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The Possibility of Saturation Transfer in a New Nickel(II) Complex with 2,6-Bis(pyrazol-3-yl)pyridine

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Abstract

The reaction of N,N '-disubstituted 2,6-bis(pyrazol-3-yl )pyridine ligand (L) with a divalent nickel salt gave a new nickel(II) complex [Ni(L)(H2O)(THF)Cl]BPh4 (I), which was isolated in a pure state and characterized by elemental analysis, mass spectrometry, NMR spectroscopy, and X-ray diffraction (CCDC no. 2221412). According to NMR spectroscopy data combined with the results of quantum chemical calculations, complex I does not show saturation transfer effect in solutions.

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ACKNOWLEDGMENTS

X-ray diffraction studies were carried out using the research equipment of the Molecular Structure Investigation Center of the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, supported by the Ministry of Science and Higher Education of the Russian Federation (state assignment no. 075-00697-22-00).

Funding

This study was supported by the of the Council under President of the Russian Federation (scholarship for young scientists and post-graduates SP-3215.2022.4).

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    D. Yu. Aleshin, I. A. Nikovskii, E. A. Khakina, A. A. Dan’shina & Yu. V. Nelyubina

  2. National Research University, Higher School of Economics, Moscow, Russia

    E. A. Khakina

  3. Moscow Institute of Physics and Technology, Dolgoprudnyi, Russia

    A. A. Dan’shina

  4. Bauman Moscow State Technical University, Moscow, Russia

    Yu. V. Nelyubina

Authors
  1. D. Yu. Aleshin
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  2. I. A. Nikovskii
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  3. E. A. Khakina
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  4. A. A. Dan’shina
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  5. Yu. V. Nelyubina
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Corresponding author

Correspondence to Yu. V. Nelyubina.

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Translated by Z. Svitanko

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Aleshin, D.Y., Nikovskii, I.A., Khakina, E.A. et al. The Possibility of Saturation Transfer in a New Nickel(II) Complex with 2,6-Bis(pyrazol-3-yl)pyridine. Russ J Coord Chem 49, 777–783 (2023). https://doi.org/10.1134/S1070328423700677

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  • DOI: https://doi.org/10.1134/S1070328423700677

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