Abstract
Reducing carbon dioxide emissions during production is one of the main trends in modern oil and gas chemistry. One of the most realistic possibilities for achieving this is to involve carbon dioxide generated in technological processes as a feedstock for producing gas chemical products. The maximum effect can be achieved in the production of large-scale chemicals, such as syngas, hydrogen, and methanol. We consider such possibilities and present a new combined autothermal process for the joint production of hydrogen and methanol based on non-catalytic matrix conversion of natural gas into syngas, which allows one to almost avoid CO2 emissions.
Similar content being viewed by others
REFERENCES
Paris Agreement, United Nations, 2015, available at: https://unfccc.int/files/meetings/paris_nov_2015/application/pdf/paris_agreement_russian_.pdf. Accessed on April 9, 2023.
IPCC Special Report on Carbon Dioxide Capture and Storage, Metz, B., Davidson, O., de Coninck, H., Loos, M., and Meyer, L., Eds., Cambridge University Press,UK, 2005, available at: www.ipcc.ch/report/carbon-dioxide-capture-and-storage/. Accessed on April 9, 2023.
Zhang, Z., Oh, D.-H., Nguyen, V.D., Lee, C.-H., and Lee, J.-C., Energy Fuels, 2023, vol. 37, pp. 5961–5975. https://doi.org/10.1021/acs.energyfuels.3c00122
Kuznetsov, N.Yu., Maksimov, A.L., and Beletskaya, I.P., Russ. J. Org. Chem., 2022, vol. 58, no. 12, pp. 1681–1711. https://doi.org/10.31857/S0514749222120011
Dement’ev, K.I., Dement’eva, O.S., Ivantsov, M.I., Kulikova, M.V., Magomedova, M.V., Maximov, A.L., Lyadov, A.S., Starozhitskaya, A.V., and Chudakova, M.V., Petroleum Chem., 2022, vol. 62, pp. 445–474. https://doi.org/10.31857/S0028242122030017
Makaryan, I.A., Sedov, I.V., and Savchenko, V.I., Katal. Prom., 2023, vol. 23, no. 4, pp. 6–32. https://doi.org/10.18412/1816-0387-2023-4-6-32
Vasudevan, S., Farooq, S., Karimi, I.A., Saeys, M., Quah, M.C.G., and Agrawal, R., Energy, 2016, vol. 103, pp. 709–714.https://doi.org/10.1016/j.energy.2016.02.154
Cavaliere, A. and de Joannon, M., Prog. Energy Combust. Sci., 2004, vol. 30, pp. 329–366. https://doi.org/10.1016/j.pecs.2004.02.003
Mi, J., Li, P., Wang, F., Cheong, K.-P., and Wang, G., Energy Fuels, 2021, vol. 35, pp. 7572–7607. https://doi.org/10.1021/acs.energyfuels.1c00511
Lapidus, A.L., Golubeva, I.A., and Zhagfarov, F.G., Gazokhimiya. Uchebnoe posobie (Gas Chemistry, A Textbook), Moscow: TsentrLit-NefteGaz, 2014.
Afanas’ev, S.V., Sadovnikov, A.A., Gartman, V.G., Obysov, A.V., and Dul’nev, A.V., Promyshlennyi kataliz v gazokhimii (Industrial Catalysis in Gas Chemistry), Afanas’ev, S.V., Ed., Samara: Izd. SNTs RAN, 2018.
Makaryan, I.A., Salgansky, E.A., Arutyunov, V.S., and Sedov, I.V., Energies, 2023, vol. 16, p. 2916. https://doi.org/10.3390/en16062916
Soleimani, S. and Lehner, M., Energies, 2022, vol. 15, p. 7159. https://doi.org/10.3390/en15197159
Minh, D.P., Pham, X.-H., Siang, T.J., and Vo, D.-V.N., Appl. Catal., A, 2021, vol. 621, p. 118202. https://doi.org/10.1016/j.apcata.2021.118202
Nikitin, A., Ozersky, A., Savchenko, V., Sedov, I., Shmelev, V., and Arutyunov, V., Chem. Eng. J., 2019, vol. 377, art. 129883. https://doi.org/10.1016/j.cej.2019.01.162
Dorofeenko, S.O. and Polianczyk, E.V., Chem. Eng. J., 2016, vol. 292, pp. 183–189. https://doi.org/10.1016/j.cej.2016.02.013
Savchenko, V.I., Nikitin, A.V., Zimin, Ya.S., Ozerskii, A.V., Sedov, I.V., and Arutyunov, V.S., Chem. Eng. Res. Des., 2021, pp. 250–258. https://doi.org/10.1016/j.cherd.2021.09.009
Savchenko, V.I., Zimin, Ya.S., Nikitin, A.V., Sedov, I.V., Arutyunov, V.S., Russ. J. Appl. Chem., 2022, vol. 95, pp. 1045–1052. https://doi.org/10.1134/S107042722208016X
Nikitin, A.V., Starostin, A.D., Ozerskii, A.V., Zimin, Ya.S., and Arutyunov, V.S., RF Patent RU 217582 U1, publ. April 6, 2023.
Peng, D.Y. and Robinson, D.B., Ind. Eng. Chem. Fundam., 1976, vol. 15, no. 1, pp. 59–64.
Narochnyi, G.B., Savost’yanov, A.P., Zubkov, I.N., Dul’nev, A.V., and Yakovenko, R.E., Katal. Prom., 2021, vol. 21, pp. 406–412. https://doi.org/10.18412/1816-0387-2021-6-406-412
Funding
The study was supported by the Russian Science Foundation (project no. 22-13-00324).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
ETHICS APPROVAL AND CONSENT TO PARTICIPATE
This work does not contain any studies involving human and animal subjects.
CONFLICT OF INTEREST
The authors of this work declare that they have no conflict of interest.
Additional information
Dedicated to the Anniversary of Corresponding Member of the RAS Albert L’vovich Lapidus
Translated by G. Kirakosyan
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Arutyunov, V.S., Nikitin, A.V., Savchenko, V.I. et al. Combined Production of Hydrogen and Methanol without CO2 Emission Based on Matrix Conversion of Natural Gas. Dokl Chem 513, 361–366 (2023). https://doi.org/10.1134/S0012500823601018
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0012500823601018