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Novel Fe3O4–ZnO Carbonized Rice Husk Modified Nano Composite Sorbent for Removal of Humic Acid from Aqueous Media

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Abstract

In this study, we used a novel absorbent ZnO/Fe3O4/carbonized rice husk (CRH) composite for removal of humic acid (HA) from aqueous solutions. The ZnO/Fe3O4/CRH composite was produced via chemical procedure under heating and vigorous stirring conditions. The ZnO/Fe3O4/CRH were characterized by SEM, FT-IR, XRD and VSM techniques. The analysis results show that the ZnO/Fe3O4/CRH can be used as an appropriate adsorbent. Variables affecting the adsorption of humic acid such as: pH, HA concentration, adsorbent amount and contact time were investigated. The kinetics of adsorption of HA on ZnO/Fe3O4/CRH composite could be expressed by the pseudo-second order kinetic model and Langmuir model was found to be more applicable in interpreting between mentioned adsorbent and adsorbent as suitable adsorption isotherms. Furthermore, the ZnO/Fe3O4/CRH nanocomposites could be also served as convenient recyclable sorbent because of their magnetic properties.

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References

  • Aboua KN, Yobouet YA, Yao KB, Gone DL, Trokourey A (2015) Investigation of dye adsorption onto activated carbon from the shells of Macoré fruit. J Environ Manag 156:10–14

    Article  CAS  Google Scholar 

  • Alam MM, Hossain MA, Hossain MD, Johir MAH, Hossen J, Rahman MS, Zhou JL, Hasan ATMK, Karmakar AK, Ahmed MB (2020) The potentiality of rice husk-derived activated carbon: from synthesis to application. Processes 8(2):203

    Article  CAS  Google Scholar 

  • Alomar T, Qiblawey H, Almomani F, Al-Raoush RI, Han DS, Ahmad NM (2023) Recent advances on humic acid removal from wastewater using adsorption process. J Water Process Eng 53:103679

    Article  Google Scholar 

  • Brum MC, Oliveira JF (2007) Removal of humic acid from water by precipitate flotation using cationic surfactants. Miner Eng 20(9):945–949

    Article  CAS  Google Scholar 

  • Cheng S, Chen Q, Xia H, Zhang L, Peng J, Lin G, Liao X, Jiang X, Zhang Q (2018) Microwave one-pot production of ZnO/Fe3O4/activated carbon composite for organic dye removal and the pyrolysis exhaust recycle. J Clean Prod 188:900–910

    Article  CAS  Google Scholar 

  • Daifullah AAM, Girgis BS, Gad HMH (2004) A study of the factors affecting the removal of humic acid by activated carbon prepared from biomass material. Colloids Surf A 235(1–3):1–10

    Article  CAS  Google Scholar 

  • Farrokhi M, Hosseini S-C, Yang J-K, Shirzad-Siboni M (2014) Application of ZnO–Fe3O4 nanocomposite on the removal of azo dye from aqueous solutions: kinetics and equilibrium studies. Water Air Soil Pollut 225:1–12

    Article  CAS  Google Scholar 

  • Foroutan R, Mohammadi R, Ahmadi A, Bikhabar G, Babaei F, Ramavandi B (2022) Impact of ZnO and Fe3O4 magnetic nanoscale on the methyl violet 2B removal efficiency of the activated carbon oak wood. Chemosphere 286:131632

    Article  CAS  PubMed  Google Scholar 

  • Gaffney JS, Marley NA, Clark SB (1996) Humic and fulvic acids: isolation, structure, and environmental role. ACS Publications, Washington

    Book  Google Scholar 

  • Geng N, Chen W, Xu H, Lin T, Ding M, Wang Y, Tao H, Hu K (2019) Preparation of Fe3O4/TiO2-N-GO sonocatalyst and using for humic acid removal with the assist of ultrasound. Mater Sci Semicond Process 102:104593

    Article  CAS  Google Scholar 

  • Heijman SGJ, Van Paassen AM, Van Der Meer WGJ, Hopman R (1999) Adsorptive removal of natural organic matter during drinking water treatment. Water Sci Technol 40(9):183–190

