Abstract
The main reasons for the promoting effect of phosphorus on the properties of Pd–P/ZSM-5 catalysts during direct synthesis of H2O2 from H2 and O2 under mild conditions are considered based on the data obtained by X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), and inductively coupled plasma mass spectrometry (ICP MS). The introduction of phosphorus in the catalyst affects the particle size and the electronic state of palladium in the surface layer, as well as the surface concentration of the phosphate and phosphite ions. The yield of H2O2 increases when the particle size of the Pd–P catalysts decreases, when the side process of H2O2 decomposition is inhibited by the phosphate and phosphite surface ions, and when the hydrogen solubility in the solid solutions of phosphorus in palladium decreases.
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REFERENCES
Menegazzo, F., Signoretto, M., Ghedini, E., and Strukul, G., Catalysts, 2019, vol. 9, no. 3, p. 251.
Blanco-Brieva, G., Desmedt, F., Miquel, P., Campos-Martin, J.M., and Fierro, J.L.G., Catalysts, 2022, vol. 12, p. 796.
Lewis, R.J., Koy, M., Macino, M., Das, M., Carter, J.H., Morgan, D.J., Davies, T.E., Ernst, J.B., Freakley, S.J., Glorius, F., and Hutchings, G.J., J. Am. Chem. Soc., 2022, vol. 144, p. 15431.
Barnes, A., Lewis, R.J., Morgan, D.J., Davies, T.E., and Hutchings, G.J., Catal. Sci. Technol., 2022, vol. 12, p. 1986.
Wang, S., Gao, K., Li, W., and Zhang, J., Appl. Catal. A: Gen., 2017, vol. 531, p. 89.
Deguchi, T., Yamano, H., Takenouchi, S., and Iwamoto, M., Catal. Sci. Technol., 2018, vol. 8, p. 1002.
Yoon, J., Han, G.-H., Lee, M.W., Lee, S.-H., Lee, S.H., and Lee, K.-Y., Appl. Surf. Sci., 2022, vol. 604, p. 154464.
Shi, Y., Elnabawy, A.O., Gilroy, K.D., Hood, Z.D., Chen, R., Wang, C., Mavrikakis, M., and Xia, Y., ChemCatChem, 2022, vol. 14, p. e202200475.
Blanco-Brieva, G., Montiel-Argaiz, M., Desmedt, F., Miquel, P., Campos-Martin, J.M., and Fierro, G.J.L., Top. Catal., 2017, vol. 60, p. 1151.
Han, G.H., Lee, S.H., Hwang, S.Y., and Lee, K.Y., Adv. Energy Mater., 2021, vol. 11, no. 27, p. 2003121.
Chen, L., Medlin, J.W., and Gronbeck, H., ACS Catal., 2021, vol. 11, p. 2735.
Liu, Y., McCue, A.J., and Li, D., ACS Catal., 2021, vol. 11, p. 9102.
Van, Ya., Nuzhdin, A.L., Shamanaev, I.V., and Bukhtiyarova, G.A., Kinet. Katal., 2022, vol. 63, no. 6, p. 743.
Zhurenok, A.V., Markovskaya, D.V., Potapenko, K.O., Cherepanova, S.V., Saraev, A.A., Gerasimov, E.Yu., and Kozlova, E.A., Kinet. Katal., 2022, vol. 63, no. 3, p. 294.
Belykh, L.B., Skripov, N.I., Sterenchuk, T.P., Kornaukhova, T.A., Milenkaya, E.A., and Schmidt, F.K., Mol. Catal., 2022, vol. 528, p. 112509.
Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York: Wiley, 1972.
Matthews, J.C., Nashua, N.H., and Wood, L.L., US Patent 3.474.464, 1969.
Skripov, N.I., Belykh, L.B., Sterenchuk, T.P., Kornaukhova, T.A., Milenkaya, E.A., and Schmidt, F.K., Kinet. Catal., 2022, vol. 63, no. 2, p. 197.
Yu, S., Cheng, X., Wang, Y., Xiao, B., Xing, Y., Ren, J., Lu, Y., Li, H., Zhuang, H., and Chen, G., Nat. Commun., 2022, vol. 13, p. 4737.
Hu, B., Deng, W., Li, R., Zhang, Q., Wang, Y., Delplanque-Janssens, F., Paul, F., Desmedt, F., and Miquel, P., J. Catal., 2014, vol. 319, p. 15.
Liang, W., Fu, J., Chen, H., Zhang, X., and Deng, G., Mater. Lett., 2021, vol. 283, p. 128857.
Smirnov, M.Yu., Kalinkin, A.V., Simonov, P.A., and Bukhtiyarov, V.I., Kinet. Katal., 2022, vol. 63, no. 5, p. 602.
Lou, Y., Ma, J., Hu, W., Dai, Q., Wang, L., Zhan, W., Guo, Y., Cao, X.-M., Guo, X.-M., Hu, P., and Lu, G., ACS Catal., 2016, vol. 6, no. 12, p. 8127.
