Abstract
CO oxidation at mild condition is significant for industrial process but still challenging nowadays, especially for the non-noble metal catalysts. The preparation method significant affect the catalytic activity of the catalyst. Comparing with cobalt supported on tantalum oxide prepared by impregnation method, Co/Ta2O5 prepared by deposition–precipitation method with urea in this study has smaller particle size, higher specific surface area and better redox properties, and these features make the catalyst exhibit higher catalytic activity for CO oxidation at mild condition. 90% CO conversion was achieved at 130 ℃, and CO was fully converted at 150 ℃. The XPS and DRIFTs results show that Co/Ta2O5 has more oxygen vacancies, and the absorbed CO will react with oxygen. The study may provide a new thought for the preparation of catalysts with high activity at mild condition.
Graphical Abstract
Similar content being viewed by others
References
Kim D, Park D, Song HC et al (2023) Metal encapsulation-driven strong metal-support interaction on Pt/Co3O4 during CO oxidation. ACS Catal 13(8):5326–5335
Wang LC, Liu Q, Huang XS et al (2009) Gold nanoparticles supported on manganese oxides for low-temperature CO oxidation. Appl Catal B-Environ 88(1–2):204–212
Hinojosa-Reyes M, Zanella R, Maturano-Rojas V et al (2016) Gold–TiO2–nickel catalysts for low temperature-driven CO oxidation reaction. Appl Surf Sci 368:224–232
Mahyuddin MH, Staykov A, Shiota Y, Yoshizawa K (2016) Direct conversion of methane to methanol by metal-exchanged ZSM-5 zeolite (metal = Fe Co, Ni, Cu). ACS Catal 6(12):8321–8331
Mei J, Xie J, Qu Z et al (2018) Ordered mesoporous spinel Co3O4 as a promising catalyst for the catalytic oxidation of dibromomethane. Mol Catal 461:60–66
Feng C, Liu X, Zhu T et al (2021) Catalytic oxidation of CO over Pt/TiO2 with low Pt loading: the effect of H2O and SO2. Appl Catal A 622:118218
Qi D, Yao J, Luo X et al (2022) Study on CO catalytic oxidation mechanism on Pd/CeO2 surface models: the effect of oxygen vacancies on CO catalytic oxidation reaction. Chem Pap 76(11):6975–6983
Cui X, Zhang X, Yang Y et al (2022) The noble metals M (M = Pd, Ag, Au) decorated CeO2 catalysts derived from solution combustion method for efficient low-temperature CO catalytic oxidation: effects of different M loading on catalytic performances. Nanotechnology 33(41):415705
Rao R, Liang H, Hu C et al (2022) A melamine-assisted pyrolytic synthesis of Ag–CeO2 nanoassemblys for CO oxidation: activation of Ag–CeO2 interfacial lattice oxygen. Appl Surf Sci 571:151283
Liu M, Liu C, Gouse Peera S et al (2022) Catalytic oxidation mechanism of CO on FeN2-doped graphene. Chem Phys 559:111536
Tang B, Wang S, Li R et al (2019) Urea treated metal organic frameworks-graphene oxide composites derived N-doped Co-based materials as efficient catalyst for enhanced oxygen reduction. J Power Sources 425:76–86
Dey S, Dhal GC, Mohan D et al (2019) Synthesis of highly active cobalt catalysts for low temperature CO oxidation. Chem Data Collect 24:100283
Dey S, Dhal GC, Mohan D et al (2018) Synthesis and characterization of AgCoO2 catalyst for oxidation of CO at a low temperature. Polyhedron 155:102–113
Yigit N, Genest A, Terloev S et al (2022) Active sites and deactivation of room temperature CO oxidation on Co(3)O(4)catalysts: combined experimental and computational investigations. J Phys Condens Matter 34(35):435801
Prasad R, Singh P (2012) A review on CO oxidation over copper chromite catalyst. Catal Rev 54(2):224–279
Wei Y, Li Y, Han D et al (2022) Facile strategy to construct porous CuO/CeO2 nanospheres with enhanced catalytic activity toward CO catalytic oxidation at low temperature. Appl Nanosci 13:3633–3641
Guo J-X, Wu S-Y, Zhong S-Y et al (2021) Janus WSSe monolayer adsorbed with transition-metal atoms (Fe, Co and Ni): excellent performance for gas sensing and CO catalytic oxidation. Appl Surf Sci 565:150558
Zhang T, Wu J, Xu Y et al (2017) Cobalt and cobalt carbide on alumina/NiAl(110) as model catalysts. Catal Sci Technol 7(24):5893–5899
Liu Y, Jia L, Hou B et al (2017) Cobalt aluminate-modified alumina as a carrier for cobalt in Fischer–Tropsch synthesis. Appl Catal A 530:30–36
Jiang Q, Gao J, Yi L et al (2016) Enhanced performance of dye-sensitized solar cells based on P25/Ta2O5 composite films. Appl Phys A 122(4):442
Zhu G, Lin T, Cui H et al (2016) Gray Ta2O5 nanowires with greatly enhanced photocatalytic performance. ACS Appl Mater Interfaces 8(1):122–127
Ismail AA, Faisal M, Harraz FA et al (2016) Synthesis of mesoporous sulfur-doped Ta2O5 nanocomposites and their photocatalytic activities. J Colloid Interface Sci 471:145–154
Yang Y, Kawazoe Y (2018) Prediction of new ground-state crystal structure of Ta2O5. Phys Rev Mater 2(3):034602
