Skip to main content
SpringerLink
Log in

Chemical Transformations of [Pd(OOCMe)4Mn] in the Reactions with 1,10-Phenanthroline and Pivalic Acid

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A series of new Pd–Mn bimetallic acetate and pivalate complexes were synthesized and structurally characterized. The starting [Pd(OOCMe)4Mn] complex reacts with N‑donor ligands such as 1,10-phenanthroline (phen) to give [Pd(OOCMe)4Mn(phen)]⋅MeCN (I) (CCDC no. 2217716). The replacement of acetate bridges in the heterometallic Pd–Mn carboxylate complexes with pivalate bridges was investigated. It was shown that complete replacement of all acetate bridges with pivalate ones can occur both in heterometallic complex I, which contains a ligand coordinated to the second metal atom, to give the compound [Pd(Piv)4Mn(phen)]⋅C6H6 (II) (CCDC no. 2217717), structurally related to the initial acetate complex, and in the acetate complex [Pd(OOCMe)4Mn]. The heterometallic co-crystallized pivalate [Pd(Piv)4Mn⋅2HPiv] (III) (CCDC no. 2217718) formed in the latter case can react with 5-nitro-1,10-phenanthroline to give the complex [Pd(Piv)4Mn(Nphen)] (IV) (CCDC no. 2217719).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Buchwalter, P., Rosé, J., and Braunstein, P., Chem. Rev., 2015, vol. 115, no. 1, p. 28.

    Article  PubMed  CAS  Google Scholar 

  2. Kozitsyna, N.Yu., Nefedov, S.E., Yakushev, I.A., et al., Mendeleev Commun., 2007, vol. 17, no. 5, p. 261.

    Article  CAS  Google Scholar 

  3. Khramov, E., Belyakova, O., Murzin, V., et al., Z. Anorg. Allg. Chem., 2014, vol. 640, nos. 12−13, p. 2577.

    Article  CAS  Google Scholar 

  4. Ershov, B.G., Anan’ev, A.V., Abkhalimov, E.V., et al., Nanotechnologies Russ., 2011, vol. 6, nos. 5–6, p. 323.

    Article  Google Scholar 

  5. Cherkashina, N.V., Churakov, A.V., Yakushev, I.A., et al., Russ. J. Coord. Chem., 2019, vol. 45, no. 4, p. 253. https://doi.org/10.1134/S107032841904002X

    Article  CAS  Google Scholar 

  6. Garkul, I.A., Zadesenets, A.V., Korolkov, I.V., et al., J. Struct. Chem., 2020, vol. 61, no. 5, p. 719.

    Article  CAS  Google Scholar 

  7. Garkul’, I.A., Zadesenets, A.V., Plyusnin, P.E., et al., Russ. J. Inorg. Chem., 2020, vol. 65, no. 10, p. 1571. https://doi.org/10.1134/S003602362010006X

    Article  Google Scholar 

  8. Smirnova, N.S., Khramov, E.V., Stolarov, I.P., et al., Intermetallics, 2021, vol. 132, p. 107160.

    Article  CAS  Google Scholar 

  9. Nefedov, S.E., Vargaftik, M.N., and Moiseev, I.I., Inorg. Chem. Commun., 2006, vol. 9, no. 7, p. 755.

    Article  CAS  Google Scholar 

  10. Yakushev, I.A., Sosunov, E.A., Makarevich, Yu.E., et al., J. Struct. Chem., 2022, vol. 63, no. 12, p. 103431.

    Article  Google Scholar 

  11. Pasynskii, A.A., Shapovalov, S.S., Skabitskii, I.V., et al., Russ. J. Inorg. Chem., 2016, vol. 42, no. 9, p. 608. https://doi.org/10.31857/S0132344X22030069

    Article  CAS  Google Scholar 

  12. Nefedov, S.E., Yakushev, I.A., Kozitsyna, N.Yu., et al., Inorg. Chem. Commun., 2007, vol. 10, no. 8, p. 948.

    Article  CAS  Google Scholar 

  13. Nefedov, S.E., Kozitsyna, N.Yu., Akhmadullina, N.S., et al., Inorg. Chem. Commun., 2011, vol. 14, no. 4, p. 554.

    Article  CAS  Google Scholar 

  14. Nefedov, S.E., Kozitsyna, N.Yu., Vargaftik, M.N., et al., Polyhedron, 2009, vol. 28, no. 1, p. 172.

    Article  CAS  Google Scholar 

  15. Ho, P.-H., Hung, C.-C., Wang, Y.-H., et al., Asian J. Org. Chem., 2019, vol. 8, no. 2, p. 275.

    Article  CAS  Google Scholar 

  16. Pasynskii, A.A. and Shapovalov, S.S., Russ. J. Inorg. Chem., 2016, vol. 42, no. 9, p. 574. https://doi.org/10.1134/S1070328416090050

