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Reactivity of Half-Sandwich 16e Carborane Complex Me4CpCo[S2C2B10H10] with Phosphorous Compounds

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Abstract

Treatment of o-carborane, n-butyllithium, sulfur and Me4CpCo(CO)I2 under argon leads to half-sandwich 16e carborane complex Me4CpCo[S2C2B10H10]. Me4CpCo[S2C2B10H10] reacts with PPh2Me, PPhMe2, PMe3 to afford addition products Me4CpCo[S2C2B10H10](PPh2Me) (I), Me4CpCo-[S2C2B10H10](PPhMe2) (II), Me4CpCo[S2C2B10H10](PMe3) (III), respectively. I, II and III have been characterized by IR, NMR, elemental analysis, mass spectrum. I and III have also been characterized by single-crystal X-ray diffraction analysis (CCDC nos. 2245287 (I) and 2245288 (III)). The UV and fluorescent spectra properties of the compounds I, II and III have been tested. The UV spectra results of complexes I, II and III in acetonitrile solution show that the bands are located at 412, 399 and 401 nm, respectively. The fluorescence spectra result of the complexes I, II and III exhibit maximum emission peaks at about 405 nm.

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Funding

This work was supported by the Department of Science and Technology Research Projects of Shangrao City (no. SKB2021005), the National Natural Science Foundation of China (no. 62065016), the Natural Science Foundation of Jiangxi Province (no. 20202BABL202023), Innovation Training Program of Shangrao Normal University (no. 202310416002) and the Science and Technology Project of Education Department of Jiangxi Province (no. GJJ190883, GJJ211707).

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Authors and Affiliations

  1. School of Chemistry and Environmental Science, Jiangxi Provincial Research of Targeting Pharmaceutical Engineering Technology, Shangrao Normal University, 334001, Jiangxi, P.R. China

    Y. Huang, Q. Xiao, G. R. Xu, H. D. Ye, H. N. Peng & X. L. Zhang

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  1. Y. Huang
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  2. Q. Xiao
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  3. G. R. Xu
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  4. H. D. Ye
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Correspondence to H. D. Ye or H. N. Peng.

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Huang, Y., Xiao, Q., Xu, G.R. et al. Reactivity of Half-Sandwich 16e Carborane Complex Me4CpCo[S2C2B10H10] with Phosphorous Compounds. Russ J Coord Chem 49, 856–861 (2023). https://doi.org/10.1134/S107032842360050X

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  • DOI: https://doi.org/10.1134/S107032842360050X

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