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A Voltammetric Sensor Based on Carbon Veil Modified with Graphene and Phytosynthesized Cobalt Oxide Nanoparticles for the Determination of Food Dyes Tartrazine (E102) and Allura Red (E129)

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Abstract

A voltammetric sensor based on carbon veil modified with graphene nanoplates and phytosynthesized cobalt oxide Co3O4 nanoparticles is proposed for the determination of tartrazine (E102) and allura red AC (E129). The use of a composite nanomodifier contributes to an increase and better separation of the oxidation currents of azo dyes on their simultaneous presence. The process of the oxidation of azo dyes is irreversible, involves two electrons, and has a mixed nature. The sensor is characterized by a low limit of detection: 30 nM for E102 and 27 nM for E129, and in the inversion mode 16 and 3 nM, respectively. The analytical range the dyes is 0.1–15 µM. The sensor has been successfully used in the analysis of fruit jellies and beverage. The advantages of the developed sensor are high performance and operational characteristics, ease of manufacture, and low cost.

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REFERENCES

  1. Karimi-Maleh, H., Beitollahi, H., Senthil Kumar, P., Tajik, S., Jahani, P.M., Karimi, F., Karaman, C., Vasseghian, Y., Baghayeri, M., Rouhi, J., Show, P.-L., Rajendran, S., Fu, L., and Zare, N., Food Chem. Toxicol., 2022, vol. 164, p. 112961.

    Article  CAS  PubMed  Google Scholar 

  2. John, A., Yang, H.-H., Muhammad, S., Khan, Z.I., Yu, H., Luqman, M., Tofail, M., Hussain, M.I., and Awan, M.U.F., Appl. Sci., 2022, vol. 12, p. 7084.

    Article  CAS  Google Scholar 

  3. Scientific opinion on the re-evaluation Tartrazine (E 102), EFSA J., 2009, vol. 7, no. 11, p. 1331.

  4. European food safety authority, refined exposure assessment for Allura Red AC (E 129), EFSA J., 2015, vol. 13, p. 4007.

  5. SanPiN 2.3.2.1293-03: Hygienic Requirements for the Use of Food Additives, Moscow: Minzdrav Rossii, 2003. 416 s.

  6. Wang, M. and Zhao, J., Sens. Actuators, B, 2015, vol. 216, p. 578.

    Article  CAS  Google Scholar 

  7. Zhang, Y., Hu, L., Liu, X., Liu, B., and Wu, K., Food Chem., 2015, vol. 166, p. 352.

    Article  CAS  PubMed  Google Scholar 

  8. Wang, M. and Zhao, J., J. Electrochem. Soc., 2015, vol. 162, no. 6, p. H321.

    Article  CAS  Google Scholar 

  9. Stozhko, N.Yu., Khamzina, E.I., Bukharinova, M.A., and Tarasov, A.V., Sensors, 2022, vol. 22, no. 11, p. 4092.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  10. Ziyatdinova, G., Titova, M., and Davletshin, R., Polymers, 2022, vol. 14, no. 24, p. 5429.

    Article  CAS  PubMed  Google Scholar 

  11. Lipskikh, O.I., Korotkova, E.I., Barek, J., Vyskocil, V., Saqib, M., and Khristunova, E.P., Talanta, 2020, vol. 218, p. 121136.

    Article  CAS  PubMed  Google Scholar 

  12. Wu, J.-H. and Lee, H.-L., Microchem. J., 2020, vol. 158, p. 105133.

    Article  CAS  Google Scholar 

  13. Gimadutdinova, L., Ziyatdinova, G., and Davletshin, R., Sensors, 2023, vol. 23, no. 3, p. 1094.

    Article  CAS  PubMed  Google Scholar 

  14. Blanco, E., Arias, L., Vázquez, L., del Pozo, M., Sanchez, L., Petit-Dominguez, M.D., Quintana, C., and Casero, E., FlatChem, 2020, vol. 23, p. 100185.

    Article  CAS  Google Scholar 

  15. Rodríguez, J.A., Juárez, M.G., Galán-Vidal, C.A., Miranda, J.M., and Barrado, E., Electroanalysis, 2015, vol. 27, no. 10, p. 2329.

    Article  Google Scholar 

  16. Penagos-Llanos, J., García-Beltrán, O., Calderón, J.A., Hurtado-Murillo, J.J., Nagles, E., and Hurtado, J.J., J. Electroanal. Chem., 2019, vol. 852, p. 113517.

    Article  CAS  Google Scholar 

  17. Brainina, K.Z., Bukharinova, M.A., Stozhko, N.Y., Sokolkov, S.V., Tarasov, A.V., and Vidrevich, M.B., Sensors, 2020, vol. 20, no. 6, p. 1800.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  18. Stozhko, N.Y., Khamzina, E.I., and Bukharino-va, M.A., Nanomaterials, 2022, vol. 12, no. 23, p. 4197.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  19. Vinayagam, R., Hebbar, A., Senthil Kumar, P., Rangasamy, G., Varadavenkatesan, T., Murugesan, G., Srivastava, S., Concepta Goveas, L., Manoj Kumar, N., and Selvaraj, R., Environ. Res., 2023, vol. 216, p. 114766.

    Article  CAS  PubMed  Google Scholar 

  20. Vijayalakshmi, S., Sharmila Lydia, I., and Vasudevan, D., Indian J. Adv. Chem. Sci., 2019, vol. 7, no. 4, p. 122.

    CAS  Google Scholar 

  21. Anuradha, C.T. and Raji, P., Mater. Res., 2019, vol. 6, no. 9, p. 095063.

    CAS  Google Scholar 

  22. Memon, S.A., Hassan, D., Buledi, J.A., Solangi, A.R., Memon, S.Q., and Palabiyik, I.M., Microchem. J., 2020, vol. 159, p. 105480.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The authors are grateful to M.V. Medvedeva, Ural Federal University for assistance in conducting impedimetric measurements.

Funding

The study was supported by the Russian Science Foundation, project no. 23-23-00353, https://rscf.ru/project/23-23-00353/.

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Authors and Affiliations

  1. Ural State University of Economics, 620144, Ekaterinburg, Russia

    M. A. Buharinova, E. I. Khamzina, V. Yu. Kolotygina & N. Yu. Stozhko

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  1. M. A. Buharinova
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  2. E. I. Khamzina
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  3. V. Yu. Kolotygina
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  4. N. Yu. Stozhko
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Correspondence to N. Yu. Stozhko.

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Translated by V. Kudrinskaya

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Buharinova, M.A., Khamzina, E.I., Kolotygina, V.Y. et al. A Voltammetric Sensor Based on Carbon Veil Modified with Graphene and Phytosynthesized Cobalt Oxide Nanoparticles for the Determination of Food Dyes Tartrazine (E102) and Allura Red (E129). J Anal Chem 78, 1679–1687 (2023). https://doi.org/10.1134/S106193482312002X

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  • DOI: https://doi.org/10.1134/S106193482312002X

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