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Synthesis of Two-Dimensional NiO Nanostructures by a Combination of Programmable Chemical Deposition and Hydrothermal Treatment

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

The synthesis of two-dimensional NiO nanostructures by programmable chemical deposition in combination with the hydrothermal treatment of intermediates in distilled water and in aqueous ammonia solution was studied. Simultaneous thermal analysis was used to determine the dependence of thermal stability and sorption capacity of particles of the intermediates on the parameters of their hydrothermal treatment and on the composition of the dispersion medium. The results of IR spectroscopy and X-ray diffraction analysis helped us to recognize the crystal structure specifics and the set of functional groups for intermediates and for NiO nanopowders formed on their basis. The average size of the coherent scattering regions (CSRs) of the manufactured nickel oxide powders varied from 4.0 ± 0.5 to 8.6 ± 0.8 nm depending on the hydrothermal treatment parameters. Scanning (SEM) and transmission (TEM) electron microscopy showed that the recrystallization of NiO nanoparticles can be tuned depending on the synthesis parameters to yield two-dimensional nanostructures of various shapes and required sizes, ranging from nanosheets of chaotic geometry to flat hexagons with a variable diameter. Due to their anisotropic microstructure, the manufactured nanomaterials can be effectively used in the fabrication of functional components for advanced alternative energy devices (supercapacitor electrodes, solid oxide fuel cells, etc.), including the use of printing technologies.

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ACKNOWLEDGMENTS

The XRD and SEM studies were carried out using shared experimental facilities supported by the Ministry of Science and Higher Education of the Russian Federation as part of the IGIC RAS State assignment.

Funding

The work (in terms of NiO nanopowders preparation) was supported by the Council for Grants of the President of the Russian Federation for the state support of young Russian scientists (MK-1749.2022.1.3).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    T. L. Simonenko, D. A. Dudorova, N. P. Simonenko, E. P. Simonenko & N. T. Kuznetsov

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  1. T. L. Simonenko
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  2. D. A. Dudorova
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  3. N. P. Simonenko
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Correspondence to T. L. Simonenko.

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Translated by O. Fedorova

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Simonenko, T.L., Dudorova, D.A., Simonenko, N.P. et al. Synthesis of Two-Dimensional NiO Nanostructures by a Combination of Programmable Chemical Deposition and Hydrothermal Treatment. Russ. J. Inorg. Chem. 68, 1865–1874 (2023). https://doi.org/10.1134/S0036023623602131

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