Skip to main content
SpringerLink
Log in

Effect of Bridging Group Nature on the Extraction Ability of Diphenylphosphorylketones toward Actinides and Lanthanides

  • PHYSICOCHEMISTRY OF SOLUTIONS
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Effect of structure of phosphorylketones containing flexible alkyl and conformationally rigid fragments in the linker on extraction ability toward actinides and lanthanides has been studied. It has been shown that the introduction of conformationally rigid cycloalkanediyl and alkenediyl fragments in the bridge between P=O and C=O groups in the structure of molecule decreases efficiency of extractants for both actinides and lanthanides. At the same time, the introduction of flexible alkyl groups in linker structure increases complexing and extraction ability. This dependence has been explained theoretically by modeling complexation (DFT, PBE, cc-pVDZ), monodentate coordination was observed for all studied phosphorylalkanones

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

REFERENCES

  1. Assessment of Partitioning Processes for Transmutation of Actinides IAEA (Vienna, 2010, IAEA-TECDOC-1648).

  2. B. Ya. Zil’berman, E. A. Puzikov, D. V. Ryabkov, et al., At. Energy 107, 333 (2009). https://doi.org/10.1007/s10512-010-9233-z

    Article  CAS  Google Scholar 

  3. Ion Exchange and Solvent Extraction: A Series of Advances, Ed. by B. A. Moyer (CRC Press, New York, 2010).

    Google Scholar 

  4. A. M. Rozen, Ros. Khim. Zh. 40, 42 (1996).

    CAS  Google Scholar 

  5. T. A. Mastryukova, O. I. Artyushin, I. L. Odinets, and I. G. Tananaev, Ros. Khim. Zh. 49, 86 (2005).

    CAS  Google Scholar 

  6. A. M. Rozen and B. V. Krupnov, Russ. Chem. Rev. 65, 973 (1996). https://doi.org/10.1070/RC1996v065n11ABEH000241

    Article  Google Scholar 

  7. P. Matveev, P. K. Mohapatra, S. N. Kalmykov, et al., Solvent Extr. Ion Exch. 679 (2020). https://doi.org/10.1080/07366299.2020.1856998

  8. T. Ya. Medved’, M. K. Chmutova, N. P. Nesterova, et al., Izv. AN SSSR, Ser. Khim. 9, 2112 (1981).

    Google Scholar 

  9. M. K. Chmutova, N. E. Kochetkova, O. E. Koiro, et al., J. Radioanal. Chem. 80, 63 (1983). https://doi.org/10.1007/BF02517648

    Article  Google Scholar 

  10. B. F. Myasoedov, M. K. Chmutova, N. E. Kochetkova, et al., Solvent Extr. Ion Exch. 4, 61 (1986). https://doi.org/10.1080/07366298608917853

    Article  CAS  Google Scholar 

  11. M. N. Litvina, M. K. Chmutova, Yu. M. Kulyako, and B. F. Myasoedov, Radiochemistry 43, 66 (2001). https://doi.org/10.1023/A:1012878106998

    Article  CAS  Google Scholar 

  12. E. V. Sharova, O. I. Artyushin, I. L. Odinets, Russ. Chem. Rev. 83, 95 (2014). https://doi.org/10.1070/RC2014v083n02ABEH004384

    Article  CAS  Google Scholar 

  13. D. A. Tatarinov, V. F. Mironov, A. A. Kostin, et al., Russ. Gen. Chem. 80, 1377 (2010). https://doi.org/10.1134/S1070363210070297

    Article  CAS  Google Scholar 

  14. G. V. Bodrin, E. I. Goryunov, I. B. Goryunova, et al., Dokl. Chem. 447, 269 (2012). https://doi.org/10.1134/S0012500812120014

    Article  CAS  Google Scholar 

  15. E. I. Goryunov, G. V. Bodrin, I. B. Goryunova, et al., Russ. Chem. Bull. 62, 780 (2013). https://doi.org/10.1007/s11172-013-0106-1

    Article  CAS  Google Scholar 

  16. A. M. Safiulina, A. G. Matveeva, A. V. Lizunov, et al., Dokl. Chem. 460, 57 (2015). https://doi.org/10.1134/S001250081502007X

    Article  CAS  Google Scholar 

  17. A. M. Safiulina, N. E. Borisova, A. V. Lizunov, et al., Russ. J. Inorg. Chem. 67, 524 (2022). https://doi.org/10.1134/S0036023622040167

    Article  CAS  Google Scholar 

  18. Yu. G. Elistratova, A. R. Mustafina, D. A. Tatarinov, et al., Russ. Chem. Bull. 60, 790 (2011). https://doi.org/10.1007/s11172-011-0126-7

    Article  CAS  Google Scholar 

  19. A. G. Matveeva, E. I. Goryunov, A. M. Tu, et al., Russ. Chem. Bull. 63, 2493 (2014). https://doi.org/10.1007/s11172-014-0767-4

    Article  CAS  Google Scholar 

  20. A. G. Matveeva, A. M. Tu, A. M. Safiulina, et al., Russ. Chem. Bull. 62, 1309 (2013). https://doi.org/10.1007/s11172-013-0184-0

    Article  CAS  Google Scholar 

  21. S. Mazzotta, L. Gramigna, L. Bernardi, et al., Org. Proc. Res. Dev. 14, 687 (2010). https://doi.org/10.1021/op1000308

