Abstract
The use of synthetic single used plastic packaging and mulching films has serious environmental effects due to their non-degradable waste causing pollution. To replace these synthetic materials, high-strength biodegradable polymer composites of Pectin, Luffa Fiber (agro-waste) and Glycerol are synthesized by the solvent casting technique using a universal solvent. The experimentation is carried out using a 3 × 3 factorial design and the tensile behavior (tensile strength and elongation) of composites is analyzed by response surface methodology (RSM). The tensile strength of pectin containing 10% glycerol is 11.48 MPa which is increased to 19.34 MPa by incorporation of 15% luffa fiber and this composition is optimized with desirability index method (simultaneously optimization) to achieve the best results for elongation at break (188.89%) as well. The interactions between constituents of composites are characterized by FTIR spectro-scopy and scanning electron microscopic study reveals a uniform distribution of fiber. The composites have sustained thermal stability as all composites are stable up to 260°C in an inert atmosphere under TGA study. The biodegradability of composite films was observed by soil burial method and found completely degradable in 75 days. The present composites of non-toxic components with high tensile properties, sustained thermal stability and complete biodegradability are suitable for green packaging applications.
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REFERENCES
S. B. Obebe and A. A. Adamu, Int. J. Eng. Appl. Sci. Technol. 4, 85 (2020).
D. Xanthos and T. R. Walker, Mar. Pollut. Bull. 118, 17 (2017).
M. M. Altayan and T. A. l. Darouich, Polym. Sci., Ser. B 63, 152(2021).
M. Menossi, M. Cisneros, V. A. Alvarez and C. Casalongué, Agron. Sustainable Dev. 41, 53 (2021).
Y. Yang, Z. Li, C. Yan, D. Chadwick, D. L. Jones, E. Liu, Q. Liu, R. Bai, and W. He, Sci. Total Environ. 814, 152572 (2022).
M. Teodorescu, M. Bercea, and S. Morariu, Polym. Rev. 58, 247 (2018).
S. Patra, K. L. Mohanta, and C. Parida, Mod. Phys. Lett. B 34, 2150009 (2020).
Masturi, W. N. Jannah, R. M. Maulana, T. Darsono, Sunarno, and S. Rustad, Adv. Compos. Lett. 29, 2633366X2096250 (2020). https://doi.org/10.1177/2633366X20962507
E. A. Arlakova, I.V. Zubrov, A. M. Bochek, N. N. Saprykina, E. M. Ivan’kova, V. K. Lavrent’ev. and V. E. Yudin, Polym. Sci., Ser. B 65, 144 (2023).
S. Lal, V. Kumar, G. Jagdeva, S. Arora, P. Kumar, K. Gulati, and O. Singh, J. Appl. Polym. Sci. 139, 52232 (2022).
N. Mebarki, H. Ziane, F. Fazouane, and M. Nabiev, Iran. Polym. J. 31, 301 (2022).
M. A. López-Mata, M. Gastelum-Cabrera, E. Valbuena-Gregorio, P. B. Zamudio-Flores, S. E. Burruel-Ibarra, G. G. Morales-Figueroa, L. Quihui-Cota, and J. E. Juarez-Onofre, Iran. Polym. J. 27, 545 (2018).
T. P. Singh, G. Chauhan, R. K. Agrawal, and S. K. Mendiratta, Iran. Polym. J. 27, 861 (2018).
R. Bana and A. K. Banthia, Polym. Plast. Technol. Eng. 46, 821 (2007).
S. M. Davachi, S. Bakhtiari, P. Pouresmaeel-Selakjani, J. Mohammadi-Rovshandeh, B. Kaffashi, S. Davoodi, and A. Yousefi, Adv. Polym. Technol. 37, 5 (2018).
S. Tabasum, M. Younas, M. A. Zaeem, I. Majeed, M. Majeed, A. Noreen, M. N. Iqbal, and K. M. Zia, Int. J. Biol. Macromol. 122, 969 (2019).
J. Huang, Z. Hu, L. Hu, G. Li, Q. Yao, and Y. Hu, Trends Food Sci. Technol. 118, 167 (2021).
C. V. L. Giosafatto, P. Di Pierro, P. Gunning, A. Mackie, R. Porta, and L. Mariniello, Carbohydr. Polym. 106, 200 (2014).
R. Priyadarshi, S. M. Kim and J. W. Rhim, Food Chem. 347, 129022 (2021).
S. Padma Ishwarya, R. Sandhya, and P. Nisha, Crit. Rev. Food Sci. Nutr. 62, 4393 (2021).
V. O. A. Tanobe, T. H. D. Sydenstricker, M. Munaro and S. C. Amico, Polym. Test. 24, 474 (2005).
S. Arora, S. Lal, S. Kumar, M. Kumar, and M. Kumar, Arch. Appl. Sci. Res. 3, 188 (2011).
R. Sa-Ad, Y. Sasithornsonti, and P. Phinyocheep, Carbohydr. Polym. 89, 251 (2012).
J. Aburto, M. Moran, A. Galano, and E. Torres-García, J. Anal. Appl. Pyrolysis 112, 94 (2015).
J. B. Dahiya, K. Kumar, M. Muller-Hagedorn, and H. Bockhorn, Polym. Int. 57, 722 (2008).
M. Asim, M. T. Paridah, M. Chandrasekar, R. M. Shahroze, M. Jawaid, M. Nasir, and R. Siakeng, Iran. Polym. J. 29, 625 (2020).
Y. Jiugao, W. Ning, and M. Xiaofei, Starch-Stärke 57, 494 (2005).
ACKNOWLEDGMENTS
Acknowledgment is also due to Chairperson, Chemistry Department, Kurukshetra University, Kurukshetra for providing necessary laboratory facilities.
Funding
Financial support from the Council of Scientific and Industrial Research (CSIR), New Delhi as Senior Research Fellowship to Mr. Vinod Kumar (Grant no. 09/105(0234)/2016-EMR-I) is gratefully acknowledged.
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Vinod Kumar, Lal, S., Kumar, S. et al. Preparation of Ecofriendly Viable Packaging Films Based on Pectin and Agro-Waste: Thermal and Mechanical Studies by Design of Experiments Approach. Polym. Sci. Ser. A 65, 557–567 (2023). https://doi.org/10.1134/S0965545X23600448
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DOI: https://doi.org/10.1134/S0965545X23600448