A solid-state 171Yb NMR-spectroscopic characterization of selected divalent ytterbium intermetallics

Josef Maximilian Gerdes; Lars Schumacher; Michael Ryan Hansen; Rainer Pöttgen

doi:10.1515/znb-2023-0070

Published by De Gruyter January 12, 2024

A solid-state ¹⁷¹Yb NMR-spectroscopic characterization of selected divalent ytterbium intermetallics

Josef Maximilian Gerdes , Lars Schumacher , Michael Ryan Hansen and Rainer Pöttgen

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-2023-0070

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Abstract

The intermetallic ytterbium compounds YbZnSn, YbPdSn₂, YbAuIn₂ and their calcium-substituted counterparts Yb_0.5Ca_0.5ZnSn, Yb_0.5Ca_0.5PdSn₂ and Yb_0.5Ca_0.5AuIn₂ were synthesized by reaction of the elements in sealed tantalum tubes in an induction furnace. The samples were characterized by X-ray powder diffraction. Their static, temperature-dependent solid-state ¹⁷¹Yb NMR spectra exhibit strong positive Knight shifts without any significant temperature dependence. The resonance shifts including anisotropy parameters for the ternary compounds have been determined.

Keywords: ytterbium; intermetallics; solid-state NMR spectroscopy

Dedicated to Professor Wolfgang Bensch on the occasion of his 70th birthday.

Corresponding authors: Michael Ryan Hansen, Institut für Physikalische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail: mhansen@uni-muenster.de; and Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail: pottgen@uni-muenster.de

Research ethics: Not applicable.
Author contributions: All authors have accepted responsibility for the entire content of this submitted manuscript and approved the submission.
Competing interests: The authors declare no conflicts of interest regarding this article.
Research funding: This research was funded by Universität Münster and Deutsche Forschungsgemeinschaft (INST 211/1034-1).
Data availability: Data is available from the corresponding author on well-founded request.

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Received: 2023-08-23

Accepted: 2023-09-06

Published Online: 2024-01-12

Published in Print: 2024-01-29

A solid-state ¹⁷¹Yb NMR-spectroscopic characterization of selected divalent ytterbium intermetallics

Abstract

References

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