Ustyugov A.V., Korypaeva V.V., Obeidat Z.Z., Putin A.Yu., Shvarts A.L., Bruk L.G., Kinet. Katal., 2022, vol. 63, no. 2, p. 258.
Belykh, L.B., Sterenchuk, T.P., Skripov, N.I., Akimov, V.V., Tauson, V.L., Romanchenko, A.S., Gvozdovskaya, K.L., Sanzhieva, S.B., and Shmidt, F.K., Kinet. Catal., 2019, vol. 60, no. 6, p. 808.
Lei, J., Niu, R., Wang, S., and Li, J., Solid State Sci., 2020, vol. 101, p. 106097.
Gabasch, H., Unterberger, W., Hayek, K., Klotzer, B., Kleimenov, E., Teschner, D., Zafeiratos, S., Havecker, M., Knop-Gericke, A., Schlog, R., Han, J., Ribeiro, F.H., Aszalos-Kiss, B., Curtin, T., and Zemlyanov, D., Surf. Sci., 2006, vol. 600, p. 2980.
Wu, T., Kaden, W.E., Kunkel, W.A., and Anderson, S.L., Surf. Sci., 2009, vol. 603, p. 2764.
Koyano, G., Yokoyama, S., and Misono, M., Appl. Catal. A: Gen., 1999, vol. 188, p. 301.
Akolekar, D.B. and Bhargava, S.K., J. Mol. Catal. A: Chem., 2005, vol. 236, p. 77.
Belykh L.B., Skripov N.I., Akimov V.V., Tauson V.L., Stepanova T.P., Shmidt F.K., Russ. J. Gen. Chem., 2013, vol. 83, no. 12, p. 1974.
Neyyathala, A., Flecken, F., and Hanf, S., ChemPlusChem, 2023, vol. 88, p. e202200431.
Xiong, R., Zhao, W., Wang, Z., and Zhang, M., Mol. Catal., 2021, vol. 500, p. 111332.
Skripov, N.I., Belykh, L.B., Belonogova, L.N., Umanets, V.A., Ryzhkovich, E.N., and Schmidt, F.K., Kinet. Catal., 2010, vol. 51, no. 5, p. 714.
Khoshkhoo, M.S., Scudino, S., Thomas, J., Gemming, T., Wendrock, H., and Eckert, J., Mater. Lett., 2013, vol. 108, p. 343.
Lewis, R.J. and Hutchings, G.J., ChemCatChem, 2019, vol. 11, p. 298.
Cao, K., Yang, H., Bai, S., Xu, Y., Yang, C., Wu, Y., Xie, M., Cheng, T., Shao, Q., and Huang, X., ACS Catal. 2021, vol. 11, p. 1106.
Jeong, H.E., Kim, S., Seo, M.-G., Lee, D.-W., and Lee, K.-Y., J. Mol. Catal. A: Chem. 2016, vol. 420, p. 88.
Adams, J.S., Kromer, M.L., Rodríguez-López, J., and Flaherty, D.W., J. Am. Chem. Soc. 2021, vol. 143, p. 7940.
Chen, L., Medlin, J.W., Gronbeck, H., ACS Catal., 2021, vol. 11, p. 2735.
Deschner, B.J., Doronkin, D.E., Sheppard, T.L., Zimina, A., Grunwaldt, J.-D., and Dittmeyer, R., J. Phys. Chem. C, 2021, vol. 125, p. 3451.
Flanagan, B.T.B., Biehl, G.E., Clewley, J.D., Kundqvist, S., and Anderson, Y., J.C.S. Faraday I, 1980, vol. 76, p. 196.
ACKNOWLEDGMENTS
This study was performed using the equipment of the Multiaccess Center of Irkutsk State University, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences (PHOIBOS 150 MCD 9 photoelectronic spectrometer); Baikal Center for Nanotechnology, Irkutsk National Research Technical University (Tecnai G2 electron microscope); and Multiaccess Center for Isotope Geochemical Research (ELEMENT 2 high-resolution mass spectrometer). The zeolite Na-ZSM-5 was provided by S.A. Skornikova.
Funding
The study was supported by the Russian Science Foundation (grant no. 22-23-00836, https://rscf.ru/project/22-23-00836/).
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Translated by L. Smolina
Abbreviations and notation: XPS is X-ray photoelectron spectroscopy; XRD, X-ray diffraction analysis; HRTEM, high-resolution transmission electron microscopy; ICP MS, inductively coupled plasma mass spectrometry; FWHM is the full width at half maximum of spectral lines; DMF, N,N-dimethylformamide; CSR, coherent scattering region; Eb, binding energy; dPd, the average size of palladium particles; a, activity; S, selectivity; and TOF, turnover frequency of reaction.
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Belykh, L.B., Skripov, N.I., Sterenchuk, T.P. et al. The First Application of Palladium–Phosphorus Catalysts in the Direct Synthesis of Hydrogen Peroxide: Reasons for the Promoting Action of Phosphorus. Kinet Catal 64, 804–814 (2023). https://doi.org/10.1134/S0023158423060022
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DOI: https://doi.org/10.1134/S0023158423060022