Abstract
Carbon nanotube fiber (CNTF) has promising applications in the fields of electronic devices, sensors, smart fabrics, electrochemical electrodes, electromagnetic shielding, electric heating elements, and composite materials due to its excellent thermal and electrical properties. In this research, the CNTF was continually prepared through floating catalyst chemical vapor deposition (CVD) using a systematic high-temperature shaft furnace equipment. As for applications, an electrochemical electrode based on the CNTF wrapping showed stronger current responding signal due to its high specific surface. Then, a CNTF-based electrothermal element could heat 25 ml water up to 40 °C within 0.5 h. After that, a unidirectional electrically conductive tape based on the CNTF showed different electromagnetic shielding with changing wave vibration direction. Following with that, a CNTF tubular composite was also successfully fabricated showed more light-weight property. Finally, the electrical variation under different forces was studied for the exploration of the CNTF in implantable biosensing electrode.
Graphical abstract
Similar content being viewed by others
Data availability
The data will be available on reasonable request.
References
X. Zhang, W. Lu, G. Zhou, Q. Li, Understanding the mechanical and conductive properties of carbon nanotube fibers for smart electronics. Adv. Mater. 32(5), 1902028 (2020)
W. Lu, M. Zu, J.H. Byun, B.S. Kim, T.W. Chou, State of the art of carbon nanotube fibers: opportunities and challenges. Adv. Mater. 24(14), 1805–1833 (2012)
ja.wikipedia.org/wiki/カーボンナノチューブ
Y. Bai, R. Zhang, X. Ye, Z. Zhu, H. Xie, B. Shen et al., Carbon nanotube bundles with tensile strength over 80 GPa. Nat. Nanotechnol. 13(7), 589–595 (2018)
Y. Jung, Y.S. Cho, J.W. Lee, J.Y. Oh, C.R. Park, How can we make carbon nanotube yarn stronger? Compos. Sci. Technol. 166, 95–108 (2018)
M.F. Yu, B.S. Files, S. Arepalli, R.S. Ruoff, Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties. Phys. Rev. Lett. 84(24), 5552 (2000)
M. Miao, Yarn spun from carbon nanotube forests: production, structure, properties and applications. Particuology 11(4), 378–393 (2013)
M.D. Yadav, K. Dasgupta, A.W. Patwardhan, J.B. Joshi, High performance fibers from carbon nanotubes: synthesis, characterization, and applications in composites: a review. Ind. Eng. Chem. Res. 56(44), 12407–12437 (2017)
N. Behabtu, M.J. Green, M. Pasquali, Carbon nanotube-based neat fibers. Nano Today 3(5–6), 24–34 (2008)
C.-D. Tran, Dry spinning carbon nanotubes into continuous yarn: progress, processing and applications, in Nanotube Superfiber Materials (William Andrew Publishing, 2014), pp. 211–242
Z. Zhang, M.T. Innocent, N. Tang, R. Li, Z. Hu, M. Zhai, L. Yang, W. Ma, H. Xiang, M. Zhu, Electromechanical performance of strain sensors based on viscoelastic conductive composite polymer fibers. ACS Appl. Mater. Interfaces 14(39), 44832–44840 (2022)
H.D. Jeong, S.G. Kim, G.M. Choi, M. Park, B.C. Ku, H.S. Lee, Theoretical and experimental investigation of the wet-spinning process for mechanically strong carbon nanotube fibers. Chem. Eng. J. 412, 128650 (2021)
Y. Inoue, Direct dry spinning of millimeter-long carbon nanotube arrays for aligned sheet and yarn, in Nanotube Superfiber Materials (William Andrew Publishing, 2014), pp. 389–414
