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Mesoporous Gallium-Based Catalysts for Oxidative Dehydrogenation of Propane in the Presence of Carbon Dioxide

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Abstract

The present study investigates a series of gallium-based catalysts supported on natural and composite aluminosilicate mesoporous supports in the CO2-assisted oxidative dehydrogenation of propane. The catalyst supports were prepared by mixing a functional material with a boehmite binder, the functional materials being derived from natural halloysite nanotubes (HNTs). Three different supports were used: pristine HNTs; HNTs with MCM-41 synthesized around halloysite; and HNTs with MCM-41 synthesized inside the halloysite lumen. The CO2-assisted oxidative propane dehydrogenation was tested in the range of 550–700°C at a CO2/C3H8 molar ratio of 2.0. All the catalysts showed comparable propane conversion (from 10–13% to 70–80%) and propylene selectivity (from 80–84 to 30–32%). The highest propylene space-time yield (6.5 mol kgcat–1 h–1) was observed for the Ga/HNT catalyst at 650°C.

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Funding

This study was funded by the Ministry of Science and Higher Education of the Russian Federation (theme: Metastable Catalysts Prepared by Laser Treatment in a Liquid for Efficient Dehydrogenation of Alkanes; agreement no. 075-15-2021-1386, code 13.2251.21.0100).

The study was performed at the Northwestern Polytechnical University and supported by the National Natural Science Foundation of China (NSFC, project no. SQ2020YFE010397).

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Authors and Affiliations

  1. Gubkin Russian State University of Oil and Gas (National Research University), 119991, Moscow, Russia

    D. P. Melnikov, E. M. Smirnova, M. V. Reshetina, A. P. Glotov, A. A. Novikov, P. A. Gushchin & V. A. Vinokurov

  2. State Key Laboratory of Solidification Processing, Center for Nano Energy Materials, School of Materials Science and Engineering, Northwestern Polytechnical University and Shaanxi Joint Laboratory of Graphene (NPU), 710072, Xi’an, China

    H. Q. Wang

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  1. D. P. Melnikov
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  2. E. M. Smirnova
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  3. M. V. Reshetina
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  4. A. P. Glotov
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  5. A. A. Novikov
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  6. P. A. Gushchin
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  7. H. Q. Wang
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  8. V. A. Vinokurov
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Correspondence to D. P. Melnikov.

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Melnikov, D.P., Smirnova, E.M., Reshetina, M.V. et al. Mesoporous Gallium-Based Catalysts for Oxidative Dehydrogenation of Propane in the Presence of Carbon Dioxide. Pet. Chem. 63, 1228–1234 (2023). https://doi.org/10.1134/S0965544123090049

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