    Article  CAS  Google Scholar 

  • Kadirvelu K, Kavipriya M, Karthika C, Vennilamani N, Pattabhi S (2004) Mercury (II) adsorption by activated carbon made from sago waste. Carbon 42(4):745–752

    Article  CAS  Google Scholar 

  • Kasprzyk-Hordern B, Ziółek M, Nawrocki J (2003) Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment. Appl Catal B 46(4):639–669

    Article  CAS  Google Scholar 

  • Katal R, Baei MS, Rahmati HT, Esfandian H (2012) Kinetic, isotherm and thermodynamic study of nitrate adsorption from aqueous solution using modified rice husk. J Ind Eng Chem 18(1):295–302

    Article  CAS  Google Scholar 

  • Katal R, Pourkarimi S, Bahmani E, Dehkordi HA, Ghayyem MA, Esfandian H (2013) Synthesis of Fe3O4/polyaniline nanocomposite and its application for nitrate removal from aqueous solutions. J Vinyl Add Tech 19(2):147–156

    Article  CAS  Google Scholar 

  • Kaykioglu G, Gunes E (2016) Comparison of acid red 114 dye adsorption by Fe3O4 and Fe3O4 impregnated rice husk ash. J Nanomater 2016:1

    Article  Google Scholar 

  • Khaledyan E, Alizadeh K, Mansourpanah Y (2019) Synthesis of magnetic nanocomposite core–shell Fe3O4@ MCM-41-NH2 and its application for removal of congo red from aqueous solutions. Iran J Sci Technol Trans A Sci 43:801–811

    Article  Google Scholar 

  • Lawagon CP, Amon REC (2020) Magnetic rice husk ash’cleanser’as efficient methylene blue adsorbent. Environ Eng Res 25(5):685–692

    Article  Google Scholar 

  • Liao P, Ismael ZM, Zhang W, Yuan S, Tong M, Wang K, Bao J (2012) Adsorption of dyes from aqueous solutions by microwave modified bamboo charcoal. Chem Eng J 195:339–346

    Article  Google Scholar 

  • Lin C-F, Huang Y-J, Hao OJ (1999) Ultrafiltration processes for removing humic substances: effect of molecular weight fractions and PAC treatment. Water Res 33(5):1252–1264

    Article  CAS  Google Scholar 

  • Lowe J, Hossain MM (2008) Application of ultrafiltration membranes for removal of humic acid from drinking water. Desalination 218(1–3):343–354

    Article  CAS  Google Scholar 

  • MacCarthy P, Malcolm RL, Clapp CE, Bloom PR (1990) An introduction to soil humic substances. In: MacCarthy P, Bloom PR, Clapp CE, Malcolm RL (eds) Humic substances in soil and crop sciences: selected readings. Soil Science Society of America, Madison, WI, pp 1–12

  • Matilainen A, Sillanpää M (2010) Removal of natural organic matter from drinking water by advanced oxidation processes. Chemosphere 80(4):351–365

    Article  ADS  CAS  PubMed  Google Scholar 

  • Mazloumi S, Nabizadeh NR, Naseri S, Nadafi K, Nazmara S, Mahvi AH (2009) Efficiency of domestic reverse osmosis (RO) in removal of trihalomethanes (THMS) from drinking water. J Environ Health Sci 6(4):301–306

    Google Scholar 

  • Menya E, Olupot PW, Storz H, Lubwama M, Kiros Y (2018a) Characterization and alkaline pretreatment of rice husk varieties in Uganda for potential utilization as precursors in the production of activated carbon and other value-added products. Waste Manag 81:104–116

    Article  CAS  PubMed  Google Scholar 

  • Menya E, Olupot PW, Storz H, Lubwama M, Kiros Y (2018b) Production and performance of activated carbon from rice husks for removal of natural organic matter from water: a review. Chem Eng Res Des 129:271–296

