Skip to main content
SpringerLink
Log in

On Separation of Rare-Earth Metals in Cascade of Sieve Tray Extraction Columns in the Liquid–Liquid Chromatography Mode

  • CHEMISTRY AND TECHNOLOGY OF RARE, SCATTERED, AND RADIOACTIVE ELEMENTS
  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

This article presents the experimental results of extraction chromatography separation in a cascade of sieve tray extraction columns operating in the mode of continuous flow of the disperse mobile phase. The possibility of extraction separation of rare-earth metals in a cascade of sieve tray extraction columns operating in the liquid–liquid chromatography mode is demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

REFERENCES

  1. Friesen, J.B., McAlpine, J.B., Chen, S.-N., and Pauli, G.F., Countercurrent separation of natural products: An update, J. Nat. Prod., 2015, vol. 78, no. 7, pp. 1765–1796. https://doi.org/10.1021/np501065h

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  2. Chami, M.C., Bouju, E., Lequemener, C., de Vaumas, R., Hadji-Minaglou, F., Fernandez, X., and Michel, T., Purification of two valepotriates from Centranthus ruber by centrifugal partition chromatography: From analytical to preparative scale, J. Chromatogr. A, 2018, vol. 1580, pp. 126–133. https://doi.org/10.1016/j.chroma.2018.10.044

    Article  CAS  Google Scholar 

  3. Guilois-Dubois, S., Guyot, S., and Poupard, P., Preparative isolation of apple flavan-3-ols monomers and oligomers using pH-zone-refining centrifugal partition chromatography combined with reversed-phase liquid chromatography, J. Chromatogr. A, 2021, vol. 1653, article no. 462382. https://doi.org/10.1016/j.chroma.2021.462382

    Article  CAS  PubMed  Google Scholar 

  4. Li, H., Zhang, F., Jin, Q., and Zhu, T., Preparative separation and purification of Cyclosporin D from fungus Hypoxylon Spp. by improved closed-loop recycling counter-current chromatography, J. Chromatogr. A, 2021, vol. 1649, article no. 462221. https://doi.org/10.1016/j.chroma.2021.462221

    Article  CAS  PubMed  Google Scholar 

  5. Huang, X.-Y., Pei, D., Liu, J.-F., and Di, D.-L., A review on chiral separation by counter-current chromatography: Development, applications and future outlook, J. Chromatogr. A, 2018, vol. 1531, pp. 1–12. https://doi.org/10.1016/j.chroma.2017.10.073

    Article  CAS  PubMed  Google Scholar 

  6. Sutherland, I., Hewitson, P., Siebers R., Van den Heuvel, R., Arbenz, L., Kinkel, J., and Fisher, D., Scale-up of protein purifications using aqueous two-phase systems: Comparing multilayer toroidal coil chromatography with centrifugal partition chromatography, J. Chromatogr. A, 2011, vol. 1218, no. 32, pp. 5527–5530. https://doi.org/10.1016/j.chroma.2011.04.013

    Article  CAS  PubMed  Google Scholar 

  7. Kostanyan, A.E., Extraction-chromatographic separation of rare-earth metals in the cascade of centrifugal extractors, Zh. Neorg. Khim., 2017, vol. 62, no. 12, pp. 1666–1671. https://doi.org/10.7868/S0044457X17120170

    Article  Google Scholar 

  8. Kostanyan, A.E., Erastov, A.A., and Tsareva, Yu.V., On operation of centrifugal extractors in mode of liquid–liquid chromatography, Khim. Tekhnol., 2020, vol. 21, no. 2, pp. 91–96. https://doi.org/10.31044/1684-5811-2020-21-2-91-96

    Article  Google Scholar 

  9. Galieva, Zh.N., Semenov, A.A., Kostanyan, A.E., and Aldushkin, A.V., Pilot plant for investigation of REE separation by extraction chromatography method on base of cascade of centrifugal extractors, Khim. Tekhnol., 2020, vol. 21, no. 12, pp. 565–573. https://doi.org/10.31044/1684-5811-2020-21-12-565-573

    Article  Google Scholar 

  10. Kostanyan, A.E., Galieva, Z.N., Semenov, A.A., and Aldushkin, A.V. Chromatographic behavior of six lanthanides on a centrifugal mixer–settler extractor cascade, J. Chromatogr. A, 2020, vol. 1634, article no. 461686. https://doi.org/10.1016/j.chroma.2020.461686

    Article  CAS  PubMed  Google Scholar 

  11. Kostanyan, A.E., Tsareva, Yu.V., Belova, V.V., and Teleshova, M.A., On separation of rare-earth metals in series of extraction columns by methods of liquid–liquid chromatography, Khim. Tekhnol., 2021, vol. 22, no. 7, pp. 330–336. https://doi.org/10.31044/1684-5811-2021-22-7-330-336

    Article  Google Scholar 

Download references

Funding

This work was supported by the governmental contract of the Institute of General and Inorganic Chemistry in the field of fundamental scientific research and by the Russian Foundation for Basic Research (project No. 20-53-18007).

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. V. Tsareva, D. A. Vorotov, V. V. Belova & A. E. Kostanyan

Authors
  1. Yu. V. Tsareva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. Vorotov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Belova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. E. Kostanyan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. E. Kostanyan.

Ethics declarations

The authors declare that they have no conflict of interest.

Additional information

Translated by I. Moshkin

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tsareva, Y.V., Vorotov, D.A., Belova, V.V. et al. On Separation of Rare-Earth Metals in Cascade of Sieve Tray Extraction Columns in the Liquid–Liquid Chromatography Mode. Theor Found Chem Eng 57, 1211–1214 (2023). https://doi.org/10.1134/S0040579523050329

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0040579523050329

Keywords:

Search

Navigation