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Synthesis and Optical Properties of a Heterocarboxylate Complex with the Zn2Eu Metal Core

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Abstract

It was shown that refluxing of europium(III) acetate hydrate with trifluoroacetic acid in a dioxane–acetonitrile mixture gives the polymer {[Eu(μ-OOCCF3)3(OH2)2]}n (I) containing dioxane solvate molecules. The reaction of I with [phen(µ-OOCtBu)2(OOCtBu)2] (II) (phen = 1,10-phenanthroline) in CH2Cl2 at room temperature gives a precipitate, the recrystallization of which from acetonitrile affords an unusual trinuclear heterometallic heteroanionic phen2Zn2Eu(µ3-OH)(OOCtBu)4(OOCCF3)2 complex (III). The structure of the products was established from X-ray diffraction data (CCDC no. 2235937–2235939). The optical properties of complex III were studied.

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ACKNOWLEDGMENTS

X-ray diffraction studies, elemental analysis, and IR spectroscopy were performed using equipment of the Center of Molecular Structure Investigation of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, and was supported by the Ministry of Science and Higher Education of the Russian Federation. Study of the optical properties was carried out using the equipment of the Lebedev Physical Institute, Russian Academy of Sciences.

Funding

This study was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Uvarova, M. A. Shmelev, S. E. Nefedov & I. L. Eremenko

  2. Lebedev Physical Institute, Russian Academy of Sciences, Moscow, Russia

    I. V. Taidakov

  3. Plekhanov Russian University of Economics, Moscow, Russia

    I. V. Taidakov

Authors
  1. M. A. Uvarova
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  2. I. V. Taidakov
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  3. M. A. Shmelev
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  4. S. E. Nefedov
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  5. I. L. Eremenko
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Corresponding author

Correspondence to M. A. Uvarova.

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Translated by Z. Svitanko

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Uvarova, M.A., Taidakov, I.V., Shmelev, M.A. et al. Synthesis and Optical Properties of a Heterocarboxylate Complex with the Zn2Eu Metal Core. Russ J Coord Chem 49, 784–791 (2023). https://doi.org/10.1134/S1070328423600882

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  • DOI: https://doi.org/10.1134/S1070328423600882

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