A.G. Osorio, A.S. Takimi, C.P. Bergmann, Synthesis of vertically aligned carbon nanotubes by CVD technique: a review, in NanoCarbon 2011: Selected Works from the Brazilian Carbon Meeting (Springer, Berlin/Heidelberg, 2013), pp. 113–124
H. Inoue, M. Hada, T. Nakagawa, T. Marui, T. Nishikawa, Y. Yamashita, Y. Inoue, K. Takahashi, Y. Hayashi, The critical role of the forest morphology for dry drawability of few-walled carbon nanotubes. Carbon 158, 662–671 (2020)
F. Smail, A. Boies, A. Windle, Direct spinning of CNT fibres: past, present and future scale up. Carbon 152, 218–232 (2019)
T. Zhou, Y. Niu, Z. Li, H. Li, Z. Yong, K. Wu, Y. Zhang, Q. Li, The synergetic relationship between the length and orientation of carbon nanotubes in direct spinning of high-strength carbon nanotube fibers. Mater. Des. 203, 109557 (2021)
P. Dariyal, A.K. Arya, B.P. Singh et al., A review on conducting carbon nanotube fibers spun via direct spinning technique. J. Mater. Sci. 56, 1087–1115 (2021)
H. Khoshnevis, T.Q. Tran, S.M. Mint, A. Zadhoush, H.M. Duong, M. Youssefi, Effect of alignment and packing density on the stress relaxation process of carbon nanotube fibers spun from floating catalyst chemical vapor deposition method. Colloids Surf. A 558, 570–578 (2018)
T.Q. Tran, R.J. Headrick, E.A. Bengio, S. Myo Myint, H. Khoshnevis, V. Jamali, H.M. Duong, M. Pasquali, Purification and dissolution of carbon nanotube fibers spun from the floating catalyst method. ACS Appl. Mater. Interfaces 9(42), 37112–37119 (2017)
S.Y. Moon, B.R. Kim, C.W. Park, S.H. Lee, S.M. Kim, High-crystallinity single-walled carbon nanotube aerogel growth: understanding the real-time catalytic decomposition reaction through floating catalyst chemical vapor deposition. Chem. Eng. J. Adv. 10, 100261 (2022)
Y.J. Yan, H. Xia, Y.P. Qiu, Z.Z. Xu, Q.Q. Ni, Shape memory driving thickness-adjustable G@SMPU sponge with ultrahigh carbon loading ratio for excellent microwave shielding performance. Mater. Lett. 236, 116–119 (2019)
Y.J. Yan, H. Xia, Y. Fu, Z. Xu, Q.Q. Ni, Carbon nanofiber-structured polyurethane foams for compaction-adjustable microwave shielding. Mater. Chem. Phys. 246, 122808 (2020)
Y.J. Yan, H. Xia, Y.P. Qiu, Z.Z. Xu, Q.Q. Ni, Fabrication of gradient vapor grown carbon fiber based polyurethane foam for shape memory driven microwave shielding. RSC Adv. 9, 9401–9409 (2019)
Y.J. Yan, H. Xia, Y.P. Qiu, Z.Z. Xu, Q.Q. Ni, Highly aligned nonwoven vapor grown carbon fibre based polyurethane fibrous membrane for direction-dependent microwave shielding. Mater. Lett. 245, 98–102 (2019)
Acknowledgments
This work was supported by Scientific Research Foundation (11112932612214, Zhejiang Sci-Tech University), National Natural Science Foundation of China (52073259), Open Fund Project (TYY202207, Zhejiang Sci-Tech University Tongxiang Research Institute), Open Fund Project (No.YB17, Key Laboratory of Intelligent Textile and Flexible Interconnection of Zhejiang Province), Program of “Xinmiao” (Potential) Talents in Zhejiang Province (11110032662312).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Competing interests
The authors declare that there are no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Yan, Y., Duan, M., Zheng, H. et al. Continuous preparation of carbon nanotube fiber and its potential applications in electrical, thermal, mechanical and biosensing fields. Journal of Materials Research 39, 1023–1034 (2024). https://doi.org/10.1557/s43578-024-01289-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/s43578-024-01289-6