Rathnayake D, Perera I, Shirazi-Amin A et al (2020) Mesoporous crystalline niobium oxide with a high surface area: a solid acid catalyst for alkyne hydration. ACS Appl Mater Interfaces 12(42):47389–47396
Aryal B, Morikawa D, Tsuda K et al (2019) Electron diffraction study of crystal structures of (Sr1−xBax)2Nb2O7. Phys Rev Mater 3(4):044405
Dey S, Dhal GC, Mohan D, Prasad R (2019) Advances in transition metal oxide catalysts for carbon monoxide oxidation: a review. Adv Compos Hybrid Mater 2(4):626–656
Cao KLA, Rahmatika AM, Kitamoto Y et al (2021) Controllable synthesis of spherical carbon particles transition from dense to hollow structure derived from Kraft lignin. J Colloid Interface Sci 589:252–263
Li W-J, Tsai S, Wey M-Y (2021) Positive effects of a halloysite-supported Cu/Co catalyst fabricated by a urea-driven deposition precipitation method on the CO-SCR reaction and SO2 poisoning. Catal Sci Technol 11(10):3456–3465
Wei YH, Li SY, Jing J et al (2019) Synthesis of Cu–Co catalysts for methanol decomposition to hydrogen production via deposition-precipitation with urea method. Catal Lett 149(10):2671–2682
Zanella R (2004) Characterization and reactivity in CO oxidation of gold nanoparticles supported on TiO2 prepared by deposition-precipitation with NaOH and urea. J Catal 222(2):357–367
Clause O, Bonneviot L, Che M et al (1991) EXAfs characterization of the adsorbed state of Ni(II) ions in Ni/SiO2 materials prepared by deposition-precipitation. J Catal 130(1):21–28
Qin H, Wang H, Xia Q et al (2023) Efficient CO catalytic oxidation by the combination of cobalt and excellent carrier Ta2O5. Fuel 333:126179
Natile MM, Glisenti A (2002) study of surface reactivity of cobalt oxides: interaction with methanol. Chem Mater 14(7):3090–3099
Luo J-Y, Meng M, Li X et al (2008) Mesoporous Co3O4–CeO2 and Pd/Co3O4–CeO2 catalysts: synthesis, characterization and mechanistic study of their catalytic properties for low-temperature CO oxidation. J Catal 254(2):310–324
Feng Z, Du C, Chen Y et al (2018) Improved durability of Co3O4 particles supported on SmMn2O5 for methane combustion. Catal Sci Technol 8(15):3785–3794
Song W, Poyraz AS, Meng Y et al (2014) Mesoporous Co3O4 with controlled porosity: inverse micelle synthesis and high-performance catalytic CO oxidation at −60 °C. Chem Mater 26(15):4629–4639
Ren Q, Mo S, Peng R et al (2018) Controllable synthesis of 3D hierarchical Co3O4 nanocatalysts with various morphologies for the catalytic oxidation of toluene. J Mater Chem A 6(2):498–509
Jiang Y, Li W, Chen K et al (2022) A rod-like Co3O4 with high efficiency and large specific surface area for lean methane catalytic oxidation. Molecular Catalysis 522:112229
Bae J, Shin D, Jeong H et al (2021) Facet-dependent Mn doping on shaped Co3O4 crystals for catalytic oxidation. ACS Catal 11(17):11066–11074
Lu S, Zhu Q, Dong Y et al (2019) Influence of MnO2 morphology on the catalytic performance of Ag/MnO2 for the HCHO oxidation. Catal Surv Asia 23(3):210–218
Zhong J, Zeng Y, Zhang M et al (2020) Toluene oxidation process and proper mechanism over Co3O4 nanotubes: investigation through in-situ DRIFTS combined with PTR-TOF-MS and quasi in-situ XPS. Chem Eng J 397:125375
Ji L, Lin J, Zeng HC (2000) Metal−support interactions in Co/Al2O3 catalysts: a comparative study on reactivity of support. J Phys Chem B 104(8):1783–1790
Xiong H, Nolan M, Shanks BH, Datye AK (2014) Comparison of impregnation and deposition precipitation for the synthesis of hydrothermally stable niobia/carbon. Appl Catal A 471:165–174
Zhang Z, Li J, Yi T et al (2018) Surface density of synthetically tuned spinel oxides of Co3+ and Ni3+ with enhanced catalytic activity for methane oxidation. Chin J Catal 39(7):1228–1239
Szymanowski H, Zabeida O, Klemberg-Sapieha JE, Martinu L (2005) Optical properties and microstructure of plasma deposited Ta2O5 and Nb2O5 films. J Vac Sci Technol A Vac Surf Films 23(2):241–247
Cai Z, Li J, Liew K, Hu J (2010) Effect of La2O3-dopping on the Al2O3 supported cobalt catalyst for Fischer–Tropsch synthesis. J Mol Catal A Chem 330(1–2):10–17
Zhang J, Chen J, Ren J, Sun Y (2003) Chemical treatment of γ-Al2O3 and its influence on the properties of Co-based catalysts for Fischer-Tropsch synthesis. Appl Catal A 243(1):121–133
Acknowledgements
This study was supported by the Natural Science Foundation of Jiangsu Province (BK20210983).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
Xia, Q., Qin, H., Xia, F. et al. Efficient CO Oxidation by Co/Ta2O5 Prepared by Deposition–Precipitation with Urea. Catal Lett (2024). https://doi.org/10.1007/s10562-023-04551-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10562-023-04551-4