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Vanishing Superstructure: Crystal and Local Structures of Ni3 – xMTe2 (M = Sb, Sn)

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Series of compounds Ni3 – xMTe2 (M = Sb, Sn; x = 0–1) were obtained by high-temperature sealed-tube synthesis and characterized by X-ray powder diffraction and 121Sb and 119Sn Mössbauer spectroscopy. For Ni3–xSnTe2, it was shown that, as х varies from 1 to 0, nickel is distributed over three possible sites, two of which give a total occupancy of 1 and have ordered vacancies. Meanwhile, for Ni3–xSbTe2 and х other than ~0.9–1.0, the vacancy ordering disappears. The temperature dependence of the presence or absence of vacancy ordering was established for Ni2SbTe2; the ordering disappears on heating above 600°C and appears again on cooling.

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Funding

This study was supported by the Russian Foundation for Basic Research (grant 20-33-90209 Post-graduates). X-ray diffraction studies were supported by the Program of Development of the Moscow State University.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    E. A. Stroganova, S. M. Kazakov, P. B. Fabrichnii, M. I. Afanasov & A. N. Kuznetsov

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  1. E. A. Stroganova
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  2. S. M. Kazakov
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  3. P. B. Fabrichnii
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  4. M. I. Afanasov
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  5. A. N. Kuznetsov
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Correspondence to A. N. Kuznetsov.

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Translated by Z. Svitanko

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Stroganova, E.A., Kazakov, S.M., Fabrichnii, P.B. et al. Vanishing Superstructure: Crystal and Local Structures of Ni3 – xMTe2 (M = Sb, Sn). Russ. J. Inorg. Chem. 68, 1714–1724 (2023). https://doi.org/10.1134/S0036023623602246

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