Abstract—
The work is devoted to the study of the tribological properties of functional coatings based on the FeO oxide matrix, additionally doped with boron oxide B2O3 and zirconium dioxide ZrO2. The coatings are obtained by highly concentrated short-pulse laser processing of powder compositions previously applied to metal surfaces. The resulting coatings are subject to wear tests under conditions of dry sliding friction with fixation of the friction coefficient, depending on the applied load and the composition of the powder composition. The results give an idea of the degree of change in the coefficient of friction of coatings depending on the powder compositions, as well as their alloying. It has been confirmed that additional alloying with boron oxide has a positive effect on the tribological performance of the coating; in particular, the introduction of 4% boron oxide reduces the coefficient of dry sliding friction to a unique 0.09–0.10. At the same time, a more stable scuffing resistance of friction surfaces is observed, confirmed by studies of surface roughness after testing. A feature of the tribological behavior of the coatings under study is the excessively high temperature background of the tests, reaching 300°C. High temperature and the presence of oxide structures are a catalyst for the formation of stable tribological structures between the rubbing surfaces. The nature of the tribostructures is self-organizing in a “glaze” type and has the property of recovery under friction conditions. After the formation of tribostructures in the friction zone, a significant decrease in temperature and an abrupt decrease in the friction coefficient are observed. With an increase in the amount of boron oxide, the friction coefficient does not decrease so significantly and the minimum value of the dry friction coefficient corresponds to 0.14–0.15, which is caused by a decrease in the cohesive strength of the coating.
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REFERENCES
Kolesnikov, I.V., Motrenko, P.D., Kolesnikov, V.I., and Manturov, D.S., Povyshenie iznosostoikosti metallicheskikh i metallopolimernykh tribosistem putem formirovaniya struktury i svoistv ikh poverkhnostnogo sloya (Increasing the Wear Resistance of Metal and Metal–Polymer Tribosystems by Forming the Structure and Properties of their Surface Layer), Moscow: VINITI RAN, 2021.
Chernyshev, S.L., Kolesnikov, V.I., Vereskun, V.D., Kolesnikov, I.V., Manturov, D.S., and Ozyabkin, A.L., Elastic-dissipative properties of heavy-loaded modified friction pairs, J. Frict. Wear, 2023, vol. 44, no. 1, pp. 34–41. https://doi.org/10.3103/S1068366623010026
Gök, M.S., Kücük, Y., Erdoğan, A., Öge, M., Kanca, E., and Günen, A., Dry sliding wear behavior of borided hot-work tool steel at elevated temperatures, Surf. Coat. Technol., 2017, vol. 328, pp. 54–62. https://doi.org/10.1016/j.surfcoat.2017.08.008
Kharanzhevskiy, E.V., Ipatov, A.G., Krivilyov, M.D., Makarov, A.V., Gil’mutdinov, F.Z., and Volkova, E.G., Ultralow friction behaviour of B4C-BN-MeO composite ceramic coatings deposited on steel, Surf. Coat. Technol., 2020, vol. 390, p. 125664. https://doi.org/10.1016/j.surfcoat.2020.125664
Dreano, A., Fouvry, S., Sao-Joao, S., Galipaud, J., and Guillonneau, G., The formation of a cobalt-based glaze layer at high temperature: A layered structure, Wear, 2019, pp. 440–441. https://doi.org/10.1016/j.wear.2019.203101
Dreano, A., Fouvry, S., and Guillonneau, G., Understanding and formalization of the fretting-wear behavior of a cobalt-based alloy at high temperature, Wear, 2020, pp. 452–453. https://doi.org/10.1016/j.wear.2020.203297
Dreano, A., Baydoun, S., Fouvry, S., Nar, S., and Alvarez, P., Influence of a pre-existing glaze layer on the fretting-wear response of HS25 cobalt-based alloy subjected to various temperature conditions, Wear, 2022, pp. 488–489. https://doi.org/10.1016/j.wear.2021.204144
Rosenkranz, A., Costa, H.L., Baykara, M.Z., and Martini, A., Synergetic effects of surface texturing and solid lubricants to tailor friction and wear—a review, Tribol. Int., 2021, vol. 155, p. 106792. https://doi.org/10.1016/j.triboint.2020.106792
Sassatelli, P., Bolelli, G., Gualtieri, M.L., Heinonen, E., Honkanen, M., Lusvarghi, L., Manfredini, T., Rigon, R., and Vippola, M., Properties of HVOF-sprayed stellite-6 coatings, Surf. Coat. Technol., 2017, vol. 338, pp. 45–62. https://doi.org/10.1016/j.surfcoat.2018.01.078
Ipatov, A.G. and Kharanzhevskiy, E.V., The tribological properties of superhard and functional coatings based on carbide and boron nitride, J. Frict. Wear, 2019, vol. 40, no. 6, pp. 588–592. https://doi.org/10.3103/S1068366619060114
Kharanzhevskiy, E.V., Ipatov, A.G., Makarov, A.V., Gil’mutdinov, F.Z., Soboleva, N.N., and Krivilyov, M.D., Tribological performance of boron-based superhard coatings sliding against different materials, Wear, 2021, vol. 477, p. 203835. https://doi.org/10.1016/j.wear.2021.203835
Kharanzhevskiy, E.V., Ipatov, A.G., Makarov, A.V., Gil’mutdinov, F.Z., Soboleva, N.N., and Krivilyov, M.D., Effect of oxygen in surface layers formed during sliding wear of Ni–ZrO2 coatings, Surf. Coat. Technol., 2022, vol. 434, p. 128174. https://doi.org/10.1016/j.surfcoat.2022.128174
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The authors are grateful to the Russian Science Foundation for financial support (project no. 19-79-20 012).
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Ipatov, A.G., Kharanzhevskiy, E.V., Shmykov, S.N. et al. Tribotechnical Properties of Ceramic Antifriction Coatings Based on Iron Oxide and Boron Oxide. J. Frict. Wear 44, 286–290 (2023). https://doi.org/10.3103/S1068366623050045
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DOI: https://doi.org/10.3103/S1068366623050045