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A New Phase of the Octahedral Tellurium-Iodine Cluster Complex of Rhenium

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Abstract

A cluster complex of the composition [{Re6Te8}(TeI2)6]I2·[{Re6Te8}(TeI2)4(TeI3)2]·I2 is obtained by a reaction between [{Re6Te8}Te7] and I2 in a sealed quartz ampoule at 400 °C. More than three times increase in the volume of the ampoule in which the reaction is performed with maintaining the other conditions is shown to lead to the formation of the previously described cluster complex [{Re6Te8}(TeI2)6]I2. An increase in the synthesis temperature to 450 °C leads to the formation of X-ray amorphous products of the unknown composition. The [{Re6Te8}(TeI2)6]I2·[{Re6Te8}(TeI2)4(TeI3)2]·I2 compound obtained at 400 °C crystallizes in the triclinic crystal system, space group \(P\bar{1}\), and unit cell parameters a = 11.0859(3) Å, b = 11.9021(4) Å, c = 21.1308(7) Å, α = 79.259(2)°, β = 85.533(2)°, γ = 66.220(2)°, V = 2506.55(14) Å3, Z = 1. The crystal structure consists of four layers of two types that alternate along the c parameter: 1) the layer formed by iodine anions and [{Re6Te8}(TeI2)6]2+ cluster cations and 2) the layer formed by neutral cluster complexes [{Re6Te8}(TeI2)4(TeI3)2] and crystallization I2 molecules. Weak interactions between the adjacent cluster complexes are observed in both layers along with I⋯I halogen bonds. The layers are linked with each other via I⋯I and Te⋯I interactions.

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Funding

The work was supported by the Russian Science Foundation (grant No. 22-23-20110) and the Government of the Novosibirsk Oblast’ (grant No. p-30).

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. D. Novikova, D. I. Konovalov, A. A. Ivanov, N. V. Kuratieva & M. A. Shestopalov

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  1. E. D. Novikova
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  2. D. I. Konovalov
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Correspondence to M. A. Shestopalov.

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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 1, 121167.https://doi.org/10.26902/JSC_id121167

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Novikova, E.D., Konovalov, D.I., Ivanov, A.A. et al. A New Phase of the Octahedral Tellurium-Iodine Cluster Complex of Rhenium. J Struct Chem 65, 160–168 (2024). https://doi.org/10.1134/S0022476624010153

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