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Cadmium(II)-Organic Coordination Polymer Containing Carboxyl Groups: Solvothermal Synthesis, Structure, and Properties

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Abstract

New metal-organic coordination polymer Cd[H2L] (I) (where H4L is 4,4'-([2,2'-bipyridine]-6,6'-diylbis(oxy))diphthalic acid) is synthesized in a high yield under the solvothermal synthesis conditions. According to the X-ray diffraction (XRD) data, each Cd(II) cation binds four organic ligands: one ligand is bound via the coordination of the chelate bipyridyl fragment, two ligands are linked via the bidentate coordination of the deprotonated COO groups, and one ligand is bound via the monodentate coordination of the protonated carboxylate group. The synthesized three-dimensional metal-organic framework contains no free space capable of including guest molecules. Compound I is characterized by powder XRD, IR spectroscopy, and elemental (C, H, N) and thermogravimetric analyses. The luminescence spectra of compound I are recorded.

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ACKNOWLEDGMENTS

The authors thank V.G. Ponomareva (Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch, Russian Academy of Sciences).

Funding

The analytical characterization of the synthesized compounds was supported by the Ministry of Science and Higher Education of the Russian Federation (project no. 121031700321-3). B. Xu and X. Yu are grateful to the China Scholarship Council (CSC) for financial support (grants nos. 202110340003 and 202008090088).

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Authors and Affiliations

  1. China-Russian Institute of Engineering Materials Chemistry, School of Chemical Engineering, University of Science and Technology Liaoning, 114051, Anshan, China

    B. Xu, W. Yao & E. Gao

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    X. Yu, D. G. Samsonenko & V. P. Fedin

  3. Novosibirsk State University, Novosibirsk, Russia

    X. Yu & V. P. Fedin

Authors
  1. B. Xu
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  2. W. Yao
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  3. X. Yu
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  4. D. G. Samsonenko
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  5. V. P. Fedin
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  6. E. Gao
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Corresponding authors

Correspondence to V. P. Fedin or E. Gao.

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The authors of this work declare that they have no conflicts of interest.

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Translated by E. Yablonskaya

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Xu, B., Yao, W., Yu, X. et al. Cadmium(II)-Organic Coordination Polymer Containing Carboxyl Groups: Solvothermal Synthesis, Structure, and Properties. Russ J Coord Chem 49, 771–776 (2023). https://doi.org/10.1134/S1070328423600316

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  • DOI: https://doi.org/10.1134/S1070328423600316

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