Abstract
New complexes of [5,10,15,20-tetra-(4-methoxyphenyl)porphinato](chloro)indium(III) ((Cl)InTPP(p-OCH3)4) with unsubstituted C60 and 1-methyl-2-(pyridin-4'-yl)-3,4- fullero[60]pyrrolidine (PyC60) were synthesized in toluene. The stability constants of 1 : 1 complexes (dyads) were determined using UV-vis and fluorescence spectroscopy. The dyads were characterized by IR and 1H NMR spectroscopy data. It was established that fluorescence of (Cl)InTPP(p-OCH3)4 is quenched upon gradual addition of fullerenes. The numerical values of the Stern–Volmer quenching constants (KSV) were determined. The most important charge transfer characteristics of dyads (the lifetime of charge-separated states and charge separation and recombination constants), needed for further consideration of dyads based on indium(III) porphyrins as photoinduced electron transfer systems, were determined using femtosecond laser spectroscopy.
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ACKNOWLEDGMENTS
The authors are grateful to Professor, Doctor of Chemical Sciences, V.A. Nadtochenko, Candidate of Chemical Sciences, I.V. Shelaev, and F.E. Gostev for performing femtosecond laser spectroscopy investigations. This study was carried out using equipment of the N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, (nos. 1440743, 506694) (Moscow) and the Center for Collective Use of Research Equipment, Upper Volga Regional Centre of Physicochemical Research.
Funding
This study was supported by the Russian Science Foundation (grant no. 21-73-20090).
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Ovchenkova, E.N., Bichan, N.G. & Lomova, T.N. Synthesis, Chemical Structure, and Ground- and Excited-State Spectral Characteristics of (Porphyrinato)(chloro)indium(III) and Its Complexes with C60 and Pyridyl-Substituted Fullero[60]pyrrolidine. Russ. J. Inorg. Chem. 68, 1562–1570 (2023). https://doi.org/10.1134/S0036023623601940
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DOI: https://doi.org/10.1134/S0036023623601940