Skip to main content

Advertisement

Log in

Microstructural Evolution and Mechanical Properties of the Ti2AlNb Alloy with 3 wt.% W and 0.1 wt.% Y Obtained Using Powder Metallurgy Technique

  • SINTERED METALS AND ALLOYS
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

TiAl intermediate compound is an important material for high-temperature applications due to its superior creep resistance and oxidation resistance. It is suitable for high-pressure compressors and low-pressure turbine blades of advanced military aircraft engines. TiAl intermediate compound is an excellent substitute for nickel-based superalloys, as it can decrease weight by 40% and greatly enhance aircraft thrust-to-weight ratio. In this paper, the microstructure evolution and the mechanical properties of Ti2AlNb alloy with a 3.0 wt.% W and 0.1 wt.% Y addition obtained by blending elemental ultrafine powders was investigated by XRD, SEM-EDS, and mechanical testing device. The findings show that high relative density of 0.9945, and the excellent mechanical properties of Ti2AlNb–3W–0.1Y alloy can be obtained through isothermal sintering for 3 hour in a furnace with controllable argon atmosphere flow of 200 mL/min at 1,500°C. The alloy’s tensile strength, yield strength, and elongation reach 1,030 MPa, 913 MPa, and 15.1% at 700°C, respectively. Meanwhile, the 3 wt.% of element W is added to the alloy to form (TiW)C as the second strengthening phase, which is uniformly distributed in the matrix of Ti2AlNb. The addition of Y element at 0.1 wt.% into the alloy can act as an effective scavenger of oxygen and inhibit the unsatisfactory precipitation of the brittle α2-phase in the Ti2AlNb alloy. Compared to the alloy without additions, the Ti2AlNb alloy with 3 wt.% W and 0.1 wt.% Y demonstrated 13.5% and 19.35% improvements in the fracture resistance at 25°C and 700°C, respectively. The alloy’s yield strength was increased as well. The evolution regularity of the main metallography is (Ti2AlNb–TiAl–Ti3Al) → (Ti2AlNb–Ti3Al) → (Ti2AlNb–Ti3Al–(TiW) C) during the isothermal sintering of Ti–22Al–25Nb–3W–0.1Y alloy at 1,500°C. This study provides technical guidance for the preparation of ultrafine TiAl-based alloy powder and high-temperature aerospace applications

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. D. Banerjee, “The intermetallic Ti2AlNb,” Prog. Mater. Sci., 42, No. 1–4, 135–158 (1997). https://doi.org/https://doi.org/10.1016/S0079-6425(97)00012-1.

    Article  CAS  Google Scholar 

  2. C.J. Boehlert, B.S. Majumdar, V. Seetharaman, and D.B. Miracle, “Part I. The microstructural evolution in Ti–Al–Nb O + BCC orthorhombic alloys,” Metall. Mater. Trans. A, 30, 2305–2323 (1999), https://doi.org/https://doi.org/10.1007/s11661-999-0240-4.

    Article  Google Scholar 

  3. C.J. Cowen and C.J. Boehlert, “Microstructure, creep, and tensile behavior of a Ti–21Al–29Nb (at.%) orthorhombic+B2 alloy,” Intermetallics, 14, No. 4, 412–422 (2006), https://doi.org/https://doi.org/10.1016/j.intermet.2005.08.006. ISSN 0966-9795.

    Article  CAS  Google Scholar 

  4. W. Chen, “Parameterized spatial SQL translation for geographic question answering,” in: 2014 IEEE Int. Conf. on Semantic Computing (16-18 June 2014), p. 23–27, doi: https://doi.org/10.1109/ICSC.2014.44. https://ieeexplore.ieee.org/document/6881997.

  5. S. Li, Y. Mao, J. Zhang, J. Li, Y. Cheng, and Z. Zhong, “Effect of microstructure on tensile properties and fracture behavior of intermetallic Ti_2AlNb alloys,” Trans Nonferr. Met. Soc. Chin., No. 04, 582–586 (2002).

  6. T.M. Pollock, “Alloy design for aircraft engines,” Nat. Mater., 15, No. 8, 809 (2016).

  7. F. Appel, R. Wagner, and V. Kumar, “Intermetallics: Titanium Aluminides,” Ref. Modul. Mater. Sci. Mater. Eng. (2017), https://doi.org/https://doi.org/10.1016/b978-0-12-803581-8.02542-x.

    Article  Google Scholar 

  8. F. Appel and R. Wagner, “Microstructure and deformation of two-phase γ-titanium aluminides,” Mater. Sci. Eng. R Rep., 22, 187–268 (1998).

    Article  Google Scholar 

  9. A.M. Hodge, L.M. Hsiung, and T.G. Nieh, “Creep of nearly lamellar TiAl alloy containing W,” Scr. Mater., 51, 411–415 (2004).

