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Sequential Synthesis of Heterometallic Complex Based on the C-Shaped Molybdovanadate: Synthesis, Crystal Structure and Magnetic Properties

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Abstract

A new molybdovanadate-based heterometallic complex, (NH4)17.5[Co0.5Na0.5(H2O)3]2[Co(H2O)4]2[(Cu6(H2O)2(OH)2V9Mo23O108)]·23.5H2O (1), was synthesized through the sequential-synthetic method and fully characterized. Structural analysis reveals that compound 1 exhibits a two-dimensional (2D) framework constructed from the C-shaped {V9Mo23Cu6} anions connected by [Co(H2O)4]2+ and [Co0.5Na0.5(H2O)3]1.5+ units. Compound 1 has a columnar structure with a smooth surface, sharp fringes, and an average size of 40 nm. Photophysical studies show that compound 1 has a band gap of ca. 2.13 eV. Magnetic studies reveal the presence of strong antiferromagnetic interactions in compound 1.

Graphical Abstract

A new molybdovanadate-based heterometallic complexes constructed from the C-shaped {V9Mo23Cu6} clusters linked with [Co(H2O)4]2+ and [Co0.5Na0.5(H2O)3]1.5+ units has been synthesized. Compound 1 has a band gap value of ca. 2.13 eV and exhibits the dominant antiferromagnetic behavior.

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Acknowledgements

The authors are thankful for the financial support from the Jilin Province Science and Technology Development Project (Grant No. 20230508160RC and YDZJ202301ZYTS187), National College Student Innovation and Entrepreneurship Training Program Project (Grant No. 202310199015), Jilin Province health science and technology ability improvement project (Grant No. 2022JC032).

Funding

This work was financially supported by the Jilin Province Science and Technology Development Project (Grant No. 20230508160RC and YDZJ202301ZYTS187), National College Student Innovation and Entrepreneurship Training Program Project (Grant No. 202310199015), Jilin Province health science and technology ability improvement project (Grant No. 2022JC032).

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Authors and Affiliations

  1. School of Pharmaceutical Sciences, Changchun University of Chinese Medicine, Changchun, 130117, People’s Republic of China

    Qiao Gao, Xin-Yue Zhang & De-Hui Li

  2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Lin Xu

Authors
  1. Qiao Gao
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  2. Xin-Yue Zhang
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  3. De-Hui Li
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Contributions

QG done the formal analysis, investigation, data curation, writing-original draft, and funding acquisition. XYZ done validation, and data collection. DHL done formal analysis, validation, and funding acquisition. LX done writing-review & editing and investigation. All authors have checked the manuscript and have agreed to the submission.

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Correspondence to De-Hui Li.

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Gao, Q., Zhang, XY., Li, DH. et al. Sequential Synthesis of Heterometallic Complex Based on the C-Shaped Molybdovanadate: Synthesis, Crystal Structure and Magnetic Properties. J Clust Sci 35, 1083–1089 (2024). https://doi.org/10.1007/s10876-023-02533-5

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  • DOI: https://doi.org/10.1007/s10876-023-02533-5

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