    Article  CAS  Google Scholar 

  • Menya E, Olupot PW, Storz H, Lubwama M, Kiros Y (2020) Synthesis and evaluation of activated carbon from rice husks for removal of humic acid from water. Biomass Convers Biorefin 12:1–20

    Google Scholar 

  • Metsämuuronen S, Sillanpää M, Bhatnagar A, Mänttäri M (2014) Natural organic matter removal from drinking water by membrane technology. Sep Purif Rev 43(1):1–61

    Article  Google Scholar 

  • Moayedi H, Aghel B, Nguyen H, Rashid ASA (2019) Applications of rice husk ash as green and sustainable biomass. J Clean Prod 237:117851

    Article  CAS  Google Scholar 

  • Nekoeinia M, Yousefinejad S, Abdi MR, Ebrahimpour B (2017) Magnetic solid—phase extraction of trace amounts of nickel in food samples using polydopamine coated Fe3O4 nanoparticles. Iran J Anal Chem 4(2):1–9

    CAS  Google Scholar 

  • Nsaifabbas M, Abbas FS (2014) Application of rice husk to remove humic acid from aqueous solutions and profiting from waste leftover. WSEAS Trans Biol Biomed 11:62–69

    Google Scholar 

  • Ouyang K, Zhu C, Zhao Y, Wang L, Xie S, Wang Q (2015) Adsorption mechanism of magnetically separable Fe3O4/graphene oxide hybrids. Appl Surf Sci 355:562–569

    Article  ADS  CAS  Google Scholar 

  • Parihar V, Raja M, Paulose R (2018) A brief review of structural, electrical and electrochemical properties of zinc oxide nanoparticles. Rev Adv Mater Sci 53(2):119–130

    Article  CAS  Google Scholar 

  • Qiu Y, Zheng Z, Zhou Z, Sheng GD (2009) Effectiveness and mechanisms of dye adsorption on a straw-based biochar. Biores Technol 100(21):5348–5351

    Article  CAS  Google Scholar 

  • Suwunwong T, Patho P, Choto P, Phoungthong K (2020) Enhancement the rhodamine 6G adsorption property on Fe3O4-composited biochar derived from rice husk. Mater Res Express 7(2):025511

    Article  ADS  CAS  Google Scholar 

  • Wang J, Bi L, Ji Y, Ma H, Yin X (2014a) Removal of humic acid from aqueous solution by magnetically separable polyaniline: adsorption behavior and mechanism. J Colloid Interface Sci 430:140–146

    Article  ADS  CAS  PubMed  Google Scholar 

  • Wang W, Wang W, Fan Q, Wang Y, Qiao Z, Wang X (2014b) Effects of UV radiation on humic acid coagulation characteristics in drinking water treatment processes. Chem Eng J 256:137–143

    Article  CAS  Google Scholar 

  • Wang L, Han C, Nadagouda MN, Dionysiou DD (2016) An innovative zinc oxide-coated zeolite adsorbent for removal of humic acid. J Hazard Mater 313:283–290

    Article  CAS  PubMed  Google Scholar 

  • Wu Y, He T, Xu W, Li Y (2016) Preparation and photocatalytic activity of magnetically separable Fe3O4@ ZnO nanospheres. J Mater Sci Mater Electron 27:12155–12159

    Article  CAS  Google Scholar 

  • Yan WL, Bai R (2005) Adsorption of lead and humic acid on chitosan hydrogel beads. Water Res 39(4):688–698

    Article  CAS  PubMed  Google Scholar 

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Acknowledgements

The authors gratefully acknowledge the Lorestan University for supporting and encouragements.

Funding

This study was supported by the college of Chemistry of Lorestan University, Khorramabad, Iran.

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Correspondence to K. Alizadeh.

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Omidvar, O., Alizadeh, K. & Shams, A. Novel Fe3O4–ZnO Carbonized Rice Husk Modified Nano Composite Sorbent for Removal of Humic Acid from Aqueous Media. Iran J Sci 48, 127–139 (2024). https://doi.org/10.1007/s40995-023-01578-5

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