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Studies on Intermolecular Interactions in Binary Liquid Mixtures of 2-Methyl-1-butanol with Glycol Ethers {CH3(OCH2CH2)nOH}, n = 1,2,3 at Different Temperatures: A Volumetric, Acoustic and Transport Study

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Abstract

In the present study, measurements of experimental density (ρ), viscosity (η) and speed of sound (u) of binary liquid mixtures of 2-methyl-1-butanol with ethylene glycol monomethyl ether, diethylene glycol monomethyl ether and triethylene glycol monomethyl ether have been carried out within the temperature range of 298.15–308.15 K with an interval of 5 K. Using the experimental data, excess properties such as excess molar volume (\({V}_{m}^{E}\)), excess molar isentropic compressibility (\({K}_{s,m}^{E}\)), excess speed of sound (\({u}^{E}\)), deviation in viscosity (Δη) and excess Gibbs free energy of activation for viscous flow (\(\Delta {G}^{{\ast}E}\)) have been calculated to study the intermolecular interactions present in these liquid mixtures. By comparing the standard deviation values the correlation ability of various proposed viscosity models has also been tested. Further, to rationalize the excess volume data Prigogine–Flory–Patterson (PFP) theory has also been studied.

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Acknowledgements

One of the authors (Rachana Singh) gratefully acknowledges the Council of Scientific & Industrial Research (CSIR), New Delhi for financial support in the form of Junior Research Fellowship via file No. 09/105(0306)/2020-EMR-I dated 30/5/2020.

Funding

This work was supported by the Council of Scientific & Industrial Research (CSIR), New Delhi [09/105(0306)/2020-EMR-I dated 30/5/2020]. My self Rachana. I am CSIR fellow with file No. 09/105(0306)/2020-EMR-I dated 30/5/2020. My fellowship has been stuck from past three months i.e. from September 2023 to November 2023. On CSIR Fellows portal it is proceeded up to university. It is not further proceeded by EMR DA. Kindly resolve my issue as soon as possible.

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  1. Department of Chemistry, Kurukshetra University, Kurukshetra, Haryana, 136119, India

    Gyan Prakash Dubey, Rachana Singh & Aarzoo Ahuja

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  1. Gyan Prakash Dubey
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Gyan Prakash Dubey: Conceptualization, validation, investigation, resources, writing—review and editing, Supervision. Rachana Singh: Conceptualization, resources, writing—original draft, visualization, funding acquisition. Aarzoo Ahuja: Conceptualization, resources, visualization.

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Correspondence to Gyan Prakash Dubey.

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Dubey, G.P., Singh, R. & Ahuja, A. Studies on Intermolecular Interactions in Binary Liquid Mixtures of 2-Methyl-1-butanol with Glycol Ethers {CH3(OCH2CH2)nOH}, n = 1,2,3 at Different Temperatures: A Volumetric, Acoustic and Transport Study. Int J Thermophys 45, 32 (2024). https://doi.org/10.1007/s10765-024-03329-z

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