    Article  CAS  Google Scholar 

  22. R. J. Giguere and B. Herberich, Synth. Commun. 21, 2197 (1991). https://doi.org/10.1080/00397919108055453

    Article  CAS  Google Scholar 

  23. S. B. Savvin, Organic Reagents of the Arsenazo III Group (Atomizdat, Moscow, 1971) [in Russian].

    Google Scholar 

  24. D. N. Laikov, Chem. Phys. Lett. 416, 116 (2005). https://doi.org/10.1016/j.cplett.2005.09.046

    Article  CAS  Google Scholar 

  25. D. N. Laikov, Chem. Phys. Lett. 281, 151 (1997). https://doi.org/10.1016/S0009-2614(97)01206-2

    Article  CAS  Google Scholar 

  26. J. P. Perdew, K. Burke, and M. Ernzerhof, Phys. Rev. Lett. 77, 3865 (1996). https://doi.org/10.1103/PhysRevLett.77.3865

    Article  CAS  PubMed  Google Scholar 

  27. J. P. Perdew, K. Burke, and M. Ernzerhof, Phys. Rev. Lett. 78, 1396 (1997). https://doi.org/10.1103/PhysRevLett.78.1396

    Article  CAS  Google Scholar 

  28. A. M. Safiulina, A. G. Matveeva, T. K. Dvoryanchikova, et al., Russ. Chem. Bull. 61, 392 (2012). https://doi.org/10.1007/s11172-012-0055-0

    Article  CAS  Google Scholar 

  29. A. G. Matveeva, M. S. Grigor’ev, T. K. Dvoryanchikova, et al., Russ. Chem. Bull. 61, 399 (2012). https://doi.org/10.1007/s11172-012-0056-z

    Article  CAS  Google Scholar 

  30. C. Reichardt and T. Welton, Solvents and Solvent Effects in Organic Chemistry (Wiley-VCH Verlag GmbH & Co. KGaA, 2011).

  31. R. Babecki, A. W. G. Platt, and D. R. Russell, Inorg. Chim. Acta 171, 25 (1990). https://doi.org/10.1016/S0020-1693(00)84658-7

    Article  CAS  Google Scholar 

  32. U. Casellato, P. A. Vigato, and M. Vidali, Coord. Chem. Rev. 36, 183 (1981). https://doi.org/10.1016/S0010-8545(00)80500-7

    Article  CAS  Google Scholar 

  33. D. J. McCabe, E. N. Duesler, and R. T. Paine, Inorg. Chim. Acta 147, 265 (1988). https://doi.org/10.1016/S0020-1693(00)83383-6

    Article  CAS  Google Scholar 

  34. S. M. Bowen, E. N. Duesler, and R. T. Paine, Inorg. Chem. 21, 261 (1982). https://doi.org/10.1021/ic00131a048

    Article  CAS  Google Scholar 

  35. S. M. Bowen, E. N. Duesler, and R. T. Paine, Inorg. Chim. Acta 61, 155 (1982). https://doi.org/10.1016/S0020-1693(00)89134-3

    Article  CAS  Google Scholar 

Download references

Funding

This work was performed under the State Assignment for 2023 of the Ministry of Science and Higher Education of the Russian Federation for the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences (INEOS RAS) (no. 075-03-2023-642). The study of the obtained compounds was supported by the Ministry of Science and Higher Education of the Russian Federation using equipment (NMR spectrometers) of the Center for Molecular Structure Studies, INEOS RAS. Computations were performed under the State assignment for the Moscow State University “Solving problems of nuclear power and environmental safety and materials diagnostics using ionizing radiation” (Project no. 122030200324-1).

Author information

Authors and Affiliations

  1. Bochvar High-Technology Research Institute of Inorganic Materials, 123098, Moscow, Russia

    A. M. Safiulina & A. V. Lizunov

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    A. M. Safiulina

  3. Moscow State University, 119991, Moscow, Russia

    N. E. Borisova & A. V. Golubev

  4. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334, Moscow, Russia

    N. E. Borisova, G. V. Bodrin, E. I. Goryunov, I. B. Goryunova & V. K. Brel’

  5. Kola Scientific Center, Russian Academy of Sciences, 184209, Apatity, Russia

    I. G. Tananaev

  6. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Scientific Center, Russian Academy of Sciences, 184209, Apatity, Russia

    I. G. Tananaev

  7. Far Eastern Federal University, Russkii island, 690090, Vladivostok, Russia

    I. G. Tananaev

Authors
  1. A. M. Safiulina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. E. Borisova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Lizunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Golubev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. V. Bodrin
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. I. Goryunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. I. B. Goryunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. V. K. Brel’
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. I. G. Tananaev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. M. Safiulina.

Ethics declarations

The authors declare no conflict of interest.

Additional information

Translated by I. Kudryavtsev

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Safiulina, A.M., Borisova, N.E., Lizunov, A.V. et al. Effect of Bridging Group Nature on the Extraction Ability of Diphenylphosphorylketones toward Actinides and Lanthanides. Russ. J. Inorg. Chem. 68, 1650–1656 (2023). https://doi.org/10.1134/S0036023623602118

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023623602118

Keywords:

Search

Navigation