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Phase Diagram of the MgF2–SrF2 System and Interactions of Magnesium and Strontium Fluorides with Other Fluorides

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

The phase diagram of the SrF2–MgF2 system has been studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The stability area of the compound SrMgF4 is very small, and its extent is about 20°С between 870 and 890°С. The formation of compounds by magnesium fluoride and strontium fluoride with other metal fluorides is considered in the M versus X coordinates, where M is the cumulative moment of the cation and X is the cation electronegativity. Two areas of compound formation were identified for each of the fluorides. Magnesium and strontium fluorides are amphoteric compounds in terms of the Lewis acid and base theory.

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ACKNOWLEDGMENTS

The facilities of the Shared Facilities Center of the Prokhorov General Physics Institute, Russian Academy of Sciences, and the “Materials Science” Shared Facilities Center of the Ogarev Mordovian State University were used in the work.

Funding

This work was fulfilled as part of the strategic project “New Generation Materials and Energy Saving” implemented at the Ogarev Mordovian State University in accordance with the “Priority 2030” program and in accordance with the scientific work plan of the Prokhorov General Physics Institute, Russian Academy of Sciences (theme “Kvant”).

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  1. Prokhorov General Physics Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    P. P. Fedorov, S. N. Ushakov, V. V. Voronov, A. A. Alexandrov & E. V. Chernova

  2. Ogarev Mordovian State University, 430005, Saransk, Russia

    A. A. Pynenkov, M. A. Uslamina, S. N. Ushakov & K. N. Nishchev

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  1. P. P. Fedorov
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Fedorov, P.P., Pynenkov, A.A., Uslamina, M.A. et al. Phase Diagram of the MgF2–SrF2 System and Interactions of Magnesium and Strontium Fluorides with Other Fluorides. Russ. J. Inorg. Chem. 68, 1789–1798 (2023). https://doi.org/10.1134/S0036023623602325

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