang X, Srinivasakannan C, Duan X, Peng J, Yang D, Jun S (2013) Leaching kinetics of zinc residues augmented with ultrasound. Sep Purif Technol 115:66–72
Xia G, Lu M, Su X, Zhao X (2012) Iron removal from kaolin using thiourea assisted by ultrasonic wave. Ultrason Sonochem 19:38–42
Kong J, Xing P, Wei D, Jin X, Zhuang Y (2021) Ultrasound-assisted leaching of iron from silicon diamond-wire saw cutting waste. JOM 73:791–800
Srinivasan S, Kottam V (2018) Solar photovoltaic module production: environmental footprint, management horizons and investor goodwill. Renew Sustain Energy Rev 81:874–882
Minguel V, Tandeep S, Gregory Y, Pratim B (2017) Solar photovoltaic module production: environmental footprint, management horizons and investor goodwill. Sci Rep 7:405335
Yoshikawa T, Morita K (2012) An evolving method for solar-grade silicon production: solvent refining. JOM 64:946–951
Yoshikawa T, Morita K (2005) Refining of Si by the solidification of Si–Al melt with electromagnetic force. ISIJ Int 45:967–971
Xue H, Lv G, Ma W, Chen D, Yu J (2015) Separation mechanism of primary silicon from hypereutectic Al–Si melts under alternating electromagnetic fields. Metall Mat Trans 46:2922–2932
Ren Y, Chen H, Ma W, Lei Y, Zeng Y (2021) Purification of aluminum–silicon alloy by electromagnetic directional solidification: degassing and grain refinement. Sep Purif Technol 277:119459
Wei K, Ma W, Yang B, Liu D, Dai Y, Morita K (2011) Study on volatilization rate of silicon in multi-crystalline silicon preparation from metallurgical grade silicon. Vacuum 85:749–754
Huang P, Ma W, Wei K, Li S, Morita K (2013) A model for distribution of aluminum in silicon refined by vacuum directional solidification. Vacuum 96:12–17
Ma X, Lei Y, Yoshikawa T, Zhao B, Morita K (2015) Effect of solidification conditions on the silicon growth and refining using Si–Sn melt. J Cryst Growth 430:98–102
Yang X (2021) Preparation of Al–Si alloy from crystalline silicon diamond wire cutting waste. Kunming University of Science and Technology
Funding
The authors are grateful to the financial support by the National Natural Science Foundation of China (No. 22268027), Key Research and Development Project of Yunnan Province (No. 202002AB080030 and No. 202103AA080003), and Major Science and Technology Projects in Yunnan Province (No. 202202AG050012).
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Zhang, R., Gui, C., Lei, Y. et al. Study on Preparation of Hypoeutectic Al–Si Alloy from Diamond Wire Saw Silicon Powder by Electromagnetic Method. J. Sustain. Metall. 10, 41–54 (2024). https://doi.org/10.1007/s40831-023-00768-0
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DOI: https://doi.org/10.1007/s40831-023-00768-0