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Potentiometric Method for Determining Biologically Non-Degradable Antimicrobial Substances

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Abstract

Ion selective electrodes (ISEs) based on polymer plasticized membranes have been developed for the determination of benzalkonium chloride (alkyldimethylbenzylammonium), the active component being cesium bis-octodecyl-2-sulfonio-closo-decaborate Cs[B10H9S(C18H37)2] (sensor A). For the determination of norfloxacin hydrochloride, the active component is potassium tris-octodecyl-1-ammonio-closo-decaborate K[B10H9N(C18H37)3] (sensor B). It has been shown that the electrodes have a reversible potentiometric response with respect to the analyzed cations in the presence of a number of other inorganic and organic cations. The influence of the concentration of the electrode-active substance on the electrochemical characteristics of the manufactured sensor has been studied. The optimal composition of the ion-sensitive membrane has been found. It has been determined that the developed sensors provide a wide range of detectable concentrations (for sensor A, 2 × 10–7–1 × 10–2; for sensor B, 1 × 10–7–1 × 10–2) and a low detection limit (for sensor A, 1 × 10–7 M; for sensor B, 8 × 10–8 M). New ISEs can be recommended for direct potentiometric detection of free ions in water bodies and water extracts of soils.

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ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Center for Collective Use of the Physical Research Methods of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

The work was supported by the Ministry of Science and Higher Education of the Russia Federation within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences and the Council for Grants of the President of the Russian Federation within the framework of the project MK-207.2022.1.3.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. S. Turyshev, A. S. Kubasov, A. V. Golubev, K. Yu. Zhizhin & N. T. Kuznetsov

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  1. E. S. Turyshev
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  2. A. S. Kubasov
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  3. A. V. Golubev
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  4. K. Yu. Zhizhin
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  5. N. T. Kuznetsov
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Correspondence to E. S. Turyshev.

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Translated by V. Avdeeva

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Turyshev, E.S., Kubasov, A.S., Golubev, A.V. et al. Potentiometric Method for Determining Biologically Non-Degradable Antimicrobial Substances. Russ. J. Inorg. Chem. 68, 1841–1847 (2023). https://doi.org/10.1134/S0036023623602386

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  • DOI: https://doi.org/10.1134/S0036023623602386

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