Abstract
In this paper, inspired by lotus leaf surfaces, we fabricated biomimetic multi-scale micro-nano-structures by Two-Step Capillary Force Lithography (TS-CFL) and UV-assisted Capillary Force Lithography (UV-CFL). The experimental results indicated that TS-CFL was unfitted to fabricate large-area multi-scale micro-nano-structures. Conversely, UV-CFL can fabricate large-area multi-scale micro-nano-structures. We discussed the hydrophobic and anti-icing properties of the biomimetic surfaces fabricated by these two technologies. We found that small structures are significant for improving the hydrophobic anti-icing properties of single-structured or structureless surfaces. We believe that these results can complement the experimental details of both technologies and enable the development of more interesting micro-nano-structures biomimetic surfaces by both technologies in the future.
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References
Zorba, V., Stratakis, E., Barberoglou, M., Spanakis, E., Tzanetakis, P., Anastasiadis, S. H., & Fotakis, C. (2008). Biomimetic artificial surfaces quantitatively reproduce the water repellency of a lotus leaf. Advanced Materials, 20, 4049–4054. https://doi.org/10.1002/adma.200800651
Gao, T., Liu, F., Yang, D., Yu, Y., Wang, Z., & Li, G. (2015). Assembly of selective biomimetic surface on an electrode surface: A design of nano-bio interface for biosensing. Analytical Chemistry, 87, 5683–5689. https://doi.org/10.1021/acs.analchem.5b00816
Kim, W., Lee, W., Park, H., Park, J., Kim, W., Kang, B., Choi, E., Kim, C.-S., Park, J.-O., Lee, G., Bang, D., & Park, J. (2022). Biomimetic nano-pine-pollen structure-based surface-enhanced raman spectroscopy sensing platform for the hypersensitive detection of toxicants: Cadmium and amyloid. ACS Sustainable Chemistry & Engineering, 10, 3180–3190. https://doi.org/10.1021/acssuschemeng.1c07117
Legrand, Q., Benayoun, S., & Valette, S. (2021). Biomimetic approach for the elaboration of highly hydrophobic surfaces: Study of the links between morphology and wettability. Biomimetics. https://doi.org/10.3390/biomimetics6020038
He, X., Li, G., Zhang, Y., Lai, X., Zhou, M., Xiao, L., Tang, X., Hu, Y., Liu, H., Yang, Y., Cai, Y., Guo, L., Liu, S., & Zhao, W. (2021). Bioinspired functional glass integrated with multiplex repellency ability from laser-patterned hexagonal texturing. Chemical Engineering Journal. https://doi.org/10.1016/j.cej.2021.129113
Kang, S. M., You, I., Cho, W. K., Shon, H. K., Lee, T. G., Choi, I. S., Karp, J. M., & Lee, H. (2010). One-step modification of superhydrophobic surfaces by a mussel-inspired polymer coating. Angewandte Chemie-International Edition, 49, 9401–9404. https://doi.org/10.1002/anie.201004693
Peng, L., Zhang, C., Wu, H., Yi, P., Lai, X., & Ni, J. (2016). Continuous fabrication of multiscale compound eyes arrays with antireflection and hydrophobic properties. IEEE Transactions on Nanotechnology, 15, 971–976. https://doi.org/10.1109/tnano.2016.2618005
Gao, X., & Guo, Z. (2017). Biomimetic superhydrophobic surfaces with transition metals and their oxides: A review. Journal of Bionic Engineering, 14, 401–439. https://doi.org/10.1016/s1672-6529(16)60408-0
Long, J., He, Z., Zhou, P., Xie, X., Zhou, C., Hong, W., & Hu, W. (2018). Low-cost fabrication of large-area broccoli-like multiscale micro- and nanostructures for metallic super-hydrophobic surfaces with ultralow water adhesion and superior anti-frost ability. Advanced Materials Interfaces. https://doi.org/10.1002/admi.201800353
