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New Method for Synthesis of Substituted 1-Amidine-closo-decaborates [1-B10H9NH=C(R1)NHR2] (R1 = Me, iPr, Ph; R2 = nBu, Bn)

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Abstract

The process of nucleophilic substitution of the phenyliodonium substituent in the [1-B10H9IPh]– anion with primary amines in organic nitriles has been studied. It has been shown that the reaction proceeds with the formation of a mixture of products, namely, 1-monoalkylammonio-closo-decaborate and the corresponding amidine, which is formed when an amine molecule is added to the nitrile. The resulting products have been characterized by 1H, 11B, 13C NMR spectroscopies, IR absorption spectroscopy, and high-resolution ESI mass spectroscopy.

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ACKNOWLEDGMENTS

The work was carried out using the equipment of the Center for Shared Facility of the Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, operating with the support of the State Assignment of the Institute of General and Inorganic Chemistry of the Russian Academy of Sciences in the field of fundamental scientific research.

Funding

This work was supported by the Russian Science Foundation (grant no. 21-73-10292).

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    A. A. Bil’bulyan

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin & N. T. Kuznetsov

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  1. A. A. Bil’bulyan
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  2. A. V. Nelyubin
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  3. N. A. Selivanov
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  4. A. Yu. Bykov
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  5. I. N. Klyukin
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  6. A. P. Zhdanov
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  7. K. Yu. Zhizhin
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Correspondence to A. P. Zhdanov.

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Translated by V. Avdeeva

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Bil’bulyan, A.A., Nelyubin, A.V., Selivanov, N.A. et al. New Method for Synthesis of Substituted 1-Amidine-closo-decaborates [1-B10H9NH=C(R1)NHR2] (R1 = Me, iPr, Ph; R2 = nBu, Bn). Russ. J. Inorg. Chem. 68, 1511–1515 (2023). https://doi.org/10.1134/S0036023623601733

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