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Evaluation of the Standard Entropy of Crystalline Alkali Metal Borates

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Abstract

A composition–property relationship has been developed that makes it possible to select the optimal values of the standard entropy of alkali metal borates, for which available experimental and reference data vary in wide ranges. This relationship allows one to estimate the standard entropy of unstudied alkali metal borates with sufficient validity. To ensure the reliability of the relationship, a critical analysis of the initial data borrowed from reference books and original experimental works has been carried out. Experimental measurements of low-temperature heat capacity were processed to verify the reliability of the standard entropy values of alkali metal borates presented in the literature.

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Funding

The study was supported by the Russian Science Foundation (project no. 22-17-20005), https://rscf.ru/project/22-17-20005/. Review and critical analysis of the data was carried out with the support of the Ministry of Science and Higher Education of the Russian Federation (State assignment no. 075-00880-22 PR).

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Authors and Affiliations

  1. Vinogradov Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, 664033, Irkutsk, Russia

    A. A. Tupitsin & V. A. Bychinskii

  2. South Urals Federal Research Center of Mineralogy and Geoecology, Ural Branch, Russian Academy of Sciences, territory Ilmen reserve, 456317, Miass, Russia

    A. A. Tupitsin & O. N. Koroleva

  3. Irkutsk State University of Railway Engineering, 664074, Irkutsk, Russia

    S. V. Yas’ko

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    S. V. Fomichev

Authors
  1. A. A. Tupitsin
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  2. S. V. Yas’ko
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  3. V. A. Bychinskii
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  4. O. N. Koroleva
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  5. S. V. Fomichev
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Correspondence to A. A. Tupitsin.

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Translated by G. Kirakosyan

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Tupitsin, A.A., Yas’ko, S.V., Bychinskii, V.A. et al. Evaluation of the Standard Entropy of Crystalline Alkali Metal Borates. Russ. J. Inorg. Chem. 68, 1782–1788 (2023). https://doi.org/10.1134/S0036023623602349

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