    Article  CAS  Google Scholar 

  17. Shapovalov, S.S., Gordienko, A.V., Pasynskii, A.A., et al., Russ. J. Inorg. Chem., 2011, vol. 37, no. 6, p. 447. https://doi.org/10.1134/S1070328411050125

    Article  CAS  Google Scholar 

  18. Yakushev, I.A., Dyuzheva, M.A., Stebletsova, I.A., et al., Russ. J. Inorg. Chem., 2022, vol. 48, no. 3, p. 153. https://doi.org/10.1134/S107032842203006X

    Article  CAS  Google Scholar 

  19. Popova, A.S., Ogarkova, N.K., Shapovalov, S.S., et al., Mendeleev Commun., 2022, vol. 32, no. 5, p. 576.

    Article  CAS  Google Scholar 

  20. Shmelev, M.A., Gogoleva, N.V., Makarov, D.A., et al., Russ. J. Inorg. Chem., 2020, vol. 46, no. 1, p. 1. https://doi.org/10.1134/S1070328420010078

    Article  CAS  Google Scholar 

  21. Nefedov, S.E., Perova, E.V., Yakushev, I.A., et al., Inorg. Chem. Commun., 2009, vol. 12, no. 6, p. 454.

    Article  CAS  Google Scholar 

  22. Nefedov, S.E., Kushan, E.V., Uvarova, M.A., et al., Inorg. Chim. Acta, 2013, vol. 395, p. 104.

    Article  CAS  Google Scholar 

  23. Nefedov, S.E., Uvarova, M.A., Golubnichaya, M.A., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 7, p. 733. https://doi.org/10.1134/S0036023614070171

    Article  CAS  Google Scholar 

  24. Kozitsyna, N.Yu., Nefedov, S.E., Dolgushin, F.M., et al., Inorg. Chim. Acta, 2006, vol. 359, no. 7, p. 2072.

    Article  CAS  Google Scholar 

  25. Perrin, D.D. and Armarego, W.L.F., Purification of Laboratory Chemicals, Oxford: Pergamon, 1988.

    Google Scholar 

  26. APEX3, SAINT and SADABS, Madison: Bruker AXS Inc., 2016.

  27. Krause, L., Herbst-Irmer, R., Sheldrick, G.M., et al., J. Appl. Crystallogr., 2015, vol. 48, no. 1, p. 3.

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  28. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Adv., 2015, vol. 71, no. 1, p. 3.

    Article  Google Scholar 

  29. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, no. 1, p. 3.

    Article  Google Scholar 

  30. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, no. 2, p. 339.

    Article  CAS  Google Scholar 

  31. Huang, G.-H., Li, J.-M., Huang, J.-J., et al., Chem.- Eur. J., 2014, vol. 20, no. 18, p. 5240.

    Article  PubMed  CAS  Google Scholar 

  32. Akhmadullina, N.S., Cherkashina, N.V., Kozitsyna, N.Yu., et al., Inorg. Chim. Acta, 2009, vol. 362, no. 6, p. 1943.

    Article  CAS  Google Scholar 

  33. Pinsky, M. and Avnir, D., Inorg. Chem., 1998, vol. 37, no. 21, p. 5575.

    Article  PubMed  CAS  Google Scholar 

  34. Cirera, J., Ruiz, E., and Alvarez, S., Chem. Eur. J., 2006, vol. 12, no. 11, p. 3162.

    Article  PubMed  CAS  Google Scholar 

  35. Janjić, G.V., Petrović, P.V., Ninković, D.B., et al., J. Mol. Model., 2011, vol. 17, no. 8, p. 2083.

    Article  PubMed  Google Scholar 

  36. Yakushev, I.A., Stebletsova, I.A., Cherkashina, N.V., et al., J. Struct. Chem., 2021, vol. 62, no. 9, p. 1411.

    Article  CAS  Google Scholar 

  37. Lord, R.C. and Merrifield, R.E., J. Chem. Phys., 1953, vol. 21, no. 1, p. 166.

    Article  CAS  Google Scholar 

Download references

Funding

This study was supported by the Russian Science Foundation (project no. 18-73-10206-P).

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    E. A. Sosunov, A. D. Maksimova, I. A. Yakushev, N. K. Ogarkova, M. N. Vargaftik & A. S. Popova

Authors
  1. E. A. Sosunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. D. Maksimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Yakushev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. K. Ogarkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. N. Vargaftik
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. S. Popova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Yakushev.

Ethics declarations

The authors of this work declare that they have no conflicts of interest.

Additional information

Dedicated to the memory of Professor Sergey Evgen’evich Nefedov

Translated by Z. Svitanko

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sosunov, E.A., Maksimova, A.D., Yakushev, I.A. et al. Chemical Transformations of [Pd(OOCMe)4Mn] in the Reactions with 1,10-Phenanthroline and Pivalic Acid. Russ J Coord Chem 49, 812–821 (2023). https://doi.org/10.1134/S1070328423600754

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328423600754

Keywords:

Search

Navigation