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Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates

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Abstract

This article presents the results of a study of new solid solutions formed in the system of diphosphates of alkaline elements and zinc: K2Zn3(P2O7)2–Cs2Zn3(P2O7)2. The obtained materials are promising as matrices for creating phosphors. The formation of phases containing two alkali cations is established on samples obtained by solid-phase synthesis by X-ray phase analysis, and the results of studying their thermal stability are presented.

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Funding

This study was carried out as part of a state task of Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences (subject no. 0081-2022-0008).

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    D. I. Tsygankova, O. Yu. Sinel’shchikova & V. L. Ugolkov

  2. Ulyanov (Lenin) St. Petersburg State Electrotechnical University “LETI,”, 197022, St. Petersburg, Russia

    D. I. Tsygankova

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  1. D. I. Tsygankova
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  2. O. Yu. Sinel’shchikova
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  3. V. L. Ugolkov
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Correspondence to O. Yu. Sinel’shchikova.

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Tsygankova, D.I., Sinel’shchikova, O.Y. & Ugolkov, V.L. Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates. Glass Phys Chem 49, 657–663 (2023). https://doi.org/10.1134/S1087659623600643

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