Skip to main content
SpringerLink
Log in

Revision of Data on the Thermochemistry of Scandium Fluorides

  • PHYSICAL METHODS OF INVESTIGATION
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

A critical analysis of the literature data on equilibria of gas-phase reactions involving scandium fluorides and calcium and barium monofluorides has been carried out. The most reliable values of ∆fH°(0) for gaseous ScF3 (–1251 ± 15 kJ/mol), ScF2 (–683 ± 10 kJ/mol), and ScF (–141 ± 6 kJ/mol) are recommended. These values and sequential Sc–F bond dissociation energies are in good agreement with the data of quantum mechanical calculations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. S. Phoung, E. Williams, G. Gaustad, et al., J. Clean. Prod. 401, 136673 (2023). https://doi.org/10.1016/j.jclepro.2023.136673

    Article  CAS  Google Scholar 

  2. Z. Zakaria and S. K. Kamarudin, Int. J. Energy Res. 45, 4871 (2021). https://doi.org/10.1002/er.6206

    Article  CAS  Google Scholar 

  3. Y. Tang, L. P. Ding, X. L. Dou, et al., Inorg. Chem. 61, 15569 (2022). https://doi.org/10.1021/acs.inorgchem.2c02314

    Article  CAS  PubMed  Google Scholar 

  4. H. van der Laan, B. Orberger, C. Dittrich, et al., in Light Metals (Springer, Cham, 2023). https://doi.org/10.1007/978-3-031-22532-1_161

    Book  Google Scholar 

  5. A. B. Botelho, Jr., D. C. R. Espinosa, J. Vaughan, and J. A. S. Tenório, www.sciencedirect.com/science/article/abs/pii/S0892687521003770.

  6. Z. Wei, L. Tan, G. Cai, et al., Phys. Rev. Lett. 124, 255502 (2020). https://doi.org/10.1103/PhysRevLett.124.255502

    Article  CAS  PubMed  Google Scholar 

  7. C. Wang, Theory and Application of Rare Earth Materials (Springer, Singapore, 2023). https://doi.org/10.1007/978-981-19-4178-8_19

    Book  Google Scholar 

  8. M. M. Aleksandrova, N. A. Bendeliani, V. D. Blank, et al., Izv. Akad. Nauk SSSR, Neorg. Mater. 26, 1028 (1990).

    Google Scholar 

  9. P. Melnikov and L. N. Komissarova, J. Phys. Chem. Solids 67, 1899 (2006). https://doi.org/10.1016/j.jpcs.2006.03.006

    Article  CAS  Google Scholar 

  10. F. M. F. de Araujo, D. Duarte-Ruiz, H. D. Saßnick, et al., Inorg. Chem. 62, 4238 (2022). https://doi.org/10.1021/acs.inorgchem.2c04357

    Article  CAS  Google Scholar 

  11. J. W. Hastie, R. Hauge, and J. Margrave, J. Less-Common Met. 39, 309 (1975). https://doi.org/10.1016/0022-5088(75)90205-2

    Article  CAS  Google Scholar 

  12. R. A. Kent, K. F. Zmbov, A. S. Kana’an, et al., J. Inorg. Nucl. Chem. 28, 1419 (1966). https://doi.org/10.1016/0022-1902(66)80174-4

    Article  CAS  Google Scholar 

  13. D. D. Wagman, W. H. Evans, V. B. Parker, et al., Selected Values of Chemical Thermodynamic Properties, National Bureau of Standards, Technical Note, 270-5 (Washington, 1971).

  14. E. L. Osina and L. N. Gorokhov, High Temp. 55, 615 (2017). https://doi.org/10.1134/S0018151X17040150

    Article  CAS  Google Scholar 

  15. E. L. Osina and L. N. Gorokhov, High Temp. 53, 817 (2015). https://doi.org/10.1134/S0018151X15060176

    Article  CAS  Google Scholar 

  16. C. P. Romao, C. R. Morelock, M. B. Johnson, et al., J. Mater. Sci. 50, 3409 (2015).

    Article  CAS  Google Scholar 

  17. K. F. Zmbov and J. L. Margrave, J. Chem. Phys. 47, 3122 (1967). https://doi.org/10.1063/1.1712362

    Article  CAS  Google Scholar 

  18. D. L. Hildenbrand and K. H. Lau, J. Chem. Phys. 102, 3769 (1995). https://doi.org/10.1063/1.468558

    Article  CAS  Google Scholar 

  19. L. V. Gurvich, I. V. Veits, V. A. Medvedev, et al., Thermodynamic Properties of Individual Substances. Reference Edition, in 4 vols. (Nauka, Moscow, 1978–1982) [in Russian].

  20. M. I. Nikitin and A. S. Alikhanyan, Russ. J. Inorg. Chem. 67, 1806 (2022). https://doi.org/10.1134/S0036023622600940

    Article  Google Scholar 

  21. S. Kardahakis, C. Koukounas, and A. Mavridis, J. Chem. Phys. 122, 054312 (2005). https://doi.org/10.1063/1.1834912

    Article  CAS  Google Scholar 

  22. S. R. Langhoff, C. W. Bauschlicher, and H. Partridge, J. Chem. Phys. 89, 396 (1988). https://doi.org/10.1063/1.455481

    Article  CAS  Google Scholar 

  23. V. G. Solomonik and A. A. Mukhanov, J. Struct. Chem. 53, 28 (2012). https://doi.org/10.1134/S0022476612010039

    Article  CAS  Google Scholar 

  24. W. Kohn, Rev. Mod. Phys. 71, 1253 (1999). https://doi.org/10.1103/revmodphys.71.1253

    Article  CAS  Google Scholar 

  25. V. M. Volokhov, T. S. Zyubina, A. V. Volokhov, E. S. Amosova, D. A. Varlamov, D. B. Lempert, and L. S. Yanovskii, Russ. J. Inorg. Chem. 66, 78 (2021). https://doi.org/10.1134/S0036023621010113

    Article  CAS  Google Scholar 

  26. J. H. Thorpe, C. A. Lopez, T. L. Nguyen, et al., J. Chem. Phys. 150, 224102 (2019). https://doi.org/10.1063/1.5095937

    Article  CAS  PubMed  Google Scholar 

Download references

Funding

The study was performed in the framework of the State assignment of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences in the field of basic research.

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. I. Nikitin, D. B. Kayumova & A. S. Alikhanyan

Authors
  1. M. I. Nikitin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. B. Kayumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Alikhanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. S. Alikhanyan.

Ethics declarations

The authors declare no conflicts of interest.

Additional information

Translated by G. Kirakosyan

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nikitin, M.I., Kayumova, D.B. & Alikhanyan, A.S. Revision of Data on the Thermochemistry of Scandium Fluorides. Russ. J. Inorg. Chem. 68, 1776–1781 (2023). https://doi.org/10.1134/S0036023623602283

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023623602283

Keywords:

Search

Navigation