Skip to main content
SpringerLink
Log in

Catalytic Oxidation of CO over LaNi1/3Sb5/3O6 Synthesized by Different Methods

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Methods for the synthesis of LaNi1/3Sb5/3O6 with a rosiaite structure have been developed using citrate method and coprecipitation followed by annealing. The influence of synthesis conditions on the morphology of the samples has been demonstrated. A comparative analysis of the catalytic properties of LaNi1/3Sb5/3O6 synthesized by various methods, in the reaction of CO oxidation has been carried out. The catalyst synthesized by the citrate method demonstrated the greatest efficiency and stability (the temperature of 90% CO conversion was T90 = 336°C). The LaNi1/3Sb5/3O6 surface was studied before and after catalysis by in situ diffuse reflectance IR spectroscopy, X-ray photoelectron spectroscopy, and temperature-programmed O2 desorption. It has been shown that the catalytic oxidation of CO on the LaNi1/3Sb5/3O6 surface proceeds according to the Mars–van Krevelen mechanism and is accompanied by redox Sb3+ ↔ Sb5+ processes. It has been established that no contamination of the sample surface occurs during the catalysis process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.
Fig. 11.

Similar content being viewed by others

REFERENCES

  1. T. Seiyama, Catal. Rev. 34, 281 (1992). https://doi.org/10.1080/01614949208016313

    Article  CAS  Google Scholar 

  2. A. Eyssler, P. Mandaliev, A. Winkler, et al., J. Phys. Chem. 114, 4584 (2010). https://doi.org/10.1021/jp911052s

    Article  CAS  Google Scholar 

  3. F. F. Tao, Jj. Shan, L. Nguyen, et al., Nat. Commun. 6, 7798 (2015). https://doi.org/10.1038/ncomms8798

    Article  CAS  PubMed  Google Scholar 

  4. H. Chang, E. Bjorgum, O. Mihai, et al., ACS Catal. 10, 3707 (2020). https://doi.org/10.1021/acscatal.9b05154

    Article  CAS  Google Scholar 

  5. X. Zhang, S. D. House, Y. Tang, et al., ACS Sustain. Chem. Eng. 6, 6467 (2018). https://doi.org/10.1021/acssuschemeng.8b00234

    Article  CAS  Google Scholar 

  6. D. Wang, R. Xu, X. Wang, and Y. Li, Nanotecnology 17, 979 (2006). https://doi.org/10.1088/0957-4484/17/4/023

    Article  CAS  Google Scholar 

  7. S. Royer and D. Duprez, ChemCatChem 3, 24 (2011). https://doi.org/10.1002/cctc.201000378

    Article  CAS  Google Scholar 

  8. J. Zhu and Q. Gao, Micropor. Mesopor. Mater. 124, 144 (2009). https://doi.org/10.1016/j.micromeso.2009.05.003

    Article  CAS  Google Scholar 

  9. Sk. Mahammadunnisa, P. Manoj Kumar Reddy, N. Lingaiah, and Ch. Subrahmanyam, Catal. Sci. Technol. 3, 730 (2013). https://doi.org/10.1039/C2CY20641B

    Article  CAS  Google Scholar 

  10. J. Chen, X. Zou, Z. Rui, and H. Ji, Energy Technol. 8, 1900641 (2020). https://doi.org/10.1002/ente.201900641

    Article  CAS  Google Scholar 

  11. A. V. Egorysheva, O. G. Ellert, E. Yu. Liberman, et al., J. Alloys Compd. 777, 655 (2019). https://doi.org/10.1016/j.jallcom.2018.11.008

    Article  CAS  Google Scholar 

  12. E. Yu. Liberman, O. G. Ellert, A. V. Naumkin, et al., Russ. J. Inorg. Chem. 65, 592 (2020). https://doi.org/10.1134/S0036023620040117

    Article  CAS  Google Scholar 

  13. A. V. Egorysheva, O. G. Ellert, E. Yu. Liberman, et al., Russ. J. Inorg. Chem. 67, 2127 (2022). https://doi.org/10.1134/S0036023622601349

    Article  CAS  Google Scholar 

  14. O. G. Ellert, A. V. Egorysheva, S. V. Golodukhina, et al., Russ Chem. Bull. 70, 2397 (2021). https://doi.org/10.1007/s11172-021-3359-0

    Article  CAS  Google Scholar 

  15. T. Birchall, J. A. Connor, and L. H. Hillier, J. Chem. Soc., Dalton Trans. 20, 2003 (1975). https://doi.org/10.1039/dt9750002003

    Article  Google Scholar 

  16. T. A. Carlson, in Photoelectron Auger Spectroscopy (Springer US, Boston, 1975). https://doi.org/10.1007/978-1-4757-0118-0_6

    Book  Google Scholar 

  17. F. Garbassi, Surf. Interface Anal. 2, 165 (1980). https://doi.org/10.1002/sia.740020502

    Article  CAS  Google Scholar 

  18. Yu. A. Teterin, A. Yu. Teterin, I. O. Utkin, and M. V. Ryzhkov, J. Electron Spectros. Relat. Phenomena 137–140, 601 (2004). https://doi.org/10.1016/j.elspec.2004.02.014

    Article  CAS  Google Scholar 

  19. L. H. Little, Infrared Spectra of Adsorbed Species (Academic Press, London, 1966).

    Google Scholar 

  20. N. Yamazoe, J. Fuchigami, M. Kishikawa, and T. Seiyama, Surf. Sci. 86, 335 (1979). https://doi.org/10.1016/0039-6028(79)90411-4

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Shared Facility Center for Physical Methods of Investigation, IGIC RAS, Shared Facility Center “Analytical Center for Problems of Advanced Oil Refining and Petrochemistry,” TIPS RAS, the Center for Research on the Structure of Molecules, INEOS RAS, and the Shared Facility Center, MSU, “Technologies for the production of new nanostructured materials and their comprehensive study.”

Funding

The work was supported by the Russian Science Foundation (project no. 23-23-00113).

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Egorysheva, S. V. Golodukhina, K. R. Plukchi & O. G. Ellert

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    E. Yu. Liberman

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334, Moscow, Russia

    A. V. Naumkin

  4. Topchiev Institute of Pertochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Chistyakov & O. V. Arapova

  5. Faculty of Materials Science, Moscow State University, 119991, Moscow, Russia

    I. V. Kolesnik

Authors
  1. A. V. Egorysheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Golodukhina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. R. Plukchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. Yu. Liberman
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. G. Ellert
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. V. Naumkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. V. Chistyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. I. V. Kolesnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. O. V. Arapova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Egorysheva.

Ethics declarations

The authors declare no conflicts of interest.

Additional information

Translated by G. Kirakosyan

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Egorysheva, A.V., Golodukhina, S.V., Plukchi, K.R. et al. Catalytic Oxidation of CO over LaNi1/3Sb5/3O6 Synthesized by Different Methods. Russ. J. Inorg. Chem. 68, 1725–1736 (2023). https://doi.org/10.1134/S0036023623602106

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023623602106

Keywords:

Search

Navigation