Yang, Y., Li, X., Zheng, X., Chen, Z., Zhou, Q., & Chen, Y. (2018). 3D-printed biomimetic super-hydrophobic structure for microdroplet manipulation and oil/water separation. Advanced Materials. https://doi.org/10.1002/adma.201704912
Jafari, R., Cloutier, C., Allahdini, A., & Momen, G. (2019). Recent progress and challenges with 3D printing of patterned hydrophobic and superhydrophobic surfaces. The International Journal of Advanced Manufacturing Technology, 103, 1225–1238. https://doi.org/10.1007/s00170-019-03630-4
Zhao, W., Xiao, L., He, X., Cui, Z., Fang, J., Zhang, C., Li, X., Li, G., Zhong, L., & Zhang, Y. (2021). Moth-eye-inspired texturing surfaces enabled self-cleaning aluminum to achieve photothermal anti-icing. Optics & Laser Technology. https://doi.org/10.1016/j.optlastec.2021.107115
Guo, Y., Zhang, Z., & Zhang, S. (2019). Advances in the application of biomimetic surface engineering in the oil and gas industry. Friction, 7, 289–306. https://doi.org/10.1007/s40544-019-0292-4
Chen, L., Duan, Y., Cui, M., Huang, R., Su, R., Qi, W., & He, Z. (2021). Biomimetic surface coatings for marine antifouling: Natural antifoulants, synthetic polymers and surface microtopography. Science of the Total Environment, 766, 144469. https://doi.org/10.1016/j.scitotenv.2020.144469
Xia, Y., & Whitesides, G. M. (1998). Soft lithography. Annual review of materials science, 28, 153–184.
Chou, S. Y., Krauss, P. R., & Renstrom, P. J. (1996). Nanoimprint lithography. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena, 14, 4129–4133.
Suh, K. Y., Kim, Y. S., & Lee, H. H. (2001). Capillary force lithography. Advanced Materials, 13, 1386–1389.
Choi, J. S., Tsui, J. H., Xu, F., Lee, S. H., Lee, H. J., Wang, C., Kim, H. J., & Kim, D. H. (2021). Fabrication of nanomolded Nafion thin films with tunable mechanical and electrical properties using thermal evaporation-induced capillary force lithography. Advanced Materials Interfaces. https://doi.org/10.1002/admi.202002005
Xing, W., Zhang, D., Zhang, L., Zhang, S., Huang, Y., Li, J., Guo, A., Li, W., & Zhao, F. (2021). Stamping of a replica with resolution doubling that of the master via capillary force lithography. Optical Materials, 120, 111467.
Cheng, K., Huang, Z., Wang, P., Sun, L., Ghasemi, H., Ardebili, H., & Karim, A. (2023). Antibacterial flexible triboelectric nanogenerator via capillary force lithography. Journal of Colloid and Interface Science, 630, 611–622.
Lee, H., Seo, H., Kim, S. K., & Bae, I. (2022). Aligned proton transport highway of hierarchically structured proton-exchange membranes constructed via capillary force lithography. ACS Applied Energy Materials, 5, 6256–6264.
Jeong, H. E., Kwak, R., Kim, J. K., & Suh, K. Y. (2008). Generation and self-replication of monolithic, dual-scale polymer structures by two-step capillary-force lithography. Small (Weinheim an der Bergstrasse, Germany), 4, 1913–1918. https://doi.org/10.1002/smll.200800151
Khang, D. Y., & Lee, H. H. (2004). Pressure-assisted capillary force lithography. Advanced Materials, 16, 176–179. https://doi.org/10.1002/adma.200305673
Zhou, T., Ruan, B., Che, J., Li, H., Chen, X., & Jiang, Z. (2021). Gecko-inspired biomimetic surfaces with annular wedge structures fabricated by ultraprecision machining and replica molding. ACS Omega, 6, 6757–6765. https://doi.org/10.1021/acsomega.0c05804
Tao, D., Gao, X., Lu, H., Liu, Z., Li, Y., Tong, H., Pesika, N., Meng, Y., & Tian, Y. (2017). Controllable anisotropic dry adhesion in vacuum: Gecko inspired wedged surface fabricated with ultraprecision diamond cutting. Advanced Functional Materials, 27, 1606576.
Bechert, D., Bruse, M., & Hage, W. (2000). Experiments with three-dimensional riblets as an idealized model of shark skin. Experiments in fluids, 28, 403–412.
