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Synthesis and Structure of the Co(III) Complex with 2-[((E)-(2-(ethylamino)-5-nitrophenylimino)methyl)-4-(phenyldiazenyl)]-Phenol

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Abstract

A new anionic Co(III) complex with 2-[((E)-(2-(ethylamino)-5-nitrophenylimino)methyl)-4-(phenyl diazenyl)]-phenol is prepared and characterized by 1H NMR, IR spectroscopy, and elemental analysis. The crystal structure of the complex is studied by single crystal X-ray diffraction (XRD). From the single crystal XRD data it is found that in the complex, two structurally non-equivalent molecules of the doubly deprotonated ligand are tridentate-chelated by the central Co atom. The cobalt(III) ion is in a slightly distorted octahedral environment of four N and two O atoms.

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Funding

The study was supported by the Ministry of Science and Higher Education of the Russian Federation (State Task in the Scientific Activity Area for 2023 No. FENW-2023-0011).

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Authors and Affiliations

  1. Southern Federal University, Research Institute of Physical and Organic Chemistry, Rostov-on-Don, Russia

    A. S. Burlov & Yu. V. Koshchienko

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    M. A. Kiskin & S. A. Nikolaevskii

  3. Southern Federal University, Research Institute of Physics, Rostov-on-Don, Russia

    V. G. Vlasenko

Authors
  1. A. S. Burlov
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  2. M. A. Kiskin
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  3. S. A. Nikolaevskii
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  4. Yu. V. Koshchienko
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  5. V. G. Vlasenko
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Correspondence to V. G. Vlasenko.

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Russian Text © The Author(s), 2023, published in Zhurnal Strukturnoi Khimii, 2023, Vol. 64, No. 12, 119419.https://doi.org/10.26902/JSC_id119419

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Burlov, A.S., Kiskin, M.A., Nikolaevskii, S.A. et al. Synthesis and Structure of the Co(III) Complex with 2-[((E)-(2-(ethylamino)-5-nitrophenylimino)methyl)-4-(phenyldiazenyl)]-Phenol. J Struct Chem 64, 2351–2357 (2023). https://doi.org/10.1134/S0022476623120065

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