Skip to main content
Log in

Investigation of the Destruction of Lubricating Layers of Sulfonate Greases under Friction and Corrosion

  • Published:
Journal of Friction and Wear Aims and scope Submit manuscript

Abstract

To study such characteristics of sulfonate greases as the lubricity during friction of solids in the mode of boundary lubrication and the protective properties of these lubricants in corrosive environments. A common requirement for the implementation of these indicators is the formation of strong lubricating layers that protect the surfaces of parts from destruction. For each of the studied sulfonate greases with various thickeners and dispersion media, based on the analysis of experimental temperature dependences of the friction coefficients in the temperature range of 30–300°C, the values of the activation energies of the boundary layers destruction were calculated, and the values of Тcm were estimated. The conducted research has shown that for the examined sulfonate greases, there is a qualitative correlation between the values of temperature-energy criterion πD with the experimentally obtained values of the corrosion rates of the steel surface in a corrosive environment under the films of sulfonate greases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

REFERENCES

  1. Spirkin, V.G., Fuchs, I.G., Tatur, I.R., et al., Khimmotologiya. Svoistva i primenenie topliv, smazochnykh i spetsial’nykh materialov (Chemmotology. Properties and Application of Fuels, Lubricants, and Special Materials, Part 2), Moscow: RGU Nefti Gaza, 2014.

  2. Lugt, P.M., Modern advancements in lubricating grease technology, Tribol. Int., 2016, vol. 97, pp. 467–477.

    Article  Google Scholar 

  3. Lubricants and Lubrication, Mang, T. and Dresel, W., Eds., New York: Wiley, 2018.

    Google Scholar 

  4. Fan, X., Li, W., Li, H., et al., Probing the effect of thickener on tribological properties of lubricating greases, Tribol. Int., 2018, vol. 118, p. 128.

    Article  Google Scholar 

  5. Wei, L., Rheologically stable calcium sulfonate grease - a case study that leads to novel calcium sulfonate and polyurea grease blends, NLGI Spokesman, 2020, vol. 84, no. 2, pp. 20–26.

    ADS  Google Scholar 

  6. Chuck, Coe, The lithium crisis for the grease industry, NLGI Spokesman, 2022, vol. 86, no. 1, pp. 39–46.

    Google Scholar 

  7. Mackwood, W., Calcium sulfonate complex greases, Tribol. Lubric. Technol., 2016, vol. 72, no. 10, p. 28.

    Google Scholar 

  8. Wang, Z., Xia, Y., and Liu, Z., The rheological and tribological properties of calcium sulfonatecomplex greases, Friction, 2015, vol. 3, no. 1, pp. 28–35.

    Article  Google Scholar 

  9. Bosman, R. and Lugt, P.M., The microstructure of calcium sulfonate complex lubricating grease and its change in the presence of water, Tribol. Trans., 2018, vol. 61, no. 5, p. 842.

    Article  Google Scholar 

  10. Zhou, Y., Bosman, R., and Lugt, P.M., On the shear stability of dry and water-contaminated calcium sulfonatecomplex lubricating greases, Tribol. Trans., 2019, vol. 62, no. 4, pp. 626–634.

    Article  Google Scholar 

  11. Buyanovskii, I.A., The kinetic characteristics of tribochemical processes under boundary lubrication estimation, Trenie Smazka Mash. Mekhanizm., 2006, no. 12, pp. 22–26.

  12. Drozdov, Yu.N., Wear prediction taking into account mechanical, physico-chemical and geometric factors, in Sovremennaya tribologiya: Itogi i perspektivy (Modern Tribology: Results and Prospects), Frolov, K.V., Ed., Moscow: LKI, 2008, pp. 24–32.

  13. Zhornik, V.I., Ivakhnik, A.V., Ivakhnik, V.P., and Zapolsky, A.V., Structure and properties of complex calcium sulfonate lubricant, Materialoved. Mashinostr., 2018, vol. 42, no. 1, p. 44.40.

  14. Anisimova, A.A., Investigation of the effect of additives on the properties of sulfonate lubricants, Cand. Sci. (Tech. Sci.) Dissertation, Moscow: Gubkin Russ. State Univ. Oil Gas, 2018.

  15. Samusenko, V.D., Strelnikova, S.S., Peskovets, A.V., Buyanovskii, I.A., Tatur, I.R., and Kal’yanova, O.A., Temperature resistance of greases thickened with calcium sulfonates, J. Mach. Manuf. Reliab., 2022, vol. 51, no. 5, pp. 488–493.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to I. A. Buyanovskii.

Ethics declarations

The authors declare that they have no conflicts of interest.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Buyanovskii, I.A., Tatur, I.R., Strelnikova, S.S. et al. Investigation of the Destruction of Lubricating Layers of Sulfonate Greases under Friction and Corrosion. J. Frict. Wear 44, 229–233 (2023). https://doi.org/10.3103/S1068366623040049

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068366623040049

Keywords:

Navigation