Wang, Y., Hu, H., Shao, J., & Ding, Y. (2014). Fabrication of well-defined mushroom-shaped structures for biomimetic dry adhesive by conventional photolithography and molding. ACS Applied Materials & Interfaces, 6, 2213–2218. https://doi.org/10.1021/am4052393
Tricinci, O., Eason, E. V., Filippeschi, C., Mondini, A., Mazzolai, B., Pugno, N. M., Cutkosky, M. R., Greco, F., & Mattoli, V. (2018). Approximating gecko setae via direct laser lithography. Smart Materials and Structures. https://doi.org/10.1088/1361-665X/aa9e5f
Liu, R., Chi, Z., Cao, L., Weng, Z., Wang, L., Li, L., Saeed, S., Lian, Z., & Wang, Z. (2020). Fabrication of biomimetic superhydrophobic and anti-icing Ti6Al4V alloy surfaces by direct laser interference lithography and hydrothermal treatment. Applied Surface Science, 534, 147576.
Yao, M., Zhang, P., Nie, J., & He, Y. (2021). The superhydrophobic fluorine-containing material prepared through biomimetic UV lithography for oil–water separation and anti-bioadhesion. Macromolecular Chemistry and Physics, 222, 2100149.
Zhan, Y., Zhao, J., Liu, W., Yang, B., Wei, J., & Yu, Y. (2015). Biomimetic submicroarrayed cross-linked liquid crystal polymer films with different wettability via colloidal lithography. ACS applied materials & interfaces, 7, 25522–25528.
Gu, Y., Zhang, W., Mou, J., Zheng, S., Jiang, L., Sun, Z., & Wang, E. (2017). Research progress of biomimetic superhydrophobic surface characteristics, fabrication, and application. Advances in Mechanical Engineering. https://doi.org/10.1177/1687814017746859
Zhang, L., Chu, X., Tian, F., Xu, Y., & Hu, H. (2022). Bio-inspired hierarchical micro-/nanostructures for anti-icing solely fabricated by metal-assisted chemical etching. Micromachines. https://doi.org/10.3390/mi13071077
Moon, B. S., Kim, S., Kim, H. E., & Jang, T. S. (2017). Hierarchical micro-nano structured Ti6Al4V surface topography via two-step etching process for enhanced hydrophilicity and osteoblastic responses. Materials Science & Engineering C-Materials for Biological Applications, 73, 90–98. https://doi.org/10.1016/j.msec.2016.12.064
Hu, H., Siu, V. S., Gifford, S. M., Kim, S., Lu, M., Meyer, P., & Stolovitzky, G. A. (2017). Bio-inspired silicon nanospikes fabricated by metal-assisted chemical etching for antibacterial surfaces. Applied Physics Letters. https://doi.org/10.1063/1.5003817
Stratakis, E., Bonse, J., Heitz, J., Siegel, J., Tsibidis, G. D., Skoulas, E., Papadopoulos, A., Mimidis, A., Joel, A. C., Comanns, P., Krüger, J., Florian, C., Fuentes-Edfuf, Y., Solis, J., & Baumgartner, W. (2020). Laser engineering of biomimetic surfaces. Materials Science and Engineering: R: Reports, 141, 100562. https://doi.org/10.1016/j.mser.2020.100562
Yang, Z., Liu, X., & Tian, Y. (2019). Hybrid laser ablation and chemical modification for fast fabrication of bio-inspired super-hydrophobic surface with excellent self-cleaning, stability and corrosion resistance. Journal of Bionic Engineering, 16, 13–26. https://doi.org/10.1007/s42235-019-0002-y
Ahmmed, K., Grambow, C., & Kietzig, A.-M. (2014). Fabrication of micro/nano structures on metals by femtosecond laser micromachining. Micromachines, 5, 1219–1253. https://doi.org/10.3390/mi5041219
Höhm, S., Rosenfeld, A., Krüger, J., & Bonse, J. (2012). Femtosecond laser-induced periodic surface structures on silica. Journal of Applied Physics, 112, 014901. https://doi.org/10.1063/1.4730902
Garcia-Lechuga, M., Haahr-Lillevang, L., Siegel, J., Balling, P., Guizard, S., & Solis, J. (2017). Simultaneous time-space resolved reflectivity and interferometric measurements of dielectrics excited with femtosecond laser pulses. Physical Review B. https://doi.org/10.1103/PhysRevB.95.214114
Osellame, R., Cerullo, G., & Ramponi, R. (2012). Femtosecond laser micromachining: Photonic and microfluidic devices in transparent materials. Springer.
