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Solubilities of Components in the Сa(ClO3)2∙NH4Сl–H2O System

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
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Abstract

The Сa(ClO3)2∙NH4Сl–H2O system has been studied in its constituent binary systems and seven inner sections, and its polythermal solubility diagram has been plotted in the range of temperatures from–42.5 to 87.5°С. The solubility diagram features the crystallization fields of ice; calcium chlorate hexahydrate, tetrahydrate, and dihydrate; and ammonium chloride. Three ternary points exist in the system. The system belongs to the complex eutonic type; its components retain their individuality and show good solubility in water. In the [40% Сa(ClO3)2 + 60% H2O]–[NH4Сl] section of the studied system, variations in crystallization temperature, viscosity, density, pH, and refractive indices of the solution have been determined. The thus-obtained results have been used to plot the composition–property diagram of the [40% Сa(ClO3)2 + 60% H2O]–[NH4Сl] section of the Сa(ClO3)2∙NH4Сl–H2O system.

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Funding

This work was supported by ongoing institutional funding. No additional grants to carry out or direct this particular research were obtained.

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, 100170, Tashkent, Uzbekistan

    O. O. Rakhmonov, A. A. Sidikov, Zh. S. Shukurov & A. S. Togasharov

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  1. O. O. Rakhmonov
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  2. A. A. Sidikov
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  3. Zh. S. Shukurov
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  4. A. S. Togasharov
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Correspondence to A. A. Sidikov.

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Translated by O. Fedorova

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Rakhmonov, O.O., Sidikov, A.A., Shukurov, Z.S. et al. Solubilities of Components in the Сa(ClO3)2∙NH4Сl–H2O System. Russ. J. Inorg. Chem. 68, 1829–1833 (2023). https://doi.org/10.1134/S0036023623602271

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