    Article  CAS  Google Scholar 

  10. M. Yamaguchi, H. Inui, and K. Ito, “High-temperature structural intermetallics,” Acta Mater., 48, 307–322 (2000).

    Article  CAS  Google Scholar 

  11. P. Erdely, P. Staron, A. Stark, T. Klein, H. Clemens, and S. Mayer, “In situ and atomic-scale investigations of the early stages of γ precipitate growth in a supersaturated intermetallic Ti–44Al–7Mo (at.%) solid solution,” Acta Mater., 164, 110–121 (2019).

    Article  CAS  Google Scholar 

  12. J.L. Yang, G.F. Wang, X.Y. Jiao, Y. Li, and Q. Liu, “High-temperature deformation behavior of the extruded Ti–22Al–25Nb alloy fabricated by powder metallurgy,” Mater. Charact., 137, 170–179 (2018).

    Article  CAS  Google Scholar 

  13. M. Dadé, V.A. Esin, L. Nazé, and P, Sallot, “Short and long-term oxidation behavior of an advanced Ti2AlNb alloy,” Corros. Sci., 148, 379–387 (2019).

  14. Z.L. Lei, K.Z. Zhang, H. Zhou, L.C. Ni, and Y.B. Chen, “A comparative study of microstructure and tensile properties of Ti2AlNb joints prepared by laser welding and laser-additive welding with the addition of filler powder,” J. Mater. Proc. Technol., 255, 477–487 (2018).

    Article  CAS  Google Scholar 

  15. Y.L. Zhang, A.H. Feng, S.J. Qu, J. Shen, and D.L. Chen, “Microstructure and low cycle fatigue of a Ti2AlNb-based lightweight alloy,” J. Mater. Sci. Technol., 44, 140–147 (2020).

    Article  CAS  Google Scholar 

  16. H. Wu, P. Zhang, H. Zhao, L. Wang, and A. Xie, “Effect of different alloyed layers on the hightemperature oxidation behavior of newly developed Ti2AlNb-based alloys,” Appl. Surf. Sci. 257, 1835–1839 (2011), Vol.. https://doi.org/10.1016/j.apsusc.2010.08.101.

  17. K.F. Kai, Y.X. Wang, J.B. Jia, and B.Y. Li, “Deformation properties and bending/diffusion bonding processing of a P/M Ti–22Al–25Nb alloy at elevated temperature,” Proc. Eng., 81, 2153–2158 (2014), https://doi.org/https://doi.org/10.1016/j.proeng.2014.10.301.

    Article  CAS  Google Scholar 

  18. G. Wang, X. Sui, Q. Liu, and Y. Liu, “Fabricating Ti2AlNb sheet with high tensile strength and good ductility by hot packed rolling the spark plasma sintered pre-alloyed powder,” Mat. Sci. Eng. A, 801, 140392 (2021), https://doi.org/https://doi.org/10.1016/j.msea.2020.140392.

    Article  CAS  Google Scholar 

  19. M. Peters, J. Hemptenmacher, J. Kumpfert, and C. Leyens, “Structure and Properties of Titanium and Titanium Alloys,” in: Titanium and Titanium Alloys: Fundamentals and Applications, Christoph Leyens and Manfred Peters (Eds.), Wiley-VCH Verlag GmbH & Co. KGaA (2003), pp. 1–36, https://doi.org/10.1002/3527602119.ch1.

  20. J.B. McAndrew and C.R. Simcoe, Investigation of the Ti–Al–Cb System as a Source of Alloys for Use at 1200–1800 F, Wright-Patterson Air Force Base (1960).

  21. S. Emura, K. Tsuzaki, and K. Tsuchiya, “Improvement of room temperature ductility for Mo and Fe modified Ti2AlNb alloy,” Mater. Sci. Eng. A, 528, No. 1, 355–362 (2010), https://doi.org/https://doi.org/10.1016/j.msea.2010.09.003.

    Article  CAS  Google Scholar 

  22. H. Inui, M.H. Oh, A. Nakamura, and M. Yamaguchi, “Room-temperature tensile deformation of polysynthetically twinned (pst) crystals of TiAl,” Acta Metall. Mater., 40, 3095–3104 (1992).

    Article  CAS  Google Scholar 

  23. M.W. Rackel, A. Stark, H. Gabrisch, N. Schell, A. Schreyer, and F. Pyczak, “Orthorhombic phase formation in an Nb-rich γ-TiAl based alloy—an in situ synchrotron radiation investigation,” Acta Mater., 121, 343–351 (2016).

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 52174274).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Youyu Li.

Additional information

Published in Poroshkova Metallurgiya, Vol. 62, Nos. 5–6 (551), pp. 49–59, 2023

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, Y. Microstructural Evolution and Mechanical Properties of the Ti2AlNb Alloy with 3 wt.% W and 0.1 wt.% Y Obtained Using Powder Metallurgy Technique. Powder Metall Met Ceram 62, 302–311 (2023). https://doi.org/10.1007/s11106-023-00394-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-023-00394-1

Keywords

Navigation