Baron, C. F., Mimidis, A., Puerto, D., Skoulas, E., Stratakis, E., Solis, J., & Siegel, J. (2018). Biomimetic surface structures in steel fabricated with femtosecond laser pulses: Influence of laser rescanning on morphology and wettability. Beilstein journal of nanotechnology, 9, 2802–2812.
Bäuerle, D. (2013). Laser processing and chemistry. Springer Science & Business Media.
Ling, E. J. Y., Saïd, J., Brodusch, N., Gauvin, R., Servio, P., & Kietzig, A.-M. (2015). Investigating and understanding the effects of multiple femtosecond laser scans on the surface topography of stainless steel 304 and titanium. Applied Surface Science, 353, 512–521.
Martínez-Calderon, M., Rodríguez, A., Dias-Ponte, A., Morant-Miñana, M., Gómez-Aranzadi, M., & Olaizola, S. (2016). Femtosecond laser fabrication of highly hydrophobic stainless steel surface with hierarchical structures fabricated by combining ordered microstructures and LIPSS. Applied Surface Science, 374, 81–89.
Qin, W., & Yang, J. (2017). Controlled assembly of high-order nanoarray metal structures on bulk copper surface by femtosecond laser pulses. Surface Science, 661, 28–33.
Suh, K. Y., & Lee, H. H. (2002). Capillary force lithography: large-area patterning, self-organization, and anisotropic dewetting. Advanced Functional Materials, 12, 405–413.
Charoenchai, M., Prompinit, P., Kangwansupamonkon, W., & Vayachuta, L. (2020). Bio-inspired surface structure for slow-release of urea fertilizer. Journal of Bionic Engineering, 17, 335–344. https://doi.org/10.1007/s42235-020-0027-2
Dong, S., Li, M., Liu, C., Zhang, J., & Chen, G. (2020). Bio-inspired superhydrophobic coating with low hydrate adhesion for hydrate mitigation. Journal of Bionic Engineering, 17, 1019–1028. https://doi.org/10.1007/s42235-020-0085-5
Mattaparthi, S., & Sharma, C. S. (2019). Fabrication of self-cleaning antireflective polymer surfaces by mimicking underside leaf hierarchical surface structures. Journal of Bionic Engineering, 16, 400–409. https://doi.org/10.1007/s42235-019-0032-5
Wang, Z., Li, B., Feng, X., Jiao, Z., Zhang, J., Niu, S., Han, Z., & Ren, L. (2020). Rapid fabrication of bio-inspired antireflection film replicating from cicada wings. Journal of Bionic Engineering, 17, 34–44. https://doi.org/10.1007/s42235-020-0001-z
Sefiane, K. (2010). On the formation of regular patterns from drying droplets and their potential use for bio-medical applications. Journal of Bionic Engineering, 7, S82–S93. https://doi.org/10.1016/s1672-6529(09)60221-3
Xu, M., Du, F., Ganguli, S., Roy, A., & Dai, L. (2016). Carbon nanotube dry adhesives with temperature-enhanced adhesion over a large temperature range. Nature Communication, 7, 13450. https://doi.org/10.1038/ncomms13450
Funding
This work was supported by National Natural Science Foundation of China (Nos. 61705096, 12274189 and 62075092), Natural Science Foundation of Shandong Province (ZR2021MF121), and Yantai City-University Integration Development Project (2021XDRHXMXK26, 2021XKZY03).
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WX and YT: conceptualization, methodology, investigation, data curation, visualization, writing—original draft. FZ and LZ: methodology, funding acquisition, supervision. DZ: writing—review and editing, supervision, funding acquisition.
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Xing, W., Tang, Y., Zhao, F. et al. Fabrication of Biomimetic Surface for Hydrophobic and Anti-icing Purposes via the Capillary Force Lithography. J Bionic Eng 21, 74–83 (2024). https://doi.org/10.1007/s42235-023-00451-w
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DOI: https://doi.org/10.1007